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There has been increasing progress toward detailed characterization of exoplanetary atmospheres, in both observations and theoretical methods. Improvements in observational facilities and data reduction and analysis techniques are enabling increasingly higher quality spectra, especially from ground-based facilities. The high data quality also necessitates concomitant improvements in models required to interpret such data. In particular, the detection of trace species such as metal oxides has been challenging. Extremely irradiated exoplanets (~3000 K) are expected to show oxides with strong absorption signals in the optical. However, there are only a few hot Jupiters where such signatures have been reported. Here we aim to characterize the atmosphere of the ultra-hot Jupiter WASP-33b using two primary transits taken 18 orbits apart. Our atmospheric retrieval, performed on the combined data sets, provides initial constraints on the atmospheric composition of WASP-33b. We report a possible indication of aluminum oxide (AlO) at 3.3-sigma significance. The data were obtained with the long slit OSIRIS spectrograph mounted at the 10-meter Gran Telescopio Canarias. We cleaned the brightness variations from the light curves produced by stellar pulsations, and we determined the wavelength-dependent variability of the planetary radius caused by the atmospheric absorption of stellar light. A simultaneous fit to the two transit light curves allowed us to refine the transit parameters, and the common wavelength coverage between the two transits served to contrast our results. Future observations with HST as well as other large ground-based facilities will be able to further constrain the atmospheric chemical composition of the planet., Comment: 15 pages, 11 figures

We present a comprehensive analysis of the 0.3--5\,$\mu$m transit spectrum for the inflated hot Jupiter HAT-P-41b. The planet was observed in transit with Hubble STIS and WFC3 as part of the Hubble Panchromatic Comparative Exoplanet Treasury (PanCET) program, and we combine those data with warm \textit{Spitzer} transit observations. We extract transit depths from each of the data sets, presenting the STIS transit spectrum (0.29--0.93\,$\mu$m) for the first time. We retrieve the transit spectrum both with a free-chemistry retrieval suite (AURA) and a complementary chemical equilibrium retrieval suite (PLATON) to constrain the atmospheric properties at the day-night terminator. Both methods provide an excellent fit to the observed spectrum. Both AURA and PLATON retrieve a metal-rich atmosphere for almost all model assumptions (most likely O/H ratio of $\log_{10}{Z/Z_{\odot}} = 1.46^{+0.53}_{-0.68}$ and $\log_{10}{Z/Z_{\odot}} = 2.33^{+0.23}_{-0.25}$, respectively); this is driven by a 4.9-$\sigma$ detection of H$_2$O as well as evidence of gas absorption in the optical ($>$2.7-$\sigma$ detection) due to Na, AlO and/or VO/TiO, though no individual species is strongly detected. Both retrievals determine the transit spectrum to be consistent with a clear atmosphere, with no evidence of haze or high-altitude clouds. Interior modeling constraints on the maximum atmospheric metallicity ($\log_{10}{Z/Z_{\odot}} < 1.7$) favor the AURA results. The inferred elemental oxygen abundance suggests that HAT-P-41b has one of the most metal-rich atmospheres of any hot Jupiters known to date. Overall, the inferred high metallicity and high inflation make HAT-P-41b an interesting test case for planet formation theories., Comment: Resubmitted to AAS Journals after revisions

The class of ultra-hot Jupiters comprises giant exoplanets undergoing intense irradiation from their host stars. They have proved to be a particularly interesting population for their orbital and atmospheric properties. One such planet, WASP-121~b, is in a highly misaligned orbit close to its Roche limit, and its atmosphere exhibits a thermal inversion. These properties make WASP-121~b an interesting target for additional atmospheric characterization. In this paper, we present analysis of archival high-resolution optical spectra obtained during transits of WASP-121~b. Artifacts from the Rossiter-McLaughlin effect and Center-to-Limb Variation are deemed negligible. However, we discuss scenarios where these effects warrant more careful treatment by modeling the WASP-121 system and varying its properties. We report a new detection of atmospheric absorption from H$\alpha$ in the planet with a transit depth of $1.87\pm0.11\%$. We further confirm a previous detection of the Na I doublet, and report a new detection of Fe I via cross-correlation with a model template. We attribute the H$\alpha$ absorption to an extended Hydrogen atmosphere, potentially undergoing escape, and the Fe I to equilibrium chemistry at the planetary photosphere. These detections help to constrain the composition and chemical processes in the atmosphere of WASP-121~b., Comment: 15 pages, 14 figures, submitted to MNRAS after addressing reviewer comments

