Search

We report the detection of CH3OH emission in comet 46P/Wirtanen on UT 2018 December 8 and 9 using the Atacama Compact Array (ACA), part of the Atacama Large Millimeter/Submillimeter Array (ALMA). These interferometric measurements of CH3OH along with continuum emission from dust probed the inner coma (3OH outgassing during five separate ACA executions between UT 23:57 December 7 and UT 04:55 December 9, with a clear progression in the spectral line profiles over a timescale of minutes. We present spectrally integrated flux maps, production rates, rotational temperatures, and spectral line profiles of CH3OH during each ACA execution. The variations in CH3OH outgassing are consistent with Wirtanen’s 9 hr nucleus rotational period derived from optical and millimeter wavelength measurements and thus are likely coupled to the changing illumination of active sites on the nucleus. The consistent blue offset of the line center indicates enhanced CH3OH sublimation from the sunward hemisphere of the comet, perhaps from icy grains. These results demonstrate the exceptional capabilities of the ACA for time-resolved measurements of comets such as 46P/Wirtanen.

International audience; Understanding the cosmogonic record encoded in the parent volatiles stored in cometary nuclei requires investigating whether evolution (thermal or otherwise) has modified the composition of short-period comets during successive perihelion passages. As the most volatile molecules systematically observed in comets, the abundances of CO, CH 4 , and C 2 H 6 in short-period comets may serve to elucidate the interplay between natal conditions and post-formative evolution in setting present-day composition, yet secure measurements of CO and CH 4 in Jupiterfamily comets (JFCs) are especially sparse. The highly favorable 2018 apparition of JFC 21P/Giacobini-Zinner enabled a sensitive search for these "hypervolatiles" in a prototypical carbon-chain depleted comet. We observed 21P/Giacobini-Zinner with the iSHELL spectrograph at the NASA Infrared Telescope Facility on four preperihelion dates, two dates near-perihelion, and one post-perihelion date. We obtained detections of CO, CH 4 , and C 2 H 6 simultaneously with H 2 O on multiple dates. We present rotational temperatures, production rates, and mixing ratios. Combined with previous work, our results may indicate that the hypervolatile coma composition of 21P/ Giacobini-Zinner was variable across apparitions as well as within a particular perihelion passage, yet the spread in these measurements is a relatively small fraction of the variation in each molecule from comet to comet. We discuss the implications of our measured hypervolatile content of 21P/Giacobini-Zinner for the evolution of JFCs, and place our results in the context of findings from the Rosetta mission and ground-based studies of comets.

We present H$_2$O production rates for comet C/2012 S1 (ISON) derived from observations of [OI] and OH emission during its inbound leg, covering a heliocentric distance range of 1.8-0.44 AU. Our production rates are in agreement with previous measurements using a variety of instruments and techniques and with data from the various observatories greatly differing in their projected fields of view. The consistent results across all data suggest the absence of an extended source of H$_2$O production, for example sublimation of icy grains in the coma, or a source with spatial extent confined to the dimensions of the smallest projected field of view (in this case $ 1.2 AU, which then decreased to about half this value from R$_h$=1.2-0.9 AU. This was followed by a rapid increase in active area at about R$_h$=0.6 AU, corresponding to the first of three major outbursts ISON experienced inside of 1 AU. The combination of a detected outburst in the light curve and rapid increase in active area likely indicates a major nucleus fragmentation event. The 5-10 km$^2$ active area observed outside of R$_h$=0.6 AU is consistent with a 50-100% active fraction for the nucleus, larger than typically observed for cometary nuclei. Although the absolute value of the active area is somewhat dependent on the thermal model employed, the changes in active area observed are consistent among models. The conclusion of a 50-100+% active fraction is robust for realistic thermal models of the nucleus. However the possibility of a contribution of a spatially unresolved distribution of icy grains cannot be discounted., Comment: 26 pages, 5 figures, 5 tables, accepted for publication in Icarus

