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The study of the pre-Mesozoic geological history of NE Mexico offers the opportunity to reconstruct the processes that occurred at the NW margin of Gondwana. The Huizachal–Peregrina Anticlinorium, which is located west of Ciudad Victoria (Tamaulipas) is a regional structure produced during the Cretaceous–Palaeogene Laramide Orogeny. Its eroded core exposes Precambrian and Palaeozoic units that together comprise the Sierra Madre Oriental basement. These units are the Neoproterozoic metamorphic Novillo Complex, the Ordovician Peregrina Tonalite, the metamorphic Pennsylvanian Granjeno Complex, and the sedimentary Silurian–Permian Tamatan Group. Aserradero Rhyolite belongs to the Tamatan Group, occurring between the siliciclastic deposits of the Early Mississippian Vicente Guerrero and the Pennsylvanian Del Monte Formations. The studied rhyolites display geochemical characteristics corresponding to high-K, low-Sr, and S-type granitoid rocks that may have been produced by upper-crustal anatexis from a source similar to that of the Novillo Complex. New LA-ICP-MS U–Pb geochronological analysis on zircons separated from the Aserradero Rhyolite yielded Early to Middle Mississippian crystallisation ages of 347.8 ± 2.7 Ma and 340.7 ± 3.6 Ma, confirming that this acidic unit is in its original stratigraphic position despite the pervasive deformation of the Tamatan Group. Based on the correlation with other Carboniferous–Early Permian magmatic complexes in Mexico and Central America, it is suggested that the Aserradero Rhyolite represents an early stage of a precollisional Carboniferous–Permian peri-Gondwanan arc, occurring also in the Las Delicias, Oaxaquia, the Acatlan Complex, the Maya Block, as well as in the buried crystalline basement along the Western Gulf of Mexico. The assembly of the Precambrian and Palaeozoic basement units from the Huizachal–Peregrina Anticlinorium were integrated with the Ciudad Victoria Block, which was dismembered from Oaxaquia and their peripheral units during the Upper-Jurassic Gulf of Mexico opening.

In the last few years, the effectiveness of nanoscale zero-valent iron (nZVI) as a treatment for polluted waters and soils has been widely studied. However, little data are available on its efficacy for metal immobilization at low and moderate doses. In this study, the effectiveness of two doses of commercial nZVI (1 and 5%) to immobilize Cu and/or Ni in water and acidic soil samples was evaluated. The influence of the nanoremediation technology on iron availability, physico-chemical soil properties and soil phytotoxicity was also assessed. The results show that the effectiveness of nZVI to immobilize Cu and Ni in water and soil samples was determined by the dose of the nanomaterial and the presence of both metals. Nickel immobilization was significantly decreased by the presence of Cu but the opposite effect was not observed. nZVI showed better immobilization capacity in water than in soil samples. In water, the dose of 5% completely removed both metals, whereas at a lower dose (1%) the percentage of immobilized metal decreased, especially for Ni in Cu + Ni samples. In soil samples, 5% nZVI was more effective in immobilizing Ni than Cu, with a 54% and 21% reduction of leachability, respectively, in single contaminated samples. In Cu + Ni soil samples, nZVI treatment led to a significant decrease in Ni immobilization, similar to that observed in water samples. The application of nZVI induced a dose-dependent increase in available Fe—a relevant effect in the context of soil rehabilitation. Germination assays of Medicago sativa and Vicia sativa seeds revealed that treatment with nZVI did not induce phytotoxicity under the experimental conditions tested, and that the phytotoxicity induced by Ni decreased significantly after the treatment. Thus, the use of nZVI emerges as an interesting option for Cu and/or Ni immobilization in water samples. The effectiveness of nZVI to remove Cu from acidic soil samples was moderate, while for Ni it was strongly dependent on the presence of Cu. These observations therefore indicate that the results in water samples cannot be extrapolated to soil samples.

