Search

The research presented in this article concerns Zr&ndash, C coatings which were deposited on 304L steel by reactive magnetron sputtering from the Zr target in an Ar&ndash, C2H2 atmosphere at various acetylene flow rates, resulting in various atomic carbon concentrations in the coating. The article describes research covering the change in the antibacterial and anticorrosive properties of these coatings due to the change in their chemical and phase composition. The concentration of C in the coatings varied from 21 to 79 at.%. The coating morphology and the elemental distribution in individual coatings were characterized using field emission scanning electron microscopy with an energy-dispersive X-ray analytical system. X-ray diffraction and Raman spectroscopy were used to analyze their microstructure and phase composition. Parallel changes in the mechanical properties of the coatings were analyzed. Based on the obtained results, it was concluded that the wide possibility of shaping the mechanical properties of Zr&ndash, C coatings in combination with relatively good antibacterial properties after exceeding 50 at.% of carbon concentration in coatings and high protective potential of these coatings make them a good candidate for medical applications. In particular, corrosion tests showed the high anti-pitting potential of Zr&ndash, C coatings in the environment of artificial saliva.

To fabricate porous copper coatings on titanium, we used the process of plasma electrolytic oxidation (PEO) with voltage control. For all experiments, the three-phase step-up transformer with six-diode Graetz bridge was used. The voltage and the amount of salt used in the electrolyte were determined so as to obtain porous coatings. Within the framework of this study, the PEO process was carried out at a voltage of 450 VRMS in four electrolytes containing the salt as copper(II) nitrate(V) trihydrate. Moreover, we showed that the content of salt in the electrolyte needed to obtain a porous PEO coating was in the range 300&ndash, 600 g/dm3. After exceeding this amount of salts in the electrolyte, some inclusions on the sample surface were observed. It is worth noting that this limitation of the amount of salts in the electrolyte was not connected with the maximum solubility of copper(II) nitrate(V) trihydrate in the concentrated (85%) orthophosphoric acid. To characterize the obtained coatings, numerous techniques were used. In this work, we used scanning electron microscopy (SEM) coupled with electron-dispersive X-ray spectroscopy (EDS), conducted surface analysis using confocal laser scanning microscopy (CLSM), and studied the surface layer chemical composition of the obtained coatings by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), glow discharge of optical emission spectroscopy (GDOES), and biological tests. It was found that the higher the concentration of Cu(NO3)2∙3H2O in the electrolyte, the higher the roughness of the coatings, which may be described by 3D roughness parameters, such as Sa (1.17&ndash, 1.90 &mu, m) and Sp (7.62&ndash, 13.91 &mu, m). The thicknesses of PEO coatings obtained in the electrolyte with 300&ndash, 600 g/dm3 Cu(NO3) 2∙3H2O were in the range 7.8 to 10 &mu, m. The Cu/P ratio of the whole volume of coating measured by EDS was in the range 0.05&ndash, 0.12, while the range for the top layer (measured using XPS) was 0.17&ndash, 0.24. The atomic concentration of copper (0.54&ndash, 0.72 at%) resulted in antibacterial and fungicidal properties in the fabricated coatings, which can be dedicated to biocompatible applications.

Modified generalized logistic functions (also known as Koya-Goshu functions) were used for mathematical description of germination. These functions constitute natural modification of traditionally used Richards' function for description of plants germination that introduces a non-linear time increase in exponent and an element related to time shift. Curves were adjusted to experimental data based on minimization of the square sum of difference between experimental data and a mathematical model (the smallest squares method). Results of simulation research show that the determined parameters of curves (e.g., values of the growth parameter, time shift or upper limit of population) describing the number of seedlings as a time function stay compliant to interpretation with regard to biology of the investigated processes. Based on the research, it was stated that for control and application of plant extracts to soil, Koyu-Gosha model has better adjustment to experimental data in comparison to the generalized logistic model.

Today, one of the greatest challenges faced by the agriculture industry is the development of sustainable and environmentally-friendly systems to meet nutritional demands of the continuously growing global population. A number of research studies have recently been undertaken with the aim to indicate types of parameters used in plant production that would be able to improve plant growth as well as the effectiveness and quality of yield, and to help plants cope with environmental stress. The aim of this study was to verify a hypothesis that the implementation of a sustainable agricultural technology, based on the use of synthetic biostimulants, will allow not only increasing crop yield and quality but also improving the cost-effectiveness of common bean cultivation. The field experiment was conducted in three growing seasons (2016&ndash, 2018). In the growing season, the plants were treated with Atonik and Tytanit biostimulants in the form of single or double spraying. We determinated biometric traits, seed yield, seed number, and 1000-seed weight. Further analyses included contents of nutraceutical potential. The economic effect of using biostimulants was also calculated. The results of our experiment allowed verifying a hypothesis that the implementation of a sustainable agricultural technology based on the use of synthetic preparations was an effective method to increase plant productivity and, consequently, economic profits to farmers.