The 2018 perihelion passage of comet 46P/Wirtanen afforded an opportunity to measure the abundances and spatial distributions of coma volatiles in a Jupiter-family comet with exceptional spatial resolution for several weeks surrounding its closest approach to Earth (Δmin ∼0.078 au on UT December 16). We conducted near-infrared spectroscopic observations of 46P/Wirtanen using iSHELL at the NASA Infrared Telescope Facility on UT 2018 December 18 in direct coordination with observations using the newly upgraded NIRSPEC-2 instrument at the W. M. Keck Observatory, and securely detected fluorescent emission from CH3OH, C2H6, and H2O. This coordinated campaign utilizing the two premier near-infrared facilities in the northern hemisphere enabled us to sample distinct projections of the coma into the plane of the sky simultaneously, and provided an unprecedented view into the inner coma of 46P/Wirtanen near closest approach. We report rotational temperatures, production rates, and abundance ratios (i.e., mixing ratios) for all sampled species and compare our iSHELL results to simultaneous (or near-simultaneous) measurements taken with NIRSPEC-2. We demonstrate the extraordinary synergy of coordinated measurements using iSHELL and NIRSPEC-2, and advocate for future cometary studies that jointly leverage the capabilities of these two facilities.

A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in time for near-infrared spectroscopic observations of comet 46P/Wirtanen during its exceptionally close flyby of Earth in 2018 December. These studies determined the abundances of several volatiles, including C2H2, C2H6, CH3OH, NH3, HCN, H2CO, and H2O. Long-slit spatial distributions of gas rotational temperature and column density are diagnostic for the presence of icy grains in the coma and understanding if different volatiles are associated with common or distinct outgassing sources. These spatial distributions suggest that C2H2, C2H6, and HCN have a common outgassing source, whereas H2O and CH3OH have additional, more extended sources. The synergy of these findings with observations by space missions (Rosetta and EPOXI) motivates continuing studies to address whether or not C2H6, C2H2, and HCN have a common source of release (plausibly associated with CO2) in a larger sample of comets and whether systematic differences exist in the release of these species compared to H2O and CH3OH. Abundances of volatiles are reported relative to H2O, as traditionally done, as well as C2H6. While not unique, the choice of C2H6 demonstrates the value of extending the chemical taxonomy of parent volatiles in comets toward additional compositional “baselines” and, importantly, closer integration between coma abundances and the underlying volatile associations as revealed by spatial distributions. Our findings on composition and sources of outgassing include information relevant to future evaluations of 46P/Wirtanen as a prospective spacecraft target.

A systematic analysis of the mixing ratios with respect to H 2 O for eight species (CH 3 OH, HCN, NH 3 , H 2 CO, C 2 H 2 , C 2 H 6 , CH 4 , and CO) measured with high-resolution infrared spectroscopy in thirty comets between 1997 and 2013 is presented. Some trends are beginning to emerge when mixing ratios in individual comets are compared to average mixing ratios obtained for all species within the population. The variation in mixing ratios for all measured species is at least an order of magnitude. Overall, Jupiter-family comets are depleted in volatile species with respect to H 2 O compared to long-period Oort cloud comets, with the most volatile species showing the greatest relative depletion. There is a high positive correlation between the mixing ratios of HCN, C 2 H 6 , and CH 4 , whereas NH 3 , H 2 CO, and C 2 H 2 are moderately correlated with each other but generally uncorrelated or show only weak correlation with other species. CO is generally uncorrelated with the other measured species possibly because it has the highest volatility and is therefore more susceptible to thermal evolutionary effects. Most of these correlations appear to be independent of dynamical class with a few possible exceptions. Molecular mixing ratios for CH 3 OH, HCN, C 2 H 6 , and CH 4 show an expected behavior with heliocentric distance suggesting a dominant ice source, whereas there is emerging evidence that the mixing ratios of NH 3 , H 2 CO, C 2 H 2 , NH 2 , and CN may increase at small heliocentric distances, suggesting the possibility of additional sources related to the thermal decomposition of organic dust. Although this provides information on the composition of the most volatile grains in comets, it presents an additional difficulty in classifying comet chemistry because most comets within this dataset were only observed over a limited range of heliocentric distance. Although there is remarkable compositional diversity resulting in a unique chemical fingerprint for each comet, a hierarchical tree cluster analysis is used to determine a taxonomic classification system containing four groups and eleven subgroups. Optical and infrared comparisons indicate that mixing ratios of daughter species and potential parents from cometary ices are sometimes but not always consistent with one another. This suggests that in many comets there are significant sources of C 2 and/or CN from grains, and that the importance of these sources is variable within the comet population.

