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1. Hydrogen isotopic fractionations during syntheses of lipid biomarkers in the seeds of broomcorn millet (Panicum miliaceum L.) under controlled environmental conditions

Author

Patricia Richard, Nicolas Bossard, Valery J. Terwilliger, Claude Le Milbeau, Elisabeth Vergès, Philippe Biron, Jérémy Jacob, Thierry Bariac, Institut des Sciences de la Terre d'Orléans - UMR7327 (ISTO), Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS), Biogéosystèmes Continentaux - UMR7327, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Géochrononologie Traceurs Archéométrie (GEOTRAC), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut d'écologie et des sciences de l'environnement de Paris (iEES Paris ), Institut de Recherche pour le Développement (IRD)-Sorbonne Université (SU)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS)-Université de Paris (UP)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), LE STUDIUM (LE STUDIUM), Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Centre national du machinisme agricole, du génie rural, des eaux et forêts (CEMAGREF)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Institut de recherche pour le développement [IRD] : UR-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), University of Kansas [Kansas City], Simon Fraser University (SFU.ca), Ministère de la Recherche et de l’Enseignement Supérieur (Action Thématique Prioritaire, 2009-2012)., Le Studium® (Loire Institute for Advanced Studies)., ANR-10-JCJC-0607,PalHydroMil,Reconstructions paléohydrologiques à partir du dD de lipides produits par les végétaux supérieurs. Calibration, validation et application aux variations hydrologiques dans les Alpes pendant l'âge du Bronze(2010), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Institut de Recherche pour le Développement (IRD)-Sorbonne Université (SU)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Institut de recherche pour le développement [IRD] : UR-Centre National de la Recherche Scientifique (CNRS), POTHIER, Nathalie, and Jeunes Chercheuses et Jeunes Chercheurs - Reconstructions paléohydrologiques à partir du dD de lipides produits par les végétaux supérieurs. Calibration, validation et application aux variations hydrologiques dans les Alpes pendant l'âge du Bronze - - PalHydroMil2010 - ANR-10-JCJC-0607 - JCJC - VALID

Subjects
010504 meteorology & atmospheric sciences, Hydrogen, chemistry.chemical_element, Biosynthetic fractionation hydrogen isotopes Panicum miliaceum Biogeochemical chambers compound-specific δ2H, Fractionation, Leaf water, 010502 geochemistry & geophysics, Graminoid, 01 natural sciences, GEOF, [SDU] Sciences of the Universe [physics], Triterpene, Geochemistry and Petrology, Relative humidity, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, 0105 earth and related environmental sciences, chemistry.chemical_classification, Panicum miliaceum, biology, Chemistry, food and beverages, miliacin, biology.organism_classification, [SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces, environment, [SDU]Sciences of the Universe [physics], Environmental chemistry, biomarker, Lipid biomarkers
Abstract

International audience; Compound specific hydrogen isotopic analyses have the potential to reveal the biosynthetic pathways of biomarkers and to reconstruct the effects of water stress in a plant, or in an ecosystem. Although C4 graminoids are of great geological interest and are some of the world's leading crops, there are few experimental studies of their biomarker responses to hydrological conditions. Here, we study a C4 graminoid, broomcorn millet, and compare the effects of controlled changes in environmental conditions on the distributions of n-alkane homologues and on the pentacyclic triterpene, miliacin, which is a biomarker for broomcorn millet; both were measured in the seeds of the graminoid. Broomcorn millet plants were propagated in hydroponic solutions with four different δ2H values for each of two growth chambers, differing in relative humidity (58 and 74 %). Analyses of δ2H values of the lipid compounds (miliacin and n-alkanes) in seeds and water extracted from transpiring and non-transpiring organs allowed us to quantify the apparent (lipids vs. source water to plant) and biosynthetic (lipids vs. leaf water) fractionations during miliacin and n-alkane syntheses. Miliacin and n-alkane δ2H values were linearly related to leaf water δ2H values, permitting credible biosynthetic fractionations to be calculated for n-alkanes (average -149.5‰ ± 11) and miliacin (-118‰ ± 5). These biosynthetic fractionations were within the range of published values for compounds with their respective biosynthetic pathways, although a 2H-enrichment of miliacin compared to n-alkanes remains unexplained.Whereas a 16% decrease in relative humidity had no significant impact on the biosynthetic fractionation of miliacin, n-C25 and n-C27 alkanes, it led to a ∼25‰ decrease in biosynthetic fractionation for n-C31 and n-C33 alkanes. This could be the consequence of a contribution of more depleted pools of hydrogen atoms in cytoplasmic water (compared to chloroplastic hydrogen pools) during the n-alkyl lipid elongation process. This finding suggests that the respective influences of source water δ2H values and relative humidity on the δ2H values of organic compounds may be discretely inferred by examining the δ2H values of compounds synthesized from distinct sources of hydrogen in cells. It provides clues to the biosynthetic fractionations in a C4 plant for compounds derived from distinct pathways, but also highlights specific issues related to seed lipids that would require further research.