Vascular cambium, a lateral plant meristem, is a central producer of woody biomass. Although a few transcription factors have been shown to regulate cambial activity1, the phenotypes of the corresponding loss-of-function mutants are relatively modest, highlighting our limited understanding of the underlying transcriptional regulation. Here, we use cambium cell-specific transcript profiling followed by a combination of transcription factor network and genetic analyses to identify 62 new transcription factor genotypes displaying an array of cambial phenotypes. This approach culminated in virtual loss of cambial activity when both WUSCHEL-RELATED HOMEOBOX 4 (WOX4) and KNOTTED-like from Arabidopsis thaliana 1 (KNAT1; also known as BREVIPEDICELLUS) were mutated, thereby unlocking the genetic redundancy in the regulation of cambium development. We also identified transcription factors with dual functions in cambial cell proliferation and xylem differentiation, including WOX4, SHORT VEGETATIVE PHASE (SVP) and PETAL LOSS (PTL). Using the transcription factor network information, we combined overexpression of the cambial activator WOX4 and removal of the putative inhibitor PTL to engineer Arabidopsis for enhanced radial growth. This line also showed ectopic cambial activity, thus further highlighting the central roles of WOX4 and PTL in cambium development. The vascular cambium contains meristem cells that produce secondary xylem and phloem in the stems and roots of many plants. Its activity largely determines wood formation. Now, a genome-wide transcript profiling of Arabidopsis thaliana root cambium is presented to unlock the complex network that regulates cambium development and activity.

In the last decade, several laboratory-scale experiments have shown the use of nanoscale zero-valent iron (nZVI) to be effective in reducing metal(loid) availability in polluted soils. The present study evaluates the capacity of nZVI for reducing the availability of As and Hg in brownfield soils at a pilot scale, and monitors the stability of the immobilization of these contaminants over a 32 month period. To the best of our knowledge, this is the first study to apply nZVI to metal(loid)-polluted soils under field conditions. Two sub-areas (A and B) that differed in pollution load were selected, and a 5 m2 plot was treated with 2.5% nZVI (by weight) in each case (Nanofer 25S, NanoIron). In sub-area A, which had a greater degree of pollution, a second application was performed eight months after the first application. Overall, the treatment significantly reduced the availability of both As and Hg, after only 72 h, although the effectiveness of the treatment was highly dependent on the degree of initial contamination. Sub-area B (with a lower level of pollution) showed the best and most stable immobilization results, with As and Hg in toxicity characteristics leaching procedure (TCLP) extracts decreasing by 70% and 80%, respectively. In comparison, the concentrations of As and Hg in sub-area A decreased by 65% and 50%, respectively. Based on our findings, the use of nZVI at a dose of 2.5% appears to be an effective approach for the remediation of soils at this brownfield site, especially in sub-area B. For sub-area A, a higher dose of nZVI—or its use in combination with other remediation strategies—should be tested.

The Huizachal–Peregrina Anticlinorium basement of the Sierra Madre Oriental in north-eastern (NE) Mexico comprises a wide variety of Precambrian and Paleozoic units. A granitic unit, described in this work as the Peregrina Tonalite (PTo), intruded the Neoproterozoic Novillo Gneiss, which is the northernmost expression of the Oaxaquia microcontinent. In contrast, the PTo’s contact with the Carboniferous Granjeno Schist is tectonic along vertical faults with a strike-slip component. This Paleozoic lithodeme is part of the Granjeno–Acatlan Belt. The PTo has been described as an orphaned block associated with an enigmatic Carboniferous magmatic arc located along the north-western (NW) margin of Gondwana. In this study, new U–Pb LA–ICP–MS data from PTo zircons included a youngest Late Ordovician (Katian stage) population at 448.8 ± 2.9 Ma, interpreted as the crystallisation age, and an oldest Grenvillian population interpreted as the potential age of its protolith. Additionally, major and trace element concentrations and ratios indicate a link to a continental arc that developed along the NW margin of Gondwana. Given this proposed arc’s age and position, a comprehensive model for the development of the NE Mexican basement without the involvement of exotic or orphaned terranes is now proposed. The PTo outcropping near Ciudad Victoria, Tamaulipas, is interpreted to be part of a previously unreported magmatic arc in NE Mexico established during the Late Ordovician, herein described as the Peregrina–Mochonian Orogeny. It represents an extension of the South American Famatinian arc into Mexico.

The effect of organic matter on the As bioavailability in soils and thus on phytoremediation processes is still controversial. The objective of the present study was to evaluate the combined effect of compost and microorganisms from rhizosphere on the tolerance of barley and wheat plants to soil polluted with different concentrations of As for the application on phytoremediation strategies. A greenhouse experiment was performed using soil artificially contaminated with As at two doses. A compost obtained from sewage sludge composted with pruning waste was used (40 t/ha) as amendment. Plants were grown until the end of their growing cycle. Arsenic uptake and plant physiological and biochemical parameters as well as As availability and physicochemical properties in soil samples were analyzed. The impact of compost addition on the structure and diversity of the microbial communities of the rhizosphere was also evaluated using PCR-DGGE. Compost application induced a different behavior in both species. Compared to wheat and irrespective of As doses, in compost amended soils, barley plants showed an enhanced As translocation to the aerial part. The different bacterial communities structure found for each species, according to the PCR-DGGE cluster analysis, suggested that specific rhizobacteria of barley may have increased As bioavailability, and would therefore enhance its translocation to aerial parts. Both species could be used for phytoremediation proposes of As-polluted soils, and specifically, barley would be an interesting option for phytoextraction due to its higher biomass and high As translocation when compost is applied to As-polluted soil.