We present analysis of observations of CO2 and OI emission in three comets to measure the CO2 abundance and evaluate the possibility of employing observations of OI emission in comets as a proxy for CO2. We obtained NIR imaging sensitive to CO2 of comets C/2012 K1 (PanSTARRS), C/2012 K5 (LINEAR), and 290P/Jager with the IRAC instrument on Spitzer. We acquired observations of OI emission in these comets with the ARCES echelle spectrometer mounted on the 3.5-meter telescope at Apache Point Observatory and observations of OH with the Swift observatory (PanSTARRS) and with Keck HIRES (Jager). The CO2/H2O ratios derived from the Spitzer images are 12.6 +/- 1.3% (PanSTARRS), 28.9 +/- 3.6% (LINEAR), and 31.3 +/- 4.2% (Jager). These abundances are derived under the assumption that contamination from CO emission is negligible. The CO2 abundance for PanSTARRS is close to the average abundance measured in comets at similar heliocentric distance to date, while the abundances measured for LINEAR and Jager are significantly larger than the average abundance. From the coma morphology observed in PanSTARRS and the assumed gas expansion velocity, we derive a rotation period for the nucleus of about 9.2 hours. Comparison of H2O production rates derived from ARCES and Swift data, as well as other observations, suggest the possibility of sublimation from icy grains in the inner coma. We evaluate the possibility that the OI emission can be employed as a proxy for CO2 by comparing CO2/H2O ratios inferred from the OI lines to those measured directly by Spitzer. We find that for PanSTARRS we can reproduce the observed CO2 abundance to an accuracy of ~20%. For LINEAR and Jager, we were only able to obtain upper limits on the CO2 abundance inferred from the OI lines. These upper limits are consistent with the CO2 abundances measured by Spitzer., Comment: 30 pages, 6 tables, 7 figures, accepted for publication in Icarus

We present high spectral resolution optical spectra obtained with the ARCES instrument at Apache Point Observatory showing detection of the [OI]6300 A line in interstellar comet 2I/Borisov. We employ the observed flux in this line to derive an H$_2$O production rate of (6.3$\pm$1.5)$\times$10$^{26}$ mol s$^{-1}$. Comparing to previously reported observations of CN, this implies a CN/H$_2$O ratio of $\sim$0.3-0.6%. The lower end of this range is consistent with the average value in comets, while the upper end is higher than the average value for Solar System comets, but still within the range of observed values. C$_2$/H$_2$O is depleted, with a value likely less than 0.1%. The dust-to-gas ratio is consistent with the normal value for Solar System comets. Using a simple sublimation model we estimate an H$_2$O active area of 1.7 km$^2$, which for current estimates for the size of Borisov suggests active fractions between 1-150%, consistent with values measured in Solar System comets. More detailed characterization of 2I/Borisov, including compositional information and properties of the nucleus, is needed to fully interpret the observed H$_2$O production rate., 8 pages, 2 figures, 1 table, Accepted in ApJ Letters

High-resolution infrared spectra of Jupiter-family comet 45P/Honda-Mrkos-Pajdusakova were obtained with NIRSPEC at the W. M. Keck Observatory on two post-perihelion dates (UT 2017 February 13 and 19), when the comet was at heliocentric distances of 1.01 and 1.10 AU, respectively. On UT February 13, H2O was measured simultaneously with six trace parent molecules: CH3OH, C2H6, HCN, NH3, C2H2, and H2CO. On UT February 19, CH4 and CO were also targeted in addition to the species measured on UT February 13. Abundances of CO, CH4, and C2H2 relative to H2O are consistent with values obtained from IRTF/iSHELL observations of 45P in early January 2017 just after perihelion when the heliocentric distance was 0.55–0.56 AU. Differences are seen in H2CO/H2O, C2H6/H2O, CH3OH/H2O, and HCN/H2O in February compared to January. Additionally, NH3 abundances appear highly variable during the February measurements, suggesting possible fluctuations of a factor of ten; however, there is significant uncertainty in quantifying NH3 owing to the marginal detections of only one or two lines on each of the two dates. Combining all infrared spectroscopic observations of 45P in January and February 2017, a post-perihelion relationship of Q(H2O) = (2.81 ± 0.25) × 1027 [Rh(−3.83±0.18)] molecules s−1 is derived. However, all measurements suggest significant variability in H2O production on timescales of hours and days. Compared to other comets, volatile abundances relative to H2O in 45P are as follows: CO (depleted relative to all measured comets), CH3OH (enriched/all comets), CH4 and C2H6 (typical/all comets, enriched/Jupiter-family comets), C2H2 (depleted/all comets, typical/Jupiter-family comets), H2CO (January: typical, February depleted/all comets), HCN (January: severely depleted, February: typical/Jupiter-family comets). The small geocentric distances of the comet in February 2017 provide high spatial resolution in the coma of 45P (~12 and 19 km/pixel on February 13 and 19, respectively). Overall, the spatial distributions of volatiles and dust suggest a relatively symmetric and uniform coma during the UT February 13 and 19 observations, with small spatial differences noted between some volatile species. Measured C2H2 and HCN abundances are consistent with HCN as the primary parent of CN and C2H2 as a significant but not primary parent for C2, based on C2 and CN production rate measurements from the 2017 and previous apparitions. Extracted spectra show an increase in the dust-to-gas ratio in 45P from February 13 to 19 in agreement with contemporaneous narrowband optical measurements.

