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Recent advances in the nanofabrication and modeling of metasurfaces have shown the potential of these systems in providing unprecedented control over light–matter interactions at the nanoscale, enabling immediate and tangible improvement of features and specifications of photonic devices that are becoming always more crucial in enhancing everyday life quality. In this work, we theoretically demonstrate that metasurfaces made of periodic and non-periodic deterministic assemblies of vertically aligned semiconductor nanowires can be engineered to display a tailored effective optical response and provide a suitable route to realize advanced systems with controlled photonic properties particularly interesting for sensing applications. The metasurfaces investigated in this paper correspond to nanowire arrays that can be experimentally realized exploiting nanolithography and bottom-up nanowire growth methods: the combination of these techniques allow to finely control the position and the physical properties of each individual nanowire in complex arrays. By resorting to numerical simulations, we address the near- and far-field behavior of a nanowire ensemble and we show that the controlled design and arrangement of the nanowires on the substrate may introduce unprecedented oscillations of light reflectance, yielding a metasurface which displays an electromagnetic behavior with great potential for sensing. Finite-difference time-domain numerical simulations are carried out to tailor the nanostructure parameters and systematically engineer the optical response in the VIS-NIR spectral range. By exploiting our computational-methods we set-up a complete procedure to design and test metasurfaces able to behave as functional sensors. These results are especially encouraging in the perspective of developing arrays of epitaxially grown semiconductor nanowires, where the suggested design can be easily implemented during the nanostructure growth, opening the way to fully engineered nanowire-based optical metamaterials.

The field of silicon photonics has experienced widespread adoption in the datacoms industry over the past decade, with a plethora of other applications emerging more recently such as light detection and ranging (LIDAR), sensing, quantum photonics, programmable photonics and artificial intelligence. As a result of this, many commercial complementary metal oxide semiconductor (CMOS) foundries have developed open access silicon photonics process lines, enabling the mass production of silicon photonics systems. On the other side of the spectrum, several research labs, typically within universities, have opened up their facilities for small scale prototyping, commonly exploiting e-beam lithography for wafer patterning. Within this ecosystem, there remains a challenge for early stage researchers to progress their novel and innovate designs from the research lab to the commercial foundries because of the lack of compatibility of the processing technologies (e-beam lithography is not an industry tool). The CORNERSTONE rapid-prototyping capability bridges this gap between research and industry by providing a rapid prototyping fabrication line based on deep-UV lithography to enable seamless scaling up of production volumes, whilst also retaining the ability for device level innovation, crucial for researchers, by offering flexibility in its process flows. This review article presents a summary of the current CORNERSTONE capabilities and an outlook for the future.

Fluorescence spectroscopy has been extensively investigated for disease diagnosis. In this framework, optical tissue phantoms are widely used for validating the biomedical device system in a laboratory environment outside of clinical procedures. Moreover, it is fundamental to consider that there are several scattering components and chromophores inside biological tissues and the interplay between scattering and absorption may result in a distortion of the emitted fluorescent signal. In this work, the photophysical behaviour of a set of liquid, tissue-like phantoms containing different compositions was analysed: phosphate buffer saline (PBS) was used as the background medium, low fat milk as a scatterer, Indian ink as an absorber and protoporphyrin IX (PpIX) dissolved in dimethyl formamide (DMF) as a fluorophore. We examined the collected data in terms of the impact of surfactant Tween-20 on the background medium, scattering effects and combination of scattering and absorption within a luminescent body on PpIX. The results indicated that the intrinsic emission peaks are red shifted by the scattering particles or surfactant, whilst the scattering agent and the absorbent can alter the emission intensity substantially. We corroborated that phantoms containing higher surfactant content (>0.5% Tween 20) are essential to prepare stable aqueous phantoms.

Metasurfaces made of arrays of vertically aligned semiconductor nanowires are suitable platforms for light management in optical and photonic applications. Here we report a design approach aimed at engineering the optical behavior of semiconductor nanowire ensembles randomly displaced on the substrate, in order to enhance modulation effects in their optical reflectance response. By resorting to analytical and numerical simulations we demonstrate that the combined implementation of a multi-shell layering together with a tapered designing on the individual nanowire offer new opportunities to tailor the optical reflectance oscillations in this kind of architectures. The simulation insights were compared to experimental results reported for self-assembled GaAs nanowires and GaAs/AlGaAs core-shell nanowires. The proposed approach is especially promising for epitaxially grown semiconductor nanowires, where the suggested design modifications can be easily implemented during the nanostructure growth.

Random assemblies of vertically aligned core&ndash, shell GaAs&ndash, AlGaAs nanowires displayed an optical response dominated by strong oscillations of the reflected light as a function of the incident angle. In particular, angle-resolved specular reflectance measurements showed the occurrence of periodic modulations in the polarization-resolved spectra of reflected light for a surprisingly wide range of incident angles. Numerical simulations allowed for identifying the geometrical features of the core&ndash, shell nanowires leading to the observed oscillatory effects in terms of core and shell thickness as well as the tapering of the nanostructure. The present results indicate that randomly displaced ensembles of nanoscale heterostructures made of III&ndash, V semiconductors can operate as optical metamirrors, with potential for sensing applications.