Tree bark is a highly specialized array of tissues that plays important roles in plant protection and development. Bark tissues develop from two lateral meristems; the phellogen (cork cambium) produces the outermost stem-environment barrier called the periderm, while the vascular cambium contributes with phloem tissues. Although bark is diverse in terms of tissues, functions and species, it remains understudied at higher resolution. We dissected the stem of silver birch (Betula pendula) into eight major tissue types, and characterized these by a combined transcriptomics and metabolomics approach. We further analyzed the varying bark types within the Betulaceae family. The two meristems had a distinct contribution to the stem transcriptomic landscape. Furthermore, inter- and intraspecies analyses illustrated the unique molecular profile of the phellem. We identified multiple tissue-specific metabolic pathways, such as the mevalonate/betulin biosynthesis pathway, that displayed differential evolution within the Betulaceae. A detailed analysis of suberin and betulin biosynthesis pathways identified a set of underlying regulators and highlighted the important role of local, small-scale gene duplication events in the evolution of metabolic pathways. This work reveals the transcriptome and metabolic diversity among bark tissues and provides insights to its development and evolution, as well as its biotechnological applications. Published version

Thermal load imposed on the ground by the foundations of some singular buildings may produce variations in geochemistry conditions. In soils containing soluble salts, such as gypsum, their dissolution/precipitation rates may be modified, triggering ground settlement as well as angular distortion of building foundations. This paper examines these processes for the case of the Central Storage Facility for high-level radioactive waste planned in Spain. This facility would impose a thermal load over a long period of time due to the disposal of spent nuclear fuel. A numerical model, including the equations for describing the dissolution/precipitation process, as well as the hydrogeological, thermal, chemical, and geomechanical changes in the ground caused by the construction and operation of the facilities, is proposed. The model focuses on the response of the building foundation under different hypothesis of thermal loading underneath the building. Comsol Multiphysics software was used for solving the resulting partial differential equations by the finite element method. This analysis concludes that moderate thermal loading of the ground would develop in the Case Study, with negligible mechanical effect on the foundation., La carga térmica impuesta al suelo por los cimientos de algunos edificios singulares puede producir variaciones en las condiciones geoquímicas . En suelos que contienen sales solubles, como el yeso , sus tasas de disolución/precipitación pueden modificarse, provocando asentamientos del suelo y distorsión angular de los cimientos de los edificios. Este artículo examina estos procesos para el caso de la Instalación Central de Almacenamiento de residuos radiactivos de alta actividad.prevista en España. Esta instalación impondría una carga térmica durante un largo período de tiempo debido a la eliminación del combustible nuclear gastado. Se propone un modelo numérico que incluye las ecuaciones para describir el proceso de disolución/precipitación, así como los cambios hidrogeológicos, térmicos, químicos y geomecánicos en el suelo provocados por la construcción y operación de las instalaciones. El modelo se centra en la respuesta de los cimientos del edificio bajo diferentes hipótesis de carga térmica debajo del edificio. Se utilizó el software Comsol Multiphysics para resolver las ecuaciones diferenciales parciales resultantes mediante el método de elementos finitos. Este análisis concluye que se desarrollaría una carga térmica moderada del suelo en el caso de estudio, con un efecto mecánico insignificante en la cimentación.

