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We report the detection of a probable $\gamma$-ray quasi-periodic oscillation (QPO) of around 314 days in the monthly binned 0.1 -- 300 GeV $\gamma$-ray {\it Fermi}-LAT light curve of the well known BL Lac blazar OJ 287. To identify and quantify the QPO nature of the $\gamma$-ray light curve of OJ 287, we used the Lomb-Scargle periodogram (LSP), REDFIT, and weighted wavelet z-transform (WWZ) analyses. We briefly discuss possible emission models for radio-loud active galactic nuclei (AGN) that can explain a $\gamma$-ray QPO of such a period in a blazar. Reports of changes in the position of quasi-stationary radio knots over a yearly timescale as well as a strong correlation between gamma-ray and mm-radio emission in previous studies indicate that the signal is probably associated with these knots., Comment: 6 pages, 4 figures, in press (MNRAS)

The resistive switching behavior of 1-D TiO2 nanotube-based resistive random access memory (ReRAM) is discussed in this article. Highly oriented TiO2 nanotubes were synthesized by anodic oxidation method on a Ti substrate, which was used as the bottom electrode. To modulate the oxygen vacancy ( ${V}_{O}$ ) in TiO2 nanotubes, hydrazine hydrate reduction was employed in the temperature range 60 °C–100 °C. After charactering the morphological, elemental, and crystallographic properties, the level of reduction in different TiO2 nanotubes array was estimated by Raman, photoluminescence, and X-ray photoelectron spectroscopies. Au/TiO2 nanotubes/Ti devices were fabricated by using TiO2 nanotubes with various levels of reductions where thin and porous Au top electrode was used to make the resistive switching faster. TiO2 Nanotubes array, reduced at 80 °C showed promising resistive switching performance with SET/RESET voltages of 2 V/1.8 V, ${R}_{ \mathrm{\scriptscriptstyle OFF}} / {R}_{ \mathrm{\scriptscriptstyle ON}}$ of 19 at a read voltage of 0.5 V (25 °C) and stable endurance behavior after the 100th cycle. Interestingly, reduction temperature at 60 °C and 100 °C, offered degraded resistive switching within the same voltage range. All the devices showed electroforming free bipolar resistive switching. Efforts were devoted to establish the role of ${V}_{O}$ and its tuning to improve the resistive switching behavior in 1-D TiO2 nanotubes. This article systematically showcases the efficacy of 1-D metal oxide for potential ReRAM application and establishes an easy but efficient approach to improve the resistive switching by modulating oxygen vacancy in it.

Einstein's theory of General Relativity predicts that the spacetime metric around astrophysical black holes is described by the Kerr solution. In this work, we employ state-of-the-art in relativistic reflection modeling to analyze a selected set of NuSTAR spectra of Galactic black holes to obtain the most robust and precise constraints on the Kerr black hole hypothesis possible today. Our constraints are much more stringent than those from other electromagnetic techniques, and with some sources we get stronger constraints than those currently available from gravitational waves., 15 pages, 11 figures. v2: refereed version

We present time series analyses of three-decade long radio observations of the BL Lacertae object AO 0235+164 made at the University of Michigan Radio Astronomical Observatory operating at three central frequencies of 4.8 GHz, 8.0 GHz and 14.5 GHz. We detected a quasi-periodic oscillation of $\sim$965 days in all three frequency bands in the light curve of the effectively simultaneous observations, along with strong signals at $\sim$1950 d, $\sim$1350 d, and $\sim$660 d. The periodicity is analyzed with three methods: Data Compensated Discrete Fourier Transform, Generalized Lomb-Scargle Periodogram and Weighted Wavelet Z-transform. These methods are chosen as they have different analysis approaches toward robust measurement of claimed periodicities. The QPO at $965\pm 50$ days is found to be significant (at least $3.5\sigma$) and is persistent throughout the observation for all three radio frequencies, and the others, which may be harmonics, are comparably significant in at least the 8.0 GHz and 14.5 GHz bands. We briefly discuss plausible explanations for the origin of such long and persistent periodicity., Comment: 12 pages, 4 figures. Accepted for publication in MNRAS

In a previous paper, we presented an extension of our reflection model RELXILL_NK to include the finite thickness of the accretion disk following the prescription in Taylor & Reynolds (2018). In this paper, we apply our model to fit the 2013 simultaneous observations by NuSTAR and XMM-Newton of the supermassive black hole in MCG-06-30-15 and the 2019 NuSTAR observation of the Galactic black hole in EXO 1846-031. The high-quality data of these spectra had previously led to precise black hole spin measurements and very stringent constraints on possible deviations from the Kerr metric. We find that the disk thickness does not change previous spin results found with a model employing an infinitesimally thin disk, which confirms the robustness of spin measurements in high radiative efficiency disks, where the impact of disk thickness is minimal. Similar analysis on lower accretion rate systems will be an important test for measuring the effect of disk thickness on black hole spin measurements., 16 pages, 9 figures. v2: refereed version

X-ray reflection spectroscopy is a powerful tool for probing the strong gravity region of black holes and can be used for testing general relativity in the strong field regime. Simplifications of the available relativistic reflection models limit the capability of performing accurate measurements of the properties of black holes. In this paper, we present an extension of the model RELXILL_NK in which the accretion disk has a finite thickness rather than being infinitesimally thin. We employ the accretion disk geometry proposed by Taylor & Reynolds (2018) and we construct relativistic reflection models for different values of the mass accretion rate of the black hole. We apply the new model to high quality Suzaku data of the X-ray binary GRS 1915+105 to explore the impact of the thickness of the disk on tests of the Kerr metric., 19 pages, 14 figures. v2: refereed version

In a previous paper, one of us calculated iron K$\alpha$ line profiