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The effects of severe plastic deformation (SPD) process via high-speed high-pressure torsion technique on martensitic transformation of Ni–Fe–Ga Heusler shape memory alloy are the subject of this work. The results show that moderate degrees of deformation lead to a decrease in the martensitic transformation temperatures, while the heat of reaction is enhanced only for the sample processed with the lowest degree of deformation. The results are explained by the interplay between the constituent tetragonal L10 and the cubic gamma crystal structures and the evolution of the samples morphology with the severity of deformation. The reduction in the samples granulation due to the progressive increase in the SPD is reflected by the magnetic properties of the samples with decreasing coercivity and Curie temperatures. At the highest applied degree of deformation, sample nanostructuring and a possible amorphization might explain the vanishing of MT.

Composites of magnetite (Fe3O4) nanoparticles dispersed in a polydimethylsiloxane (PDMS) matrix were prepared by a molding process. Two types of samples were obtained by free polymerization with randomly dispersed particles and by polymerization in an applied magnetic field. The magnetite nanoparticles were obtained from magnetic micrograins of acicular goethite (α-FeOOH) and spherical hematite (α-Fe2O3), as demonstrated by XRD measurements. The evaluation of morphological and compositional properties of the PDMS:Fe3O4 composites, performed by SEM and EDX, showed that the magnetic particles were uniformly distributed in the polymer matrix. Addition of magnetic dispersions promotes an increase of thermal conductivity compared with pristine PDMS, while further orienting the powders in a magnetic field during the polymerization process induces a decrease of the thermal conductivity compared with the un-oriented samples. The shape of the magnetic dispersions is an important factor, acicular dispersions providing a higher value for thermal conductivity compared with classic commercial powders with almost spherical shapes.

Context. The chromosphere is a partially ionized layer of the solar atmosphere that mediates the transition between the photosphere where the gas motion is determined by the gas pressure and the corona dominated by the magnetic field. Aims. We study the effect of partial ionization for 2D wave propagation in a gravitationally stratified, magnetized atmosphere characterized by properties that are similar to those of the solar chromosphere. Methods. We adopted an oblique uniform magnetic field in the plane of propagation with a strength that is suitable for a quiet sun region. The theoretical model we used is a single fluid magnetohydrodynamic approximation, where ion-neutral interaction is modeled by the ambipolar diffusion term. Magnetic energy can be converted into internal energy through the dissipation of the electric current produced by the drift between ions and neutrals. We used numerical simulations in which we continuously drove fast waves at the bottom of the atmosphere. The collisional coupling between ions and neutrals decreases with the decrease in the density and the ambipolar effect thus becomes important. Results. Fast waves excited at the base of the atmosphere reach the equipartition layer and are reflected or transmitted as slow waves. While the waves propagate through the atmosphere and the density drops, the waves steepen into shocks. Conclusions. The main effect of ambipolar diffusion is damping of the waves. We find that for the parameters chosen in this work, the ambipolar diffusion affects the fast wave before it is reflected, with damping being more pronounced for waves which are launched in a direction perpendicular to the magnetic field. Slow waves are less affected by ambipolar effects. The damping increases for shorter periods and greater magnetic field strengths. Small scales produced by the nonlinear effects and the superposition of different types of waves created at the equipartition height are efficiently damped by ambipolar diffusion.

The influence of the partial substitution of Fe by Si and thermal treatments on the structural, magnetic and magnetostrictive properties of the Fe67.5Pd30.5Si2 rapidly solidified ribbons has been investigated. A remarkable decrease in the martensite transformation temperature, with ~ 65 K lower than that of the Fe–Pd archetype alloy, is observed in the as-prepared ribbons. The thermal treatments shift the martensite transformation temperatures upward, with approximately 13 K for the higher thermal treatment. Also, these induce an improvement in the crystallinity in these ribbons with high texture and an increase in the crystallite size as a result of reducing the internal defects and stress. The thermodynamic considerations discussed in the frame of the Clapeyron–Clausius relation by using the calorimetric and thermomagnetic measurements (up to 7 T) reveal a weak influence of the magnetic fields on the martensitic transformation temperatures (~ 0.5 K/T). The magnetostriction decrease with temperature under small magnetic fields was discussed, beside an unusual behaviour in the technically saturated domain. This behaviour is based on the coexistence of the ordinary and forced magnetostrictions, the last one increasing faster with the temperature decreasing.