The journal of physical chemistry / C 124(46), 25645 - 25656 (2020). doi:10.1021/acs.jpcc.0c08670, Amorphous calcium carbonate (ACC) is an essential component present during the early stages of biomineralization of many calcifying organisms, which is used as a precursor of crystalline calcium carbonate phases. Here, we performed X-ray photon correlation spectroscopy experiments on ACC which show that the amount of adsorbed water has a strong control over its diffusive dynamics. Results of crystallization experiments under conditions of controlled humidity indicate that the adsorbed water is enough to spark crystallization of calcite. A direct proportionality is found between the relative humidity of the environment and the final size of the calcite crystals. Different hypotheses are made to explain this result, with the confinement within the amorphous matrix being the main suspect of controlling the size of the crystallites. Control of water activity and water content is, therefore, a possible way to regulate biomineral crystallinity both in nature and for the design of functional biomimetic materials., Published by Soc., Washington, DC

Nanoscale zero valent iron (nZVI) particles obtained by different methods differ in their structure, which lead to different reactivity, and therefore a likely difference in the remediation efficiency. The present study compares the effectiveness of three commercial ZVI nanoparticles to immobilize As and Hg in two soils (A and B) collected from a brownfield highly contaminated by mining and metallurgy activities. Scarce data are available on the effectiveness of nZVI for Hg immobilization in soil. Two commercial nZVI slurries from Toda (RNIP and RNIP-D) and one from Nano Iron (25S) were used at different doses (1, 5 and 10%). The metal(loid) availability and mobility was evaluated with the TCLP test and Tessier extraction procedure. The influence of nZVI application on As and Hg speciation was also evaluated as well as its impact on soil pH, electrical conductivity and soil phytotoxicity to vetch germination. The three commercial nZVI particles significantly reduced As and Hg availability in the two soils studied, which led to a decrease in soil phytotoxicity. At the dose of 5% of nZVI a decrease of exchangeable-As higher than 70% was observed for both soils, whereas in the case of Hg, a higher dose of nZVI (10%) was necessary to achieve reductions of exchangeable-Hg between 63 and 90% depending on the type of nZVI and soil. No impact on soil pH and electrical conductivity was observed. The effectiveness of metal(loid) immobilization depended on type of nZVI, soil properties and metal(loid) characteristics. Nanoparticles from Nano Iron showed better results for As immobilization whereas RNIP nanoparticles were more effective for Hg. Overall, 25S at the dose of 5% resulted more effective than RNIP nanoparticles for the reduction of exchangeable-As (in the range of 6-14%), whereas RNIP and RNIP-D were 10 and 13% more effective, respectively, for the reduction of exchangeable-Hg at the dose of 10% in soil B. Thus, nZVI can be used for the remediation of highly As and Hg polluted soils, although previous experiments at lab scale are necessary to determine the most viable type of nZVI and its dose.

In this work we exhibit flexibility phenomena for some (countable) groups acting by order preserving homeomorphisms of the line. More precisely, we show that if a left orderable group admits an amalgam decomposition of the form G=Fn∗ZFm where n+m⩾3, then every faithful action of G on the line by order preserving homeomorphisms can be approximated by another action (without global fixed points) that is not semi-conjugated to the initial action. We deduce that LO(G), the space of left orders of G, is a Cantor set. In the special case where G=π1(Σ) is the fundamental group of a closed hyperbolic surface, we found finer techniques of perturbation. For instance, we exhibit a single representation whose conjugacy class in dense in the space of representations. This entails that the space of representations without global fixed points of π1(Σ) into Homeo+(R) is connected, and also that the natural conjugation action of π1(Σ) on LO(π1(Σ)) has a dense orbit.

The effectiveness of single- and multi-metal(loid) immobilization of As, Cd, Cr, Pb and Zn using different doses of nanoscale zero-valent iron (nZVI) was evaluated and compared in two different soils, a calcareous and an acidic one. The effectiveness of nZVI to immobilize metal(loid)s in soil strongly depended on the metal characteristics, soil properties, dose of nZVI and presence of other metal(loid)s. In the case of single contamination, this nanoremediation strategy was effective for all of the metal(loid)s studied except for Cd. When comparing the two soils, anionic metal(loid)s (As and Cr) were more easily retained in acidic soil, whereas cationic metal(loid)s (Cd, Pb and Zn), were immobilized more in calcareous soil. In multi-metal(loid) contaminated soils, the presence of several metal(loid)s affected their immobilization, which was probably due to the competitive phenomenon between metal(loid) ions, which can reduce their sorption or produce synergistic effects. At 10% of nZVI, As, Cr and Pb availability decreased more than 82%, for Zn it ranged between 31 and 75% and for Cd between 13 and 42%. Thus, the application of nZVI can be a useful strategy to immobilize As, Cr, Pb and Zn in calcareous or acidic soils in both single- or multi-metal(loid) contamination conditions.