Improvement of crop cultivation technologies is focused on increasing crop productivity and improving yield quality, and at the same time on minimizing risks posed to the natural environment. The use of biostimulants contributes to the increase in the productivity of plants, especially under their exposure to stress induced by negative environmental stimuli. A field experiment was conducted in three growing seasons (2014-2016). Seeds of soybean of the Atlanta cultivar were sown in the third decade of April. Two synthetic biostimulants were used in the growing period in the form of single (stage BBCH 13-15) or double (stage BBCH 13-15, BBCH 61) spraying: Atonik (in concentrations of 0.1 and 0.2%) and Tytanit (in concentrations of 0.07 and 0.13%). Atonik, the first tested biostimulant, contained three phenolic compounds: sodium p-nitrophenolate, sodium o-nitrophenolate, and sodium 5-nitroguaiacolate. The Tytanit preparation contained a titanium complex, magnesium oxide, and sulfur (VI) oxide. This work presents a complex study addressing the action of the biostimulants Atonik and Tytanit and demonstrates their effect on the physiological traits, plant productivity, and seed yield quality of Glycine max L. The conducted experiment proved that the biostimulant type, as well as the number of its applications and its concentration, modified the biometric traits, crop productivity, as well as yield quality and the nutraceutical and antioxidative potential of soybean seeds. It was also found that by positively affecting plant growth and seed yield, the Atonik and Tytanit also resulted biostimulants decreased the protein and lipid contents in seeds. A double application of these preparations in their higher concentrations had a more positive impact on soybean seed number and soybean seed yield. The use of both Atonik and Tytanit resulted also in an increased antioxidative activity of soybean seeds. The greatest increase in this activity was observed after the application of the Tytanit preparation. Dietary fiber fraction analysis demonstrated an increase in the acid-detergent fiber, lignin, and cellulose contents in soybean seeds as a result of biostimulant application; however, the increase was greater upon the use of Tytanit. In contrast, the neutral-detergent fiber, cellulose, and hemicellulose contents were observed to decrease in all analyzed combinations of crops treated with the tested preparations.

The experiment was conducted in the years 2014-2016 with the aim to evaluate the influence of a biostimulant based on seaweed and amino acids on the content of neutral and acid detergent fiber, lignin, cellulose and hemicellulose in three cultivars of soybean. In the vegetative season, 0.7% and 1.0% solutions of the biostimulant were used in single and double spraying. Based on the determined fiber fraction contents it was evaluated whether treating soybean with the biostimulant may enhance the quality of forages obtained from it. It was found that the level of fiber fractions and contents of hemicellulose and cellulose were influenced by biostimulant application. Differences in the content of fiber fractions resulted from the number of biostimulant doses and its concentration. Mavka cultivar treated with Fylloton was characterized by the highest mean content of fiber fraction. Evaluation of the forage quality indexes demonstrated that biostimulant use caused their reduction, and the highest values were found for Annushka cultivar.

In recent years, attempts have been made to use preparations that allow obtaining high and good quality yields, while reducing the application of pesticides and mineral fertilizers. These include biostimulants that are safe for the natural environment and contribute to the improvement of yield size and quality, especially after the occurrence of stressors. Their use is advisable in the case of crops sensitive to such biotic stress factors like low temperatures or drought. One of these is soybean which is a very important plant from the economic viewpoint. Field experiments were established in the years 2014-2016 in a random block design in four replicates on experimental plots of 10 m2. Three soybean cultivars: Annushka, Mavka, and Atlanta were planted in the third decade of April. Fylloton biostimulant was used at 0.7% or 1% concentrations as single spraying (BBCH 13-15) or double spraying (BBCH 13-15, BBCH 61) in the vegetation period. The number of seeds per 1 m2, seed yield, thousand seed weight, number of pods per plant, number of nodes in the main shoot, height of plants, and protein and fat contents in seeds were determined. The content of phenolic compounds, antioxidant capacity and antioxidant effect of soybean seeds were assayed as well. Foliar treatment of soybean with Fylloton stimulated the growth and yield of plants without compromising their nutritional and nutraceutical properties. The double application of the higher concentration of Fylloton was favorable for the plant height, seed number and soybean yield. Moreover, the highest number of pods was obtained after single treatment of plants with the lower biostimulant concentration. There was also a positive effect of using this biostimulant on the content and activity of some bioactive compounds, such as phenolics and flavonoids, and on the reducing power.

Currently, modern agriculture aims to improve the quantity and quality of crop yield, while minimizing the negative impact of treatments on the natural environment. One of the methods to increase plant yield and quality, especially after the occurrence of both abiotic or biotic stress factors, is the application of biostimulants. The aim of the study was to determine the effect of Ecklonia maxima extract on plant growth, and the yield, nutritional, and nutraceutical properties of soybean seeds. A field experiment was conducted in three growing seasons (2014&ndash, 2016). Soybean seeds of Atlanta cultivar were sown in the third 10-day period of April. Ecklonia maxima extract was applied in the form of single or double, spraying in the concentrations of 0.7% and 1.0%. Determinations were conducted for: biometric traits, seed yield, seed number, thousand seeds weight, contents of lipids, and proteins in seeds. Further analyses included the contents of total polyphenols, flavonoids, anthocyanins, and reducing power. The number of seaweed extract applications and its concentration modified biometric traits, yield, and quality of crop, while also also altering the nutraceutical and antioxidative potential of soybean. The application of this preparation improved the growth and yield of soybean without any negative effect on the nutritive value of seeds.