Optical transmission spectroscopy provides crucial constraints on the reference pressure levels and scattering properties for hot Jupiter atmospheres. For certain planets, where alkali atoms are detected in the atmosphere, their line profiles could serve as a good probe to link upper and lower atmospheric layers. WASP-21b is a Saturn-mass hot Jupiter orbiting a thick disc star, with a low density and an equilibrium temperature of 1333 K, which makes it a good target for transmission spectroscopy. Here, we present a low-resolution transmission spectrum for WASP-21b based in one transit observed by the OSIRIS spectrograph at the 10.4 m Gran Telescopio Canarias (GTC), and a high-resolution transmission spectrum based in three transits observed by HARPS-N at Telescopio Nazinale Galileo (TNG) and HARPS at the ESO 3.6 m telescope. We performed spectral retrieval analysis on GTC's low-resolution transmission spectrum and report the detection of Na at a confidence level of $>$3.5-$\sigma$. The Na line exhibits a broad line profile that can be attributed to pressure broadening, indicating a mostly clear planetary atmosphere. The spectrum shows a tentative excess absorption at the K D$_1$ line. Using HARPS-N and HARPS, we spectrally resolved the Na doublet transmission spectrum. An excess absorption at the Na doublet is detected during the transit, and shows a radial velocity shift consistent with the planet orbital motion. We proposed a metric to quantitatively distinguish hot Jupiters with relatively clear atmospheres from others, and WASP-21b has the largest metric value among all the characterized hot Jupiters. The detection of Na at both lower and upper atmosphere of WASP-21b reveals that it is an ideal target for future follow-up observations, providing the opportunity to understand the nature of its atmosphere across a wide range of pressure levels., Comment: 16 pages, 14 figures, accepted for publication in A&A on July 27, 2020

Recent detections of thermal inversions in the dayside atmospheres of some hot Jupiters are motivating new avenues to understand the interplay between their temperature structures and other atmospheric conditions. In particular, TiO has long been proposed to cause thermal inversions in hot Jupiters, depending on other factors such as stellar irradiation, C/O, and vertical mixing. TiO also has spectral features in the optical and near-infrared that have been detected. However, interpretations of TiO signatures rely on the accuracy of TiO opacity used in the models. The recently reported Toto TiO line list provides a new opportunity to investigate these dependencies, which is the goal of the present work. First, we investigate how the Toto line list affects observable transmission and emission spectra of hot Jupiters at low and high resolution. The improvement in the Toto line list compared to a previous line list results in observable differences in the model spectra, particularly in the optical at high resolution. Secondly, we explore the interplay between temperature structure, irradiation and composition with TiO as the primary source of optical opacity, using 1D self-consistent atmospheric models. Among other trends, we find that the propensity for thermal inversions due to TiO peaks at C/O$\sim$0.9, consistent with recent studies. Using these models, we further assess metrics to quantify thermal inversions due to TiO, compared to frequently-used Spitzer photometry, over a range in C/O, irradiation, metallicity, gravity and stellar type., Accepted for publication in MNRAS, 19 pages, 14 figures

Atmospheric compositions can provide powerful diagnostics of formation and migration histories of planetary systems. We investigate constraints on atmospheric abundances of H$_2$O, Na, and K, in a sample of transiting exoplanets using latest transmission spectra and new H$_2$ broadened opacities of Na and K. Our sample of 19 exoplanets spans from cool mini-Neptunes to hot Jupiters, with equilibrium temperatures between $\sim$300 and 2700 K. Using homogeneous Bayesian retrievals we report atmospheric abundances of Na, K, and H$_2$O, and their detection significances, confirming 6 planets with strong Na detections, 6 with K, and 14 with H$_2$O. We find a mass-metallicity trend of increasing H$_2$O abundances with decreasing mass, spanning generally substellar values for gas giants and stellar/superstellar for Neptunes and mini-Neptunes. However, the overall trend in H$_2$O abundances, from mini-Neptunes to hot Jupiters, is significantly lower than the mass-metallicity relation for carbon in the solar system giant planets and similar predictions for exoplanets. On the other hand, the Na and K abundances for the gas giants are stellar or superstellar, consistent with each other, and generally consistent with the solar system metallicity trend. The H$_2$O abundances in hot gas giants are likely due to low oxygen abundances relative to other elements rather than low overall metallicities, and provide new constraints on their formation mechanisms. The differing trends in the abundances of species argue against the use of chemical equilibrium models with metallicity as one free parameter in atmospheric retrievals, as different elements can be differently enhanced., Accepted for publication in The Astrophysical Journal Letters

Atmospheric retrievals of exoplanetary transmission spectra provide important constraints on various properties such as chemical abundances, cloud/haze properties, and characteristic temperatures, at the day-night atmospheric terminator. To date, most spectra have been observed for giant exoplanets due to which retrievals typically assume H-rich atmospheres. However, recent observations of mini-Neptunes/super-Earths, and the promise of upcoming facilities including JWST, call for a new generation of retrievals that can address a wide range of atmospheric compositions and related complexities. Here we report Aurora, a next-generation atmospheric retrieval framework that builds upon state-of-the-art architectures and incorporates the following key advancements: a) a generalised compositional retrieval allowing for H-rich and H-poor atmospheres, b) a generalised prescription for inhomogeneous clouds/hazes, c) multiple Bayesian inference algorithms for high-dimensional retrievals, d) modular considerations for refraction, forward scattering, and Mie-scattering, and e) noise modeling functionalities. We demonstrate Aurora on current and/or synthetic observations of hot Jupiter HD209458b, mini-Neptune K218b, and rocky exoplanet TRAPPIST1d. Using current HD209458b spectra, we demonstrate the robustness of our framework and cloud/haze prescription against assumptions of H-rich/H-poor atmospheres, improving on previous treatments. Using real and synthetic spectra of K218b, we demonstrate the agnostic approach to confidently constrain its bulk atmospheric composition and obtain precise abundance estimates. For TRAPPIST1d, 10 JWST NIRSpec transits can enable identification of the main atmospheric component for cloud-free CO$_2$-rich and N$_2$-rich atmospheres, and abundance constraints on trace gases including initial indications of O$_3$ if present at enhanced levels ($\sim$10-100x Earth levels)., Accepted for publication in ApJ