The remarkable vertical and radial growth observed in tree species, encompasses a major physical challenge for wood forming tissues. To compensate with increasing size and weight, cambium-derived radial growth increases the stem width, thereby supporting the aerial body of trees. This feedback appears to be part of a so-called “proprioception” (1, 2) mechanism that controls plant size and biomass allocation. Yet, how trees experience or respond to mechanical stress derived from their own vertical loading, remains unknown. Here, we combined two strategies to dissect the proprioceptive response in birch. First, we show that in response to physical loading, trees promote radial growth with different magnitudes along the stem. Next, we identified a mutant cultivar (B. pubescens cv. Elimäki) in which the main stem shows normal vertical development, but collapses after three months. By inducing precocious flowering, we generated a backcrossed population (BC1) by producing two generations in 4 years. In his scheme, we uncovered a recessive trait (eki) that segregates and genetically maps with a Mendelian monogenic pattern. Unlike WT,ekiis resistant to vertical mechanical stimulation. However,ekiresponds normally to the gravitropic stimulus by making tension wood. Before the collapse, cell size inekiis compromised resulting in radial growth defects, depending on stem height. Cell walls of developing xylem and phloem tissues have delayed differentiation ineki, and its tissues are softer compared to WT as indicated by atomic force microscopy (AFM). The transcriptomic profile ofekihighlighted the overlap with that of theArabidopsisresponse to touch. Taken together, our results suggest that the mechanical environment and cell wall properties of developing woody tissues, can significantly affect the growth responses to vertical loading thereby compromising their proprioceptive capacity. Additionally, we introduce a fast forward genetics strategy to dissect complex phenotypes in trees.

The upwelling cores on the Caribbean Colombian coasts are mainly located at the Peninsula de la Guajira and Cabo de la Aguja. We used monthly averaged Moderate Resolution Imaging Spectroradiometer (MODIS) sea surface temperature as the only information to build up a prediction model for the upwelling events. This comprised two steps: (i) the reduction of the complexity by means of the Karhunen&ndash, Lo&egrave, ve transform and (ii) a prediction model of time series. Two prediction models were considered: (a) a parametric autoregressive-moving average (ARMA) time series from the Box&ndash, Jenkins methodology and (b) a harmonic synthesis model. The harmonic synthesis also comprised of two steps: the maximum entropy spectral analysis and a least-squares harmonic analysis on the set of frequencies. The parametric ARMA time series model failed at the time of prediction with a very narrow range, and it was quite difficult to apply. The harmonic synthesis allowed prediction with a horizon of six months with a correlation of about 0.80. The results can be summarized using the time series of the weights of the different oscillation modes, their spatial structures with the nodal lines, and a high confidence model with a horizon of prediction of about four months.

Following previous work of the second author, we establish more properties of groups of circle homeomorphisms which admit invariant laminations. In this paper, we focus on a certain type of such groups-so-called pseudo-fibered groups, and show that many 3-manifold groups are examples of pseudo-fibered groups. We then prove that torsion-free pseudo-fibered groups satisfy a Tits alternative. We conclude by proving that a purely hyperbolic pseudo-fibered group acts on the 2-sphere as a convergence group. This leads to an interesting question if there are examples of pseudo-fibered groups other than 3-manifold groups., 15 pages, 5 figures. A minor revision has been done based on the referee's comments. To appear in Journal of Group Theory

The quality of three types of treated sludges (sludge from the paper recycling industry, and sewage sludge treated by composting with pruning waste and thermally dried) was assessed in this work. The amendments were physicochemically characterized and evaluated for their microbiological quality and for contamination with pollutants. All three organic amendments showed an absence of pathogens, so they are microbially suitable for agricultural use. The pollutants studied in the amendments included eight heavy metals and 83 organic compounds. Heavy metals, pesticides, polycyclic aromatic hydrocarbons, octylphenol, bisphenol A, and parabens were found in the organic amendments. The amount and type of contaminants depended on the sample sources and differed between samples from a single origin. The presence of some of the pollutants found has not been previously reported in organic amendments. The germination assay showed that these amendments may be applied to soil in controlled doses. As far as we know, this is the first reported study that has evaluated a great variety of pollutants (heavy metals, pesticides, persistent and emerging organic pollutants) in sludge from the recycled paper industry; moreover, studies in other waste products in which such a broad range of pollutants has been evaluated have been scarce until now due to the complexity of these matrices. © 2016 Taylor & Francis Group, LLC.