Published
2021
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2. Contribution of NAD 2D-NMR in liquid crystals to the determination of hydrogen isotope profile of methyl groups in miliacin

Author

Philippe Lesot, Jérémy Jacob, Valery J. Terwilliger, P. Berdagué, Claude Le Milbeau, Université Paris-Saclay, Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), Institut de Chimie du CNRS (INC)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS), Université d'Orléans (UO), Institut des Sciences de la Terre d'Orléans - UMR7327 (ISTO), Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), University of Kansas [Kansas City], and ANR-10-JCJC-0607,PalHydroMil,Reconstructions paléohydrologiques à partir du dD de lipides produits par les végétaux supérieurs. Calibration, validation et application aux variations hydrologiques dans les Alpes pendant l'âge du Bronze(2010)

Subjects
Deuterium NMR, Amyrin, 010504 meteorology & atmospheric sciences, Stereochemistry, Isotope profile, 010502 geochemistry & geophysics, Biosynthesis, 01 natural sciences, Diagenesis, chemistry.chemical_compound, Miliacin, Geochemistry and Petrology, Computational chemistry, Molecule, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, 0105 earth and related environmental sciences, Isotope, chemistry, Deuterium, Liquid crystal, 13. Climate action, [SDU]Sciences of the Universe [physics], Yield (chemistry), Natural abundance, Site-specific, Pentacyclic triterpene, Two-dimensional nuclear magnetic resonance spectroscopy
Abstract

International audience; The hydrogen isotopic composition (δD or (D/H) value) of molecular biomarkers preserved in sedimentary archives is increasingly used to provide clues about the evolution of past climatic conditions. The rationale is that intact biomarkers retain isotopic information related to the climatic conditions that prevailed at the time of their synthesis. Some of these biomarkers may be degraded during diagenesis, however. The extent to which these degradations alter the original δD value of the source biomarker is presently debated and the capacity to resolve the debate by determinations of compound-specific δD values alone is limited. The “bulk” or “global” δD value of any molecule is in fact a composite of δD values at each site within this molecule ((δDi or (D/H)i with i= number of hydrogen/deuterium atoms in the considered molecule). Determination of this site-specific δDi value in biomarkers could not only yield outstanding paleoenvironmental information but also help forecast the impacts of diagenesis and define essential steps in biosynthetic pathways.This task is analytically challenging. Here, we examined the capabilities of natural abundance deuterium 2D-NMR (NAD 2D-NMR) using homopolypeptide liquid crystals as an NMR solvent to: i) analyze the NAD spectra of biomakers; ii) determine the site-specific distribution of hydrogen in the nine methyl groups (δDMei with i= 23 to 31) of miliacin, a pentacyclic triterpene of the amyrin family and key biomarker for broomcorn millet in sedimentary archives. Relative (D/H)Mei values were established by anisotropic NAD 2D-NMR. Then absolute δDMei values were obtained by determining δDMei value of the methoxy group of miliacin using two independent approaches: isotropic NAD NMR (SNIF-NMRTM) and GC-irMS. The resulting isotope profile for miliacin shows, for the first time, large variations in δDMei values that can directly be explained by biosynthetic processes. This approach has also the potential to permit predicting fractionations during pentacyclic triterpene diagenesis.

Published
2016
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3. The Pliensbachian-Toarcian paleoclimate transition: New insights from organic geochemistry and C, H, N isotopes in a continental section from Central Asia