In the absence of an initial seed, the Biermann battery term of a non-ideal induction equation acts as a source that generates weak magnetic fields. These fields are then amplified via a dynamo mechanism. The Kelvin-Helmholtz instability is a fluid phenomenon that takes place in many astrophysical scenarios and can trigger the action of the Biermann battery and dynamo processes. We aim to investigate the effect that the ionisation degree of the plasma and the interaction between the charged and neutral species have on the generation and amplification of magnetic fields during the different stages of the instability. We use the two-fluid model implemented in the numerical code Mancha-2F. We perform 2D simulations starting from a configuration with no initial magnetic field and which is unstable due to a velocity shear. We vary the ionisation degree of the plasma and we analyse the role that the different collisional terms included in the equations of the model play on the evolution of the instability and the generation of magnetic field. We find that when no collisional coupling is considered between the two fluids, the effect of the Biermann battery mechanism does not depend on the ionisation degree. However, when elastic collisions are taken into account, the generation of magnetic field is increased as the ionisation degree is reduced. This behaviour is slightly enhanced if the process of charge-exchange is also considered. We also find a dependence on the total density of the plasma related to the dependence on the coupling degree between the two fluids. As the total density is increased, the results from the two-fluid model converge to the predictions of single-fluid models., Comment: 20 pages, 13 figures, 2 movies. Accepted for publication in Astronomy & Astrophysics

The equimolar oxide mixture &beta, Ga2O3&mdash, &alpha, Fe2O3 was subjected to high-energy ball milling (HEBM) with the aim to obtain the nanoscaled GaFeO3 ortho-ferrite. X-ray diffraction, 57Fe M&ouml, ssbauer spectroscopy, and transmission electron microscopy were used to evidence the phase structure and evolution of the equimolar nano-system &beta, Fe2O3 under mechanochemical activation, either as-prepared or followed by subsequent calcination. The mechanical activation was performed for 2 h to 12 h in normal atmosphere. After 12 h of HEBM, only nanoscaled (~20 nm) gallium-doped &alpha, Fe2O3 was obtained. The GaFeO3 structure was obtained as single phase, merely after calcination at 950 &deg, C for a couple of hours, of the sample being subjected to HEBM for 12 h. This temperature is 450 &deg, C lower than used in the conventional solid phase reaction to obtain gallium orthoferrite. The optical and magnetic properties of representative nanoscaled samples, revealing their multifunctional character, were presented.

For DEMO fusion reactor an expected heat flux of about 10 MW/m 2 should be extracted by the divertor which will have, most likely, an armour part made of W and a following heat sink part made of Cu or ODS Cu alloy. Unfortunately, for these materials the optimum operating temperature windows do not overlap. Thermal barrier materials are interface materials included in such components, aiming to keep the temperatures of both armour and heat sink parts in the corresponding operating windows, and to mitigate the effects of their different thermomechanical properties. Here we propose a simple spark plasma sintering route to create Cu-based composites with a high content (10–40 vol%) of various dispersed materials (Al or Y oxides, C, SiC), allowing a fine tuning of the content and a large pool of predefined shapes and dimensions. The resulting specimens can be further joined to armour and heatsink components via a similar electrical field assisted technology. Micro-structural and thermal properties are investigated for these materials allowing to select the most suited materials in view of their thermal conductivity and thermal expansion coefficients.

In this paper, we investigate the influence of Cu, Co, and Al substitutions on the transport properties, and in particular, the magnetoresistive effect in Ni–Fe–Ga ferromagnetic shape memory alloys (FSMAs) prepared as ribbons by melt spinning method and subjected to different thermal treatments. X-ray diffraction, differential scanning calorimetry, magnetometry, and magnetoresistive characterizations were performed. In the range of the martensitic transformation (MT), different FSMA compositions show a rich spectrum of different behaviors. For one of the compositions (Ni52Fe20Co2Ga23Al3), the magnetoresistance (MR) showed a local minimum or, on the contrary, a local maxima of reduced amplitude on cooling, in the range of the MT, depending on the performed thermal treatments. In the same composition, by replacing one Al atom with a Co one, no local extremes are seen, the alloy having a concomitant magneto-structural transition. When the magnetic field was varied, the MR showed a nonmonotonic variation in the martensite phase for some compounds, possibly due to the dynamics of the martensite variants realignment. From the studied compositions, the highest MR found on the MT of −9% for 5 T is for Ni50Fe20Ga27Cu3.