Commercial magnetite nanoparticles (NPs) were used to immobilize As and organic pollutants, mainly PAHs, in a polluted soil. The composition, structure and morphology of the NPs were examined by means of electron microscopy, X-ray analysis, infrared spectroscopy, dynamic light scattering, thermogravimetric analysis, and magnetic property determination. To evaluate the immobilization of As and organic pollutants, soil subsamples were treated with the magnetite NPs at different doses (0.2%, 1%, 2% and 5%). The availability of As was then examined by the TCLP test and the Tessier sequential extraction procedure, whereas TPH and PAHs were measured by GC–MS. Notable results for As immobilization were achieved at a dose of 1% NPs (42.5% decrease in As, TCLP test), although the best result was obtained at the highest dose of 5% (92.3% decrease in As, TCLP test) without significant variations in As speciation. Regarding organic pollutants, a decrease in TPH and PAHs content was detected even at the lowest dose of NPs tested (49% and 89% respectively). The treatments had no negative effects on soil parameters such as soil pH and electrical conductivity. In turn, the increase in Fe availability after application of NPs was insignificant whereas soil phytotoxicity assessed by germination test was reduced. In conclusion, the use of magnetite NPs opens up new nanoremediation options to treat soils affected by both organic and metal(loid) pollution.

This paper presents a simplified method for the study of the soil-structure interaction problem for isolated footings on soils subjected to water content-related volume changes. The method is based on the 2D modelling of thermo-hydro-mechanical processes occurring in the soil and the soil–atmosphere interface, the calculation of the soil-footing system stiffness and the modelling of the structure. The idealization of soil-structure interaction from an equivalent springs model, obtained from the above characteristics, allows the movements changes in time of the foundations to be obtained. These in turn can be used for evaluation of building damage related to angular distortion among foundations.

The capacity of two iron-based nanomaterials, namely goethite nanospheres (nGoethite) and zero valent iron nanoparticles (nZVI), to immobilize As in a polluted soil was evaluated and compared. The composition and morphology of the products were studied by energy dispersive X-ray analysis and transmission electron microscopy, while zeta potential and average sizes were determined by dynamic light scattering. To assess As immobilization, soil subsamples were treated with nGoethite or nZVI at a range of Fe doses (0.5%, 2%, 5% and 10%) and then studied by the TCLP test and the Tessier sequential extraction procedure. The influence of both nanoparticles on As speciation was determined, as was impact on soil pH, electrical conductivity, Fe availability and phytotoxicity (watercress germination). For nZVI, notable results were achieved at a dose of 2% (89.5% decrease in As, TCLP test), and no negative effects on soil parameters were detected. Indeed, even soil phytotoxicity was reduced and only at the highest dose was a slight increase in As3+ detected. In contrast, excellent results were obtained for nGoethite at the lowest dose (0.2%) (82.5% decrease in As, TCLP test); however, soil phytotoxicity was increased at higher doses, probably due to a marked enhancement of electrical conductivity. For both types of nanoparticle, slight increases in Fe availability were observed. Thus, our results show that both nZVI and nGoethite have the capacity to effectively immobilize As in this brownfield. The use of lower doses of nGoethite emerges as a promising soil remediation strategy for soils affected by As pollution.

Lead is one of the most potentially toxic metals present in soils. In situ Pb immobilization techniques reducing its bioavailability to soil organisms are of increasing interest. The present work compares the effectiveness of nanoscale zero-valent iron (nZVI), compost, and phosphate for Pb immobilization in an acidic, artificially polluted soil after different contact times (15 and 45 days). The availability and mobility of Pb were evaluated by the Tessier extraction procedure and the toxicity characteristics leaching procedure (TCLP). The impact on soil properties and soil phytotoxicity was also evaluated. The phosphate was the most effective treatment in all sampling times, reaching Pb reductions in more available fractions of 72%, followed by compost (40%) and nZVI (32%). Comparing the two sampling times, a significant reduction of available Pb in phosphate-treated soils was observed at a longer contact time. Soil properties changed depending on the treatment. In general, the application of compost improved the soil fertility, soils treated with nZVI showed an increase of pH and available sodium and iron concentration, and the treatment with phosphate increased available phosphorus concentration in soil, but was less than that obtained by the compost treatment. Regarding the soil phytotoxicity, Vicia sativa showed moderate phytotoxicity to untreated Pb-polluted soils, and the different treatments decreased it. In conclusion, at the experimental conditions, the use of phosphate resulted as more effective than compost and nZVI for reducing Pb availability in an acidic soil. Longer-term assays are necessary to evaluate the stability of the process.

The Precambrian metamorphic basement exposed in the eroded core of the Huizachal-Peregrina Anticlinorium (Cd. Victoria, Mexico) is described in this contribution as Novillo Metamorphic Complex (NMC). Based on field relations, modal content, whole rock geochemistry and Nd-isotopic ratios is possible to recognize two major units: (a) Metaigneous Unit (MIU) and (b) Metasedimentary Unit (MSU). The MIU is subdivided into the Old Suite, constituted by (a) felsic gneisses from Novillo canyon, (b) felsic gneisses from Peregrina canyon, (c) metagranites, (d) mafic gneisses, and (d) migmatites; and the AMCG Suite, composed by (a) meta-anorthosites, (b) metagranite-gabbro intercalations, (c) metacharnockites, (d) garnet-rich metaferrodiorite dykes, and (e) metanelsonites. The MSU is represented by (a) meta-arkose – amphibolite intercalations and (b) calcsilicate marbles. Tectonic discrimination diagrams based on linear discriminant analysis of natural logarithm transformed ratios of elements show an island arc tectonic setting for the MIU. Nd isotopic ratios show crustal residence TDM ages of 1.49–1.44 Ga for the Old Suite (2 samples) and 1.63–1.33 Ga for the AMCG Suite (7 samples). The MSU have TDM between 1.39 a 1.25 Ga (3 samples) that support the interpretation that the protoliths were possibly deposited in a basin with sediment input from the younger MIU members. These deposits were later thrusted over MIU rather than intruded, and together metamorphosed under granulite facies conditions by the ca. 1.0 Ga Zapotecan orogeny. However, since the metaferrodioritic bodies cut discordantly the meta-anorthosites fabric, they represent a younger tectonothermal event, not yet described for the NMC.

We show that certain orderable groups admit no isolated left orders. The groups we consider are cyclic amalgamations of a free group with a general orderable group, the HNN extensions of free groups over cyclic subgroups, and a particular class of one-relator groups. In order to prove the results about orders, we develop perturbation techniques for actions of these groups on the line., 17 pages, 6 figures

The geochemistry of the metavolcanic rocks from the Granjeno Schist in northeastern Mexico indicates an origin in different tectonic environments: mid-ocean ridge and ocean island. High ratios of Hf/Th and Th/Nb (4.4-14 and 0.08-0.15), low ratios of LaN/YbN and LaN/SmN (0.74-1.7 and 0.60-1.4) and depleted LREE patterns in metabasalt display mid-ocean ridge characteristics. In contrast, the pattern of trace-element ratios and REEs in metabasalt and metapillow lava 60km to the west indicates a magma source with ocean-island basalt characteristics. Both areas were metamorphosed during the Late Carboniferous (300±4Ma). Estimated metamorphic conditions deduced from white mica and chlorite compositions, distinguish greenschist facies (350°C and 4kbar) for the mid-ocean ridge basalt, and prehnite-pumpellyite facies (250°C and 2.5kbar) for the ocean-island-type basalt. This metamorphism took place at an active continental margin during Pennsylvanian time. Our new tectonic model, which differs from earlier models, suggests that the origin of the Granjeno Schist is related to a subduction zone located at the western margin of Pangaea, active after Laurentia-Gondwana collision. (Less)

The Granjeno Schist is a meta-volcanosedimentary upper Paleozoic complex in northeastern Mexico. We suggest different tectonic settings for metamorphism of its serpentinite and talc-bearing rocks based on petrographic and geochemical compositions. According to the REE ratios (LaN/YbN = 0.51–20.0 and LaN/SmN = 0.72–9.1) and the enrichment in the highly incompatible elements Cs (0.1 ppm), U (2.8 ppm), and Zr (60 ppm) as well as depletion in Ba (1 – 15 ppm), Sr (1–184ppm),Pb(0.1–14ppm),andCe(0.1–1.9ppm)the rocks have mid-ocean ridge and subduction zones characteristics.TheserpentinitecontainsAl-chromite,ferrian chromiteandmagnetite.TheAl-chromiteischaracterized byCr#of0.48to0.55suggestingaMORBorigin,andCr#of 0.93 to 1.00 for the ferrian chromite indicates a prograde metamorphism.Weproposeatleasttwoserpentinization stagesoflithosphericmantlefortheultramaficrockofthe GranjenoSchist,(1)afirstinanocean-floorenvironment atsub-greenschisttogreenschistfaciesconditionsand(2) later a serpentinization phase related to the progressive replacement of spinel by ferrian chromite and magnetite atgreenschisttolowamphibolitefaciesconditionsduring regional metamorphism. The second serpentinization phase took place in an active continental margin during the Pennsylvanian. We propose that the origin of the ultramaficrocksisrelated toanobductionandaccretional eventatthewesternmarginofPangea. Keywords: ultramafic rocks; serpentinite; Granjeno Schist;northeasternMexico,Gondwana,Pangea