Author

François Baudin, Denise Pons, Arnaud Huguet, Marc Philippe, Sylvie Derenne, Romain Tramoy, Mathieu Sebilo, Johan Yans, Jérémy Jacob, Johann Schnyder, T. T. Nguyen Tu, Institut des Sciences de la Terre de Paris (iSTeP), Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), Evolution et Modélisation des Bassins Sédimentaires (EMBS), Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), Milieux Environnementaux, Transferts et Interactions dans les hydrosystèmes et les Sols (METIS), Université Pierre et Marie Curie - Paris 6 (UPMC)-École pratique des hautes études (EPHE), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS), Facultés Universitaires Notre Dame de la Paix (FUNDP), Institut des Sciences de la Terre d'Orléans - UMR7327 (ISTO), Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS), Biogéosystèmes Continentaux - UMR7327, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut d'écologie et des sciences de l'environnement de Paris (iEES), Institut National de la Recherche Agronomique (INRA)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'Ecologie des Hydrosystèmes Naturels et Anthropisés (LEHNA), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École Nationale des Travaux Publics de l'État (ENTPE)-Centre National de la Recherche Scientifique (CNRS), Centre de recherche sur la Paléobiodiversité et les Paléoenvironnements (CR2P), Muséum national d'Histoire naturelle (MNHN)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), EMERGENCE 2012 project from the UPMC, DARIUS program in the framework of a collaboration with KAZNTU, Almaty, ANR-10-JCJC-0607,PalHydroMil,Reconstructions paléohydrologiques à partir du dD de lipides produits par les végétaux supérieurs. Calibration, validation et application aux variations hydrologiques dans les Alpes pendant l'âge du Bronze(2010), Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC), Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC), Centre National de la Recherche Scientifique (CNRS)-École pratique des hautes études (EPHE)-Université Pierre et Marie Curie - Paris 6 (UPMC), Facultés Universitaires Notre Dame de la Paix (FUNDP) - Namur, Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, PSL Research University (PSL)-PSL Research University (PSL)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, PSL Research University (PSL)-PSL Research University (PSL)-Institut national des sciences de l'Univers (INSU - CNRS)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS), PSL Research University (PSL)-PSL Research University (PSL)-Institut national des sciences de l'Univers (INSU - CNRS)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut d'écologie et des sciences de l'environnement de Paris (IEES), Centre National de la Recherche Scientifique (CNRS)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut National de la Recherche Agronomique (INRA), Centre National de la Recherche Scientifique (CNRS)-Institut National de la Recherche Agronomique (INRA)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École Nationale des Travaux Publics de l'État (ENTPE), Systèmes d'élevage, nutrition animale et humaine (SENAH), Institut National de la Recherche Agronomique (INRA)-AGROCAMPUS OUEST, Université Pierre et Marie Curie - Paris 6 (UPMC)-École Pratique des Hautes Études (EPHE), Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), and Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers en région Centre (OSUC)

Subjects
010504 meteorology & atmospheric sciences, Climate change, Xenoxylon, 010502 geochemistry & geophysics, Oceanography, 01 natural sciences, GEOF, δ2H, Paleontology, n-Alkanes, Paleoclimatology, Organic geochemistry, medicine, Temperate climate, δ15Norg, δH, Organic matter, brGDGT, Ecology, Evolution, Behavior and Systematics, 0105 earth and related environmental sciences, Earth-Surface Processes, chemistry.chemical_classification, δN, 15. Life on land, Seasonality, medicine.disease, Isotopes of nitrogen, chemistry, 13. Climate action, Period (geology), [SDE.BE]Environmental Sciences/Biodiversity and Ecology, Geology
Abstract

The Taskomirsay section (South Kazakhstan) is a unique Pliensbachian-Toarcian sequence of lignites, clayey layers and silty-sandstones deposited in a fluvial/lacustrine environment with nearby swampy areas. This period, characterized by a drastic climate change, has been particularly studied in Western Tethyan marine environments, whereas very few studies focused on continental settings. Paleoflora analyses, associated with a multi-isotope approach, based on well-preserved Type-III bulk organic nitrogen isotopes (δ15Norg) and hydrogen isotopic composition (δ2H) of n-alkanes, were developed to document paleoclimatic changes in the area. Sporomorph associations and fossil woods revealed a globally warm- to cool-temperate climate – characterized by Xenoxylon, a conifer morphogenus biogeographically related to cool/humid settings – apart from slightly less humid and warmer conditions in the early Toarcian. Warmer conditions are supported by reconstructed Mean Annual Air Temperatures (MAATs), based on the first branched glycerol dialkyl glycerol tetraethers (brGDGTs) ever recorded in the Early Jurassic. Nevertheless, no drastic changes were recorded in the δ15Norg values; its signal being attributed to tenuous equilibrium between water- and nutrient-availability via intense N-recycling. Based on n-alkane distributions, sources of organic matter were separated in two pools: (i) a purely terrestrial (n-C27) and (ii) an “aquatic” pool (n-C23) constituted of vegetation that thrived under almost permanent water supply. The n-alkane δ2H values (− 248 to − 151‰) as well as their amounts and average chain lengths (ACL) are in agreement with cool-temperate conditions in the Pliensbachian and less humid/warmer conditions in the early Toarcian. The isotopic difference between δ2H values of n-C27 and n-C23 (Δ2Hter-aq) suggests enhanced seasonality during the Pliensbachian-Toarcian transition and low seasonality in the early Toarcian, in agreement with temperate climate-regime. Finally, contrasted response to paleoclimate changes between markers suggests different spatial integration of those proxies. The role of sea-level variations for δ2H values might also resolve this contrasted response.