Solar prominences are formed by partially ionized plasma with inter-particle collision frequencies, which generally warrant magnetohydrodynamic treatment. In this work, we explore the dynamical impacts and observable signatures of two-fluid effects in the parameter regimes when ion-neutral collisions do not fully couple the neutral and charged fluids. We performed 2.5D two-fluid (charge – neutrals) simulations of the Rayleigh-Taylor instability (RTI) at a smoothly changing interface between a solar prominence thread and the corona. The purpose of this study is to deepen our understanding of the RTI and the effects of partial ionization on the development of the RTI using nonlinear two-fluid numerical simulations. Our two-fluid model takes into account viscosity, thermal conductivity, and collisional interaction between neutrals and charge: ionization or recombination, energy and momentum transfer, and frictional heating. In this paper, we explore the sensitivity of the RTI dynamics to the prominence equilibrium configuration, including the impact of the magnetic field strength and shear supporting the prominence thread, and the amount of prominence mass-loading. We show that at small scales, a realistically smooth prominence-corona interface leads to qualitatively different linear RTI evolution than that which is expected for a discontinuous interface, while magnetic field shear has the stabilizing effect of reducing the growth rate or eliminating the instability. In the nonlinear phase, we observe that in the presence of field shear the development of the instability leads to formation of coherent and interacting 2.5D magnetic structures, which, in turn, can lead to substantial plasma flow across magnetic field lines and associated decoupling of the fluid velocities of charged particles and neutrals.

Solar chromosphere consists of a partially ionized plasma, which makes modeling the solar chromosphere a particularly challenging numerical task. Here we numerically model chromospheric waves using a two-fluid approach with a newly developed numerical code. The code solves two-fluid equations of conservation of mass, momentum, and energy, together with the induction equation for the case of the purely hydrogen plasma with collisional coupling between the charged and neutral fluid components. The implementation of a semi-implicit algorithm allows us to overcome the numerical stability constraints due to the stiff collisional terms. We test the code against analytical solutions of acoustic and Alfvén wave propagation in uniform medium in several regimes of collisional coupling. The results of our simulations are consistent with the analytical estimates, and with other results described in the literature. In the limit of a large collisional frequency, the waves propagate with a common speed of a single fluid. In the other limit of a vanishingly small collisional frequency, the Alfvén waves propagate with an Alfvén speed of the charged fluid only, while the perturbation in neutral fluid is very small. The acoustic waves in these limits propagate with the sound speed corresponding to either the charges or the neutrals, while the perturbation in the other fluid component is negligible. Otherwise, when the collision frequency is similar to the real part of the wave frequency, the interaction between charges and neutrals through momentum-transfer collisions cause alterations of the waves frequencies and damping of the wave amplitudes.

Solar prominences are formed by partially ionized plasma with inter-particle collision frequencies generally warranting magnetohydrodynamic treatment. In this work we explore the dynamical impacts and observable signatures of two-fluid effects in the parameter regimes when ion-neutral collisions do not fully couple the neutral and charged fluids. We perform 2.5D two-fluid (charges-neutrals) simulations of the Rayleigh-Taylor instability (RTI) at a smoothly changing interface between a solar prominence thread and the corona. The purpose of this study is to deepen our understanding of the RTI and the effects of the partial ionization on the development of RTI using nonlinear two-fluid numerical simulations. Our two-fluid model takes into account neutral viscosity, thermal conductivity, and collisional interaction between neutrals and charges: ionization–recombination, energy and momentum transfer, and frictional heating. In this paper, the sensitivity of the RTI dynamics to collisional effects for different magnetic field configurations supporting the prominence thread is explored. This is done by artificially varying, or eliminating, effects of both elastic and inelastic collisions by modifying the model equations. We find that ionization and recombination reactions between ionized and neutral fluids do not substantially impact the development of the primary RTI. However, such reactions can impact the development of secondary structures during the mixing of the cold prominence and hotter surrounding coronal material. We find that collisionality within and between ionized and neutral particle populations plays an important role in both linear and nonlinear development of RTI; ion-neutral collision frequency is the primary determining factor in development or damping of small-scale structures. We also observe that the degree and signatures of flow decoupling between ion and neutral fluids can depend on the inter-particle collisionality and on the magnetic field configuration of the prominence thread.

Specific functional characteristics of the ferromagnetic shape memory alloy Fe67.5Pd30.5Ga2 prepared as ribbons by rapid quenching technique are reported. The shift of the martensitic transformation temperature induced by the applied magnetic field was determined from the thermomagnetic measurements at various fields up to 5T being proved to be in good agreement with the result obtained from calorimetric data via the Clapeyron - Claussius relation. Magnetostriction measurements reveal a pure spin rotation mechanism under low applied magnetic fields, allowed by the reduced magnetic anisotropy. In high magnetic fields and at temperatures close to martensitic transformation, the magnetostriction has a linear increase up to the maximum considered magnetic induction of 3T. This behavior has been discussed in connection with the forced magnetostiction aspects.