The present study investigates the impact of the nanoremediation treatment on soil recovery as evaluated by the development of barley plants. Highly As-polluted brownfield soil was treated with nanoscale zero-valent iron (nZVI) commercial suspension at two doses (1% and 10%). Barley plants were cultivated in treated and untreated soils in a growth chamber, and the As, Fe, and nutrients uptake were determined. The efficacy of As immobilization was evaluated according to the toxicity characteristics leaching procedure (TCLP) as well as using a sequential extraction procedure. The application of nZVI reduced the amount of As in the more available fractions and increased the amount of As in the residual fraction. The best immobilization results were obtained for the highest dose of nZVI (10%). In turn, the lower availability of As in nZVI-treated soils, particularly at the dose of 10%, stimulated the development of the barley plants and decreased the As uptake. Neither an important increase of available Fe nor negative impact on soil physico-chemical and biological properties were observed. Thus, our results show that the use of nZVI could be an adequate strategy to recover the land use in As polluted soils.

Electrokinetic processes provide the basis of a range of very interesting techniques for the remediation of polluted soils. These techniques consist of the application of a current field in the soil that develops different transport mechanisms capable of mobilizing several types of pollutants. However, the use of these techniques could generate nondesirable effects related to the geomechanical behavior of the soil, reducing the effectiveness of the processes. In the case of the remediation of polluted soils with plasticity index higher than 35, an excessive shrinkage can be observed in remediation test. For this reason, the continued evaporation that takes place in the sample top can lead to the development of cracks, distorting the electrokinetic transport regime, and consequently, the development of the operation. On the other hand, when analyzing silty soils, in the surroundings of injection surfactant wells, high seepages can be generated that give rise to the development of piping processes. In this article methods are described to allow a reduction, or to even eliminate, both problems., Los procesos electrocinéticos proporcionan la base de una serie de técnicas muy interesantes para la remediación de suelos contaminados. Estas técnicas consisten en la aplicación de un campo actual en el suelo que desarrolla diferentes mecanismos de transporte capaces de movilizar varios tipos de contaminantes. Sin embargo, el uso de estas técnicas podría generar efectos no deseables relacionados con el comportamiento geomecánico del suelo, reduciendo la efectividad de los procesos. En el caso de la remediación de suelos contaminados con índice de plasticidad superior a 35, se puede observar una contracción excesiva en la prueba de remediación. Por este motivo, la evaporación continuada que se produce en la parte superior de la muestra puede provocar el desarrollo de fisuras, distorsionando el régimen de transporte electrocinético y, en consecuencia, el desarrollo de la operación. Por otra parte, al analizar suelos limosos, en el entorno de los pozos de inyección de surfactante, se pueden generar altas filtraciones que dan lugar al desarrollo de procesos de tubería. En este artículo se describen métodos para permitir una reducción, o incluso eliminar, ambos problemas.

This study evaluated the effectiveness of nZVI in reducing the availability of Cd, Cr or Zn in polluted soils. The influence of this nanoremediation process on the development of barley plants as well as its impact on soil properties and the stability of the metal immobilization afterwards were also evaluated in a greenhouse experiment. The application of nZVI reduced the availability of these metals in the soil, but the effectiveness of the immobilization and its stability depended on the metal chemical characteristics. Cadmium distribution in soil fractions showed an important change after the barley crop, favoring the immobilization of Cd in RS fraction for both nZVI-treated and untreated soils. The Cr immobilization was stable over the time studied and the doses of Cr were lethal for the barley plants. In contrast, the decrease of Cr availability reached after the nZVI treatment induced a reduction of soil phytotoxicity and an improvement in the development of the plants, which were able to complete their growing period. The Zn immobilization with nZVI was stable over time, but its effectiveness was moderate, and the growth of barley plants was poorer than that observed in the cases of Cd and Cr. Thus the best results of metal immobilization with nZVI were obtained for Cr-polluted soils. There was no overall increase of Fe in barley plants from nZVI-treated soils. In relation to the soil, no negative effects on its physico-chemical properties were observed after the time exposure with nZVI. Taking into account these results we can conclude that the use of nZVI is a promising remediation strategy, and its effectiveness would be conditioned to the soil properties and the bioavailable metal concentration.