Since its launch in 1990, the Hubble Space Telescope (HST) has served as a platform with unique capabilities for remote observations of comets in the far-ultraviolet region of the spectrum. Successive generations of imagers and spectrographs have seen large advances in sensitivity and spectral resolution enabling observations of the diverse properties of a representative number of comets during the past 25 years. To date, four comets have been observed in the far-ultraviolet by the Cosmic Origins Spectrograph (COS), the last spectrograph to be installed in HST, in 2009: 103P/Hartley 2, C/2009 P1 (Garradd), C/2012 S1 (ISON), and C/2014 Q2 (Lovejoy). COS has unprecedented sensitivity, but limited spatial information in its 2.5 arcsec diameter circular aperture, and our objective was to determine the CO production rates from measurements of the CO Fourth Positive system in the spectral range of 1400 to 1700 A. In the two brightest comets, nineteen bands of this system were clearly identified. The water production rates were derived from nearly concurrent observations of the OH (0,0) band at 3085 A by the Space Telescope Imaging Spectrograph (STIS). The derived CO/H2O production rate ratio ranged from ~0.3% for Hartley 2 to ~22% for Garradd. In addition, strong partially resolved emission features due to multiplets of S I, centered at 1429 A and 1479 A, and of C I at 1561 A and 1657 A, were observed in all four comets. Weak emission from several lines of the H2 Lyman band system, excited by solar Lyman-alpha and Lyman-beta pumped fluorescence, were detected in comet Lovejoy., Comment: 10 pages, 6 figures, accepted for publication in the Astronomical Journal

Comet C/2016 R2 (PanSTARRS) has a peculiar volatile composition, with CO being the dominant volatile as opposed to H$_2$O and one of the largest N$_2$/CO ratios ever observed in a comet. Using observations obtained with the \textit{Spitzer Space Telescope}, NASA's Infrared Telescope Facility, the 3.5-meter ARC telescope at Apache Point Observatory, the Discovery Channel Telescope at Lowell Observatory, and the Arizona Radio Observatory 10-m Submillimeter Telescope we quantified the abundances of 12 different species in the coma of R2 PanSTARRS. We confirm the high abundances of CO and N$_2$ and heavy depletions of H$_2$O, HCN, CH$_3$OH, and H$_2$CO compared to CO reported by previous studies. We provide the first measurements (or most sensitive measurements/constraints) on H$_2$O, CO$_2$, CH$_4$, C$_2$H$_6$, OCS, C$_2$H$_2$, and NH$_3$, all of which are depleted relative to CO by at least one to two orders of magnitude compared to values commonly observed in comets. The observed species also show strong enhancements relative to H$_2$O, and even when compared to other species like CH$_4$ or CH$_3$OH most species show deviations from typical comets by at least a factor of two to three. The only mixing ratios found to be close to typical are CH$_3$OH/CO$_2$ and CH$_3$OH/CH$_4$. While R2 PanSTARRS was located at a heliocentric distance of 2.8 AU at the time of our observations in January/February 2018, we argue that this alone cannot account for the peculiar observed composition of this comet and therefore must reflect its intrinsic composition. We discuss possible implications for this clear outlier in compositional studies of comets obtained to date, and encourage future dynamical and chemical modeling in order to better understand what the composition of R2 PanSTARRS tells us about the early Solar System., 36 pages, 12 figures, 7 tables, accepted for publication in AJ