In the case of DEMO fusion reactor, the divertor should be able to extract a steady heat flux of about 10 MW/m2. A promising concept is the W-monoblock which should be connected to a CuCrZr or an advanced Cu ODS alloy pipe passing through the W component. Taking into account the optimum operating temperature windows for W and existing Cu-based alloys and the thermal expansion coefficients mismatch of these two materials, a “thermal barrier” interface material is inserted in between in order to mitigate the thermal stresses and to optimize the heat flow through divertor components. In this work we investigate the feasibility to realize such divertor components using materials produced by FAST (field assisted sintering technology). This powder metallurgy technique was used firstly to produce W or W-based composites and the thermal barriers in an almost final shape and then to join the materials in realistic divertor mock-ups. The thermal barrier materials are various Cu-based composites which are included both as single material or as functionally graded components. The interface quality between different materials is investigated by scanning electron microscopy and the heat flow through components is evaluated using simulations.

The effect of “in situ” thermal treatments (by DSC measurements) on the martensitic transformation in two representative Ni-Fe-Ga and Ni-Mn-Ga alloys has been studied and discussed by correlating the structural and magnetic properties. The alloys were prepared from high purity elements, by arc melting under argon protective atmosphere as bulk and also as melt-spun ribbons - an alternative preparation route that also allows to assess the influences of grains size and strain induced by this processing method. All samples presented reversible thermo-elastic transformations. The thermal treatments promote a reduction of the martensitic transformation temperatures in the Ni-Fe-Ga investigated samples, as opposed to the stoichiometric Ni2MnGa where the temperatures increase with increasing the annealing temperatures. Interestingly however, the off-stoichiometric Ni-Mn-Ga with increased Ni content recovers the behaviour with reduction of transformation temperatures by thermal treatments. The precipitation of the secondary FCC (γ) phase is inherently found in Ni-Fe-Ga alloys with Ga ≤ 27% at, and also -although in lower amounts- in the off-stoichiometric Ni-Mn-Ga. The γ phase is considered to contribute to the decrease of the MT temperatures (via valence electrons concentration depletion of the main matrix) and of the transformation heat as well as to the final structural degradation if the temperature of the thermal treatments is further increased. In addition, this phase, located mainly at the grain boundaries, is responsible for the improved ductility of Ni-Fe-Ga based alloys. Changes in the transformation heat due to thermal treatments are observed and discussed in both types of alloys, the maxima of the transformation heat being associated with the highest atomic order. Thermo-magnetic measurements show that Ni-Fe-Ga alloys have close magnetic and structural transitions temperatures, with promising applications for magnetic refrigeration.

The influence of the heat treatments on the martensitic transformation, magnetic properties and thermo- and magnetic induced strain on Ni50Fe20Ga27Cu3 ferromagnetic shape memory alloy prepared as ribbons by melt–spinning technique are investigated. The degree of atomic order as effect of different thermal treatments produces important changes in the magneto-crystalline anisotropy of the martensite phase. The anomalies evidenced in the thermo-and magnetic- strain curves are discussed and correlated with the thermo-magnetic data. The transformation-induced strains with and without magnetic field have been measured, the results setting out the influence of the pre-martensitic transformation.

Waves and shocks traveling through the solar chromospheric plasma are influenced by its partial ionization and weak collisional coupling, and may become susceptible to multi-fluid effects, similar to interstellar shock waves. In this study, we consider fast magneto-acoustic shock wave formation and propagation in a stratified medium, that is permeated by a horizontal magnetic field, with properties similar to that of the solar chromosphere. The evolution of plasma and neutrals is modeled using a two-fluid code that evolves a set of coupled equations for two separate fluids. We observed that waves in neutrals and plasma, initially coupled at the upper photosphere, become uncoupled at higher heights in the chromosphere. This decoupling can be a consequence of either the characteristic spatial scale at the shock front, that becomes similar to the collisional scale, or the change in the relation between the wave frequency, ion cyclotron frequency, and the collisional frequency with height. The decoupling height is a sensitive function of the wave frequency, wave amplitude, and the magnetic field strength. We observed that decoupling causes damping of waves and an increase in the background temperature due to the frictional heating. The comparison between analytical and numerical results allows us to separate the role of the nonlinear effects from the linear ones on the decoupling and damping of waves.