Published
2016
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4. High frequency floral changes at the Paleocene–Eocene boundary revealed by comparative biomarker and palynological studies

Author

Claude Le Milbeau, Christian Dupuis, Jérémy Jacob, Sylvain Garel, Florence Quesnel, Mohammed Boussafir, Johann Schnyder, François Baudin, Emile Roche, Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Institut des Sciences de la Terre de Paris (iSTeP), Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), Institut des Sciences de la Terre d'Orléans - UMR7327 (ISTO), Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Département de Géologie, Université de Liège, Géologie GFA, Faculté polytechnique de Mons, Université de Mons (UMons)-Université de Mons (UMons), ANR-10-JCJC-0607,PalHydroMil,Reconstructions paléohydrologiques à partir du dD de lipides produits par les végétaux supérieurs. Calibration, validation et application aux variations hydrologiques dans les Alpes pendant l'âge du Bronze(2010), Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Observatoire des Sciences de l'Univers en région Centre (OSUC), and Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Vascular plant, PETM, 010504 meteorology & atmospheric sciences, Molecular geochemistry, Dieppe-Hampshire Basin, 010502 geochemistry & geophysics, medicine.disease_cause, 01 natural sciences, Sedimentary depositional environment, Paleontology, Geochemistry and Petrology, Pollen, Botany, Pollen and spores study, medicine, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, 0105 earth and related environmental sciences, Floral changes, Palynology, biology, Paleohydrology, fungi, food and beverages, Juglandaceae, Vegetation, 15. Life on land, biology.organism_classification, Spore, 13. Climate action, Geology, Marine transgression
Abstract

International audience; The Cap d'Ailly area (Upper Normandy, France) shows several terrestrial–lagoonal sections recording the negative carbon isotope excursion (CIE) associated with the Paleocene–Eocene Thermal Maximum (PETM; 55.8 Ma). A study of the biomarkers and spore/pollen content of the Vasterival section gave com-plementary information on paleofloral changes that occurred around the Paleocene–Eocene (P–E) bound-ary. Aliphatic hydrocarbon fractions revealed a high abundance of vascular plant biomarkers, including tricyclic diterpanes derived from conifers, fernenes derived from ferns and des-A-triterpenes derived from angiosperms. Whereas the vegetation of the depositional environment surroundings seemed alter-nately dominated by ferns and angiosperms (revealed from biomarkers), the regional flora seemed dom-inated strictly by angiosperms such as Juglandaceae (revealed by pollen). Spore/pollen assemblages revealed no major turnover in the paleovegetation, but slight variation in vegetation composition. How-ever, both biomarkers and spores/pollen exhibited two intervals of rapid floral change: the first occurred around the P–E boundary and the second at the top of the strictly terrestrial unit that coincides with a marine transgression. Comparison of the data with published paleoclimatic results, obtained from the same samples, indicated that the first interval of floral change correlates with strong paleohydrological perturbations, whereas the second is linked to an increasing marine influence.

Published
2014
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5. Distribution of miliacin (olean-18-en-3β-ol methyl ether) and related compounds in broomcorn millet (Panicum miliaceum) and other reputed sources: Implications for the use of sedimentary miliacin as a tracer of millet

Author

Valery J. Terwilliger, Joana Sauze, Nicolas Bossard, Elisabeth Vergès, Claude Le Milbeau, Bertrand Poissonnier, Jérémy Jacob, Institut des Sciences de la Terre d'Orléans - UMR7327 (ISTO), Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Department of Geography, University of Kansas [Lawrence] (KU), Institut national de recherches archéologiques préventives (Inrap), PaléoChamps project (AIR Archéométrie, CNRS/INSU) and NSF project # BCS0551668, and ANR-10-JCJC-0607,PalHydroMil,Reconstructions paléohydrologiques à partir du dD de lipides produits par les végétaux supérieurs. Calibration, validation et application aux variations hydrologiques dans les Alpes pendant l'âge du Bronze(2010)