We compare the simulated optical insertion-losses and fabrication-tolerances of a micro-optical bench (MOB) for laser hybrid-integration on the 220nm Silicon-on-Insulator (SOI) photonic-platform to standard fiber-to-grating coupling. Our millimeter-scale two-dimensional finite difference time domain (2D-FDTD) simulation captures (i) aberration, (ii) reflection, (iii) diffraction, and (iv) wave-guiding effects in a single-shot and completely self-consistent way, indicating that light from a laser-diode can be coupled to the SOI photonic integrated circuit (PIC) with a 2.8dB insertion-loss at 1550nm. This insertion loss is just 1.0dB higher than for a standard Fiber-to-PIC grating-coupler, and is due to a combination of interface-reflections and aberration-effects from the micro-optical elements in the MOB. We use further 2D-FDTD simulations to investigate the alignment and manufacturing tolerances of the MOB, and show that these are compatible with practical photonic-packaging processes for mass-manufacture.

Subwavelength nanostructured surfaces are realized with self-assembled vertically-aligned InAs nanowires, and their functionalities as optical reflectors are investigated. In our system, polarization-resolved specular reflectance displays strong modulations as a function of incident photon energy and angle. An effective-medium model allows one to rationalize the experimental findings in the long wavelength regime, whereas numerical simulations fully reproduce the experimental outcomes in the entire frequency range. The impact of the refractive index of the medium surrounding the nanostructure assembly on the reflectance was estimated. In view of the present results, sensing schemes compatible with microfluidic technologies and routes to innovative nanowire-based optical elements are discussed.

We report on the optical and photo-physical properties of a fluorinated poly(p-phenylenevinylene) derivative, namely poly(2-methoxy-5-[(2-ethylhexyl)oxy]-1,4-phenylenedifluorovinylene) (MEH-PPDFV) and we compare them with those of the well-known non fluorinated reference system, poly(2-methoxy-5-[(2-ethylhexyl)oxy]-1,4-phenylenevinylene) (MEH-PPV) synthesized with the same procedure. Remarkable blue-shifts of absorption and emission spectra of MEH-PPDFV with respect to MEH-PPV are observed, due to the larger distortion from planarity of the fluorinated species. In addition, the blue-shift for optical transitions in absorption spectra is more pronounced than in emission ones, since the molecule conformation in the excited states is more planar than in the ground one. Microsecond photo-induced absorption spectra of MEH-PPDFV reveal three bands possessing spectral properties and/or kinetics different from those observed for MEH-PPV. The assignment of these transitions is provided in terms of free and trapped polarons as well of triplet excitons. Free-polarons have an intrinsic decay constant of 3 μs, while the trapping dynamics has a longer kinetics of 40 μs. The triplet exciton, instead, shows a monoexponetial decay behavior of constant about 10 μs.

Grating couplers are widely used optical interfaces in integrated photonics, especially on the Silicon-On-Insulator (SOI) platform. Their design has been optimized for coupling light between a Photonic Integrated Circuit (PIC) and a single-mode fiber, a µlens for free space transport, or even a second PIC in the same SOI platform. In this work, we co-design matching pairs of grating-couplers on distinct SOI and InP photonic platforms for optimized PIC-to-PIC coupling. By matching the scattering strengths of the two grating-couplers, we show that a PIC-to-PIC insertion loss of 3dB can be achieved. We also investigate how the design parameters impact the coupling efficiency and the bandwidth, ending up with a tolerance analysis. The proposed coupling approach between two different waveguide materials has prospective applications for the hybrid-integration of SOI and InP photonic platforms for communication technologies.

An all-polymer photonic structure constituted by a distributed Bragg reflector topped with an ultrathin fluorescent polymer film has been studied. A Bloch surface wave resonance has been exploited to improve pumping efficiency. A strongly polarization and angle dependent fluorescence signal is found with respect to the light pumping beam and the emitted wavelength. Matching the most favorable condition for the pump coupling and the collection geometry, the signal obtained from the structure appears to be two orders of magnitude larger than the one of the bare emitting film.

The “Sacra Tharrhica Project” was started by the University of Bologna in cooperation with the University of Cagliari in 2017. The aim is to obtain a 3D virtual reconstruction of all temple structures of the Punic settlement of Tharros on the central west coast of Sardinia, starting from a systematic architectural and archaeological study of the Punic and Roman phases of the buildings. The project has firstly focused on the “Monumental Temple” or “Doric half-columns Temple”. This Punic sacred area was probably monumentalized between the late 4th and 3rd centuries B.C. After the Roman conquest, it was rebuilt between the 1st century B.C. and the 1st century A.D.