We present an optical-to-infrared transmission spectrum of the inflated sub-Saturn KELT-11b measured with the Transiting Exoplanet Survey Satellite (TESS), the Hubble Space Telescope (HST) Wide Field Camera 3 G141 spectroscopic grism, and the Spitzer Space Telescope (Spitzer) at 3.6 $\mu$m, in addition to a Spitzer 4.5 $\mu$m secondary eclipse. The precise HST transmission spectrum notably reveals a low-amplitude water feature with an unusual shape. Based on free retrieval analyses with varying molecular abundances, we find strong evidence for water absorption. Depending on model assumptions, we also find tentative evidence for other absorbers (HCN, TiO, and AlO). The retrieved water abundance is generally $\lesssim 0.1\times$ solar (0.001--0.7$\times$ solar over a range of model assumptions), several orders of magnitude lower than expected from planet formation models based on the solar system metallicity trend. We also consider chemical equilibrium and self-consistent 1D radiative-convective equilibrium model fits and find they too prefer low metallicities ($[M/H] \lesssim -2$, consistent with the free retrieval results). However, all the retrievals should be interpreted with some caution since they either require additional absorbers that are far out of chemical equilibrium to explain the shape of the spectrum or are simply poor fits to the data. Finally, we find the Spitzer secondary eclipse is indicative of full heat redistribution from KELT-11b's dayside to nightside, assuming a clear dayside. These potentially unusual results for KELT-11b's composition are suggestive of new challenges on the horizon for atmosphere and formation models in the face of increasingly precise measurements of exoplanet spectra., Comment: Accepted to The Astronomical Journal. 31 pages, 20 figures, 7 tables

Ultra hot jupiters (UHJs), giant exoplanets with equilibrium temperatures above 2000 K, are ideal laboratories for studying metal compositions of planetary atmospheres. At these temperatures the thermal dissociation of metal-rich molecules into their constituent elements makes these atmospheres conducive for elemental characterisation. Several elements, mostly ionized metals, have been detected in UHJs recently using high resolution transit spectroscopy. Even though a number of neutral transition metals (e.g., Fe, Ti, V, Cr) are expected to be strong sources of optical/NUV opacity and, hence, influence radiative processes in the lower atmospheres of UHJs, only Fe I has been detected to date. We conduct a systematic search for atomic species in the UHJ WASP-121 b. Using theoretical models we present a metric to predict the atomic species likely to be detectable in such planets with high resolution transmission spectroscopy. We search for the predicted species in observations of WASP-121 b and report the first detections of neutral transition metals Cr I and V I in an exoplanet at 3.6 $\sigma$ and 4.5 $\sigma$, respectively. We confirm previous detections of Fe I and Fe II. Whereas Fe II was detected previously in the NUV, we detect it in the optical. We infer that the neutral elements Fe I, V I, and Cr I are present in the lower atmosphere, as predicted by thermochemical equilibrium, while Fe II is a result of photoionisation in the upper atmosphere. Our study highlights the rich chemical diversity of UHJs., Comment: Accepted for publication in ApJL

Exoplanets with relatively clear atmospheres are prime targets for detailed studies of chemical compositions and abundances in their atmospheres. Alkali metals have long been suggested to exhibit broad wings due to pressure broadening, but most of the alkali detections only show very narrow absorption cores, probably because of the presence of clouds. We report the strong detection of the pressure-broadened spectral profiles of Na, K, and Li absorption in the atmosphere of the super-Neptune WASP-127b, at 4.1$\sigma$, 5.0$\sigma$, and 3.4$\sigma$, respectively. We performed a spectral retrieval modeling on the high-quality optical transmission spectrum newly acquired with the 10.4 m Gran Telescopio Canarias (GTC), in combination with the re-analyzed optical transmission spectrum obtained with the 2.5 m Nordic Optical Telescope (NOT). By assuming a patchy cloudy model, we retrieved the abundances of Na, K, and Li, which are super-solar at 3.7$\sigma$ for K and 5.1$\sigma$ for Li (and only 1.8$\sigma$ for Na). We constrained the presence of haze coverage to be around 52%. We also found a hint of water absorption, but cannot constrain it with the global retrieval owing to larger uncertainties in the probed wavelengths. WASP-127b will be extremely valuable for atmospheric characterization in the era of James Webb Space Telescope., Comment: 14 pages, 11 figures, accepted for publication in A&A on May 18, 2018