Subjects
Setaria, Millet, [SDE.MCG]Environmental Sciences/Global Changes, Ether, 010502 geochemistry & geophysics, 01 natural sciences, Panicum miliaceum, 03 medical and health sciences, chemistry.chemical_compound, Miliacin, Geochemistry and Petrology, Botany, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, 030304 developmental biology, 0105 earth and related environmental sciences, 0303 health sciences, biology, Agriculture, 15. Life on land, biology.organism_classification, Agronomy, chemistry, Pentacyclic triterpenes, Foxtail, Chaetomium olivaceum, Sedimentary rock, Pennisetum, Panicum
Abstract

International audience; Using sedimentary miliacin (olean-18-en-3β-ol methyl ether) as a molecular tracer of the history of Panicum miliaceum (broomcorn millet) cultivation depends upon broomcorn millet being sedimentary miliacin's dominant source. It also requires knowledge of the variability in miliacin concentration in broomcorn millet. Finally, it is affected by the presence of other pentacyclic triterpene methyl ethers (PTMEs) that may exist in conjunction with miliacin in other sources but not in broomcorn millet. Miliacin biosynthesis has been proposed for other Panicum species, Setaria italica (Italian or foxtail millet), Pennisetum sp., and Chaetomium olivaceum (an olive green mold). We found miliacin concentration in seeds of different varieties of P. miliaceum to be similarly high (with trace amounts of β- and α-amyrin methyl ethers). It was absent from hulls and roots, and nominally present in leaves and stems. The transfer of miliacin from plant to sediments is therefore mostly from seeds. it was abundant (often with larger amounts of β- and α-amyrin methyl ethers) in all other Panicum species studied, but only in some species of the genus Pennisetum and was absent from Setaria italica. Neither C. olivaceum nor its growth medium (rice) showed any trace of miliacin. Our results, with miliacin absent from S. italica and C. olivaceum, its high miliacin in seed of P. miliaceum relative to other PTMEs and to other grasses and, considering the high biomass that cultivated broomcorn millet has relative to other potential plant sources, support the use of sedimentary records of miliacin in some contexts to track past millet agricultural dynamics.

Published
2013
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6. Molecular Biomarkers of Anthropic Impacts in Natural Archives: A Review

Author

Nathalie Dubois, Jérémy Jacob, Surface Waters Researchand Management, Eidgenössische Anstalt für Wasserversorgung, Institut des Sciences de la Terre d'Orléans - UMR7327 (ISTO), Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM), Biogéosystèmes Continentaux - UMR7327, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Bureau de Recherches Géologiques et Minières (BRGM) (BRGM)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers en région Centre (OSUC), ERODE (EC2CO) : CNRS-INSUOTARIE - Région Centre - CG45 - FEDER 2009-000-36691AIR Archéométrie : CNRS-INSU, ANR-07-BLAN-0133,Pygmalion,Pygmalion : Paleohydrology and Human-climate-Environment Interactions in the Alps(2007), and ANR-10-JCJC-0607,PalHydroMil,Reconstructions paléohydrologiques à partir du dD de lipides produits par les végétaux supérieurs. Calibration, validation et application aux variations hydrologiques dans les Alpes pendant l'âge du Bronze(2010)

Subjects
land use change, paleoenvironment, 010504 meteorology & atmospheric sciences, lcsh:Evolution, Ecology and Evolution, 010502 geochemistry & geophysics, 01 natural sciences, Natural (archaeology), lcsh:QH540-549.5, lcsh:QH359-425, Land use, land-use change and forestry, natural archives, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, Environmental planning, Ecology, Evolution, Behavior and Systematics, 0105 earth and related environmental sciences, human impacts, Ecology, Land use, fossil molecules, biomarkers, 15. Life on land, Molecular biomarkers, Geography, 13. Climate action, lcsh:Ecology, Strengths and weaknesses
Abstract

International audience; Molecular biomarkers are becoming increasingly important tools in paleoenvironmental research, and over recent years have been shown to be useful indicators of human activities. Common indicators of past human impacts include pollen, charcoal, sedimentation rates, and magnetic susceptibility, each of which has its limitations. Thus, the advent of novel molecular markers of human activities provides an additional set of tools to make the difficult distinction between anthropogenic and natural factors that have influenced the environment in the past. Fossil biomarkers preserved in natural archives provide valuable temporal and spatial insights on land use such as cultivation practices and pastoral activities, post-harvesting activities (e.g., retting), and their consequences on the environment and ecosystems. Herein we review the progress that has been made in developing novel biomarkers of human activities, differentiating those indicating environmental changes that can be related to human activities from those unambiguously attributable to human activities. The review ends with a case study highlighting the strengths and weaknesses of the biomarker approach and finally summarizes opportunities for future research.

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