1. Strategy for the determination of mixtures of alpha and beta emitters in water samples with a combination of rapid methods
- Author
-
J. Fons-Castells, M. Llaurado, and Joana Tent-Petrus
- Subjects
medicine.medical_specialty ,Radionuclide ,Hydrogen compounds ,Chemistry ,Health, Toxicology and Mutagenesis ,Public Health, Environmental and Occupational Health ,Analytical chemistry ,010501 environmental sciences ,010403 inorganic & nuclear chemistry ,01 natural sciences ,Pollution ,0104 chemical sciences ,Analytical Chemistry ,Alpha (programming language) ,Radioecology ,Nuclear Energy and Engineering ,Partial least squares regression ,Drinking water directive ,medicine ,Radiology, Nuclear Medicine and imaging ,Deconvolution ,Radiochemical analysis ,Biological system ,Spectroscopy ,0105 earth and related environmental sciences - Abstract
Quantification of several alpha and beta emitters in mixtures of radionuclides arouses great interest in many fields such as surveillance around nuclear power plants, radioecology, accidental situations or drinking water control. Radiochemical separations are commonly used to deal with this issue. However, deconvolution methods for the analysis of LS spectra have been developed to avoid time-consuming radiochemical separations. The deconvolution procedure usually consists of the comparison of the spectrum that has to be analysed with a set of standard spectra. In order to obtain reliable results, the library of spectra used in the deconvolutions must fit with the analysed sample. For this reason, in order to determine all radionuclides included in the drinking water directive it has been established a strategy to select the radionuclides whose LS spectra must be included in the Partial least squares (PLS) model.
- Published
- 2017