We obtained high-resolution (lambda divided by delta times lambda equals approximately 25,000) pre-perihelion spectra of Comet C/2013 V5 (Oukaimeden) using NIRSPEC at Keck II on UT 2014 September 5-6, and CSHELL (Cryogenic Echelle Spectrograph) at the NASA-Infrared Telescope Facility on September 11-13, altogether spanning a range in heliocentric distance R (sub h) equals 0.789-0.698 astronomical units. We report water production rates, and production rates and abundance ratios relative to co-measured H2O for eight trace molecules: CO, H2CO, CH3OH, CH4, C2H2, C2H6, HCN, and NH3. Our measured water production rates from NIRSPEC ( Near Infra-Red Spectrograph) and CSHELL observations remained relatively constant and were close to those from SOHO (Solar and Heliospheric Observatory) / Solar Wind Anisotropies observations that encompassed our dates, suggesting H2O production dominated by release directly from or within approximately 2000 kilometers of the nucleus. All trace volatiles were depleted relative to their respective median abundances among comets, excepting NH3, which was consistent with its median abundance. Most surprising were pronounced increases in abundance ratios for CH3OH (by 51 percent relative to simultaneously measured H2O) and especially C2H6 (by 87 percent) between September 5 and 6. On September 5, C2H6 was severely depleted, consistent with its lowest abundance yet measured for any comet. It also tracked the spatial profile of H2O, suggesting C2H6 was associated with a polar ice phase dominating gas production. On September 6, C2H6 was only moderately depleted and was spatially distinct from H2O, suggesting both polar- and nonpolar-dominated ice phases contributed to the activity then. Our results are consistent with a nonhomogeneous volatile composition for C/2013V5, implying differential processing of its constituent ices.

The highly favorable 2017 apparition of 2P/Encke allowed the first comprehensive comparison of primary volatile abundances in a given comet across multiple apparitions. This apparition offered opportunities to address pressing questions in cometary science, including investigating evolutionary and/or heliocentric distance (R(sub h)) effects on volatile production, sampling the hypervolatiles CO and CH4 in an ecliptic comet, and measuring volatile release at small R(sub h). The faintness and frequently low geocentric velocity of ecliptic comets during most apparitions make our near-infrared observations of these hypervolatiles rare and of high scientific impact. We characterized the volatile composition of 2P/Encke on three post-perihelion dates using the iSHELL spectrograph at the NASA Infrared Telescope Facility on Maunakea, HI. We detected fluorescent emission from nine primary volatiles (H2O, CO, C2H6, CH3OH, CH4, H2CO, NH3, OCS, and HCN) and three fragment species (OH*, NH2, and CN), and obtained a sensitive upper limit for C2H2. We report rotational temperatures, production rates, and mixing ratios (abundances relative to H2O). Compared to mean abundances in comets observed to date in the near-infrared, mixing ratios of trace gases in 2P/Encke were depleted for all species except H2CO and NH3, which were “normal.” The detection of the hypervolatiles CO and CH4 is particularly notable given the paucity of measurements in ecliptic comets. We observed significant differences in primary volatile composition compared to published pre-perihelion results from 2003 at larger R(sub h). We discuss possible mechanisms for these differences and discuss these results in the context of findings from the Rosetta mission and ground-based studies of comets.

We used the new high spectral resolution cross-dispersed facility spectrograph, iSHELL, at the NASA Infrared Telescope Facility on Maunakea, HI, to observe Jupiter-family comet (JFC) 45P/Honda-Mrkos-Pajdusakova. We report water production rates, as well as production rates and abundance ratios relative to H2O, for eight trace parent molecules (native ices), CO, CH4, H2CO, CH3OH, HCN, NH3, C2H2, and C2H6, on 2 days spanning UT 2017 January 6/7 and 7/8, shortly following perihelion. Trace species were measured simultaneously with H2O and/or OH prompt emission, a proxy for H2O production, thereby providing a robust and consistent means of establishing the native ice composition of 45P. Its favorable geocentric radial velocity (approximately minus 35 kilometers per second) permitted sensitive measures of the "hypervolatiles" CO and CH4, which are substantially undercharacterized in JFCs. Our results represent the most precise ground-based measures of CO and CH4 to date in a JFC, providing a foundation for building meaningful statistics regarding their abundances. The abundance ratio for CH4 in 45P (0.79 percent plus or minus 0.06 percent relative to H2O) was consistent with its median value as measured among Oort Cloud comets, whereas CO (0.60 percent plus or minus 0.04 percent) was strongly depleted. Compared with all measured comets, HCN (0.049 percent plus or minus 0.012 percent) was strongly depleted, CH3OH (3.6 percent plus or minus 0.3 percent) was enriched, and the remaining species were consistent with their respective median abundances. The volatile composition measured for 45P could indicate processing of ices prior to their incorporation into its nucleus. Spatial analysis of emissions suggests enhanced release of more volatile species into the sunward-facing hemisphere of the coma.

We performed high-dispersion near-infrared spectroscopic observations of comet C/2010 G2 (Hill) at 2.5 AU from the Sun using NIRSPEC (R ≈ 25,000) at the Keck II Telescope on UT 2012 January 9 and 10, about a week after an outburst had occurred. Over the two nights of our observations, prominent emission lines of CH{sub 4} and C{sub 2}H{sub 6}, along with weaker emission lines of H{sub 2}O, HCN, CH{sub 3}OH, and CO were detected. The gas production rate of CO was comparable to that of H{sub 2}O during the outburst. The mixing ratios of CO, HCN, CH{sub 4}, C{sub 2}H{sub 6}, and CH{sub 3}OH with respect to H{sub 2}O were higher than those for normal comets by a factor of five or more. The enrichment of CO and CH{sub 4} in comet Hill suggests that the sublimation of these hypervolatiles sustained the outburst of the comet. Some fraction of water in the inner coma might exist as icy grains that were likely ejected from nucleus by the sublimation of hypervolatiles. Mixing ratios of volatiles in comet Hill are indicative of the interstellar heritage without significant alteration in the solar nebula.

We conducted high-dispersion spectroscopic observations of Comet 103P/Hartley 2 in the near-infrared wavelength region using the Keck II telescope with NIRSPEC. We obtained observations on four dates, with the last observations performed during the EPOXI closest approach. For this work we focus on the observations performed on UT 2010 October 17 and 21, while observations carried out on UT 2010 September 16 and November 4 have been reported elsewhere. On all dates the spatial distributions in the coma of C 2 H 6 , HCN and C 2 H 2 were similar to each other and consistent with the CN-jet morphology observed from optical observations. The spatial distributions in the coma of H 2 O and CH 3 OH were also similar to each other, but were generally different from C 2 H 6 , HCN and C 2 H 2 . There might be two distinct phases of ice in Comet Hartley 2; one is enriched in H 2 O and CH 3 OH, and another is enriched in more volatile species (C 2 H 6 , C 2 H 2 , and HCN). It is possible that highly volatile species like C 2 H 6 were segregated from the H 2 O matrix when warmer conditions were prevalent. We summarize our spectroscopic observations and report absolute production rates and mixing ratios of parent volatiles. There was no evidence of any significant diversity in the mixing ratios of parent volatiles on different dates. Comet Hartley 2 was normal in CH 3 OH/H 2 O, C 2 H 6 /H 2 O, C 2 H 2 /H 2 O, NH 3 /H 2 O but depleted in H 2 CO/H 2 O and CH 4 /H 2 O. OPRs of H 2 O in Comet Hartley 2 measured in its 2010 apparition were consistent with those observed by the Infrared Satellite Observatory in 1997.

We obtained high-resolution (λ/Δλ ∼ 28,000) infrared spectra of Comet 103P/Hartley 2 on UT 2010 November 4.6 using the NIRSPEC spectrometer at the W.M. Keck Observatory. Here we present spectra of Hartley 2 between 2.832 and 3.639 μm (3531–2748 cm−1), representing the most complete high-resolution infrared survey of a Jupiter-family comet to date in this wavelength region. We have tabulated rest frequencies, line fluxes, line signal-to-noise ratios and line widths for all detected emissions. Fluorescence models, published line lists and laboratory spectra were used to obtain molecular assignments for detected emissions. Multiple lines of the following species were detected in Hartley 2: H2O, OH, CH3OH, C2H6, HCN, C2H2, H2CO, NH3 and NH2. All identified species seen in this survey have been previously detected in comets. There were 364 distinct emission features present in these spectra, of which 36 were unidentified. We compare the spectrum of Hartley 2 to chemically different Jupiter-family Comets 73P/Schwassmann–Wachmann 3-B and 17P/Holmes in order to obtain additional information on the characteristics of unknown lines through the comparison of relative line fluxes for corresponding emissions in these comets. For the strongest unidentified emissions, additional information was also obtained through a comparison of their spatial distributions in the coma to that of known emission features in Hartley 2. This spectral survey of Hartley 2 provides detailed information about its overall volatile chemistry, provides a comparison to past and future high-resolution infrared datasets, and further characterizes the most promising spectral regions for future molecular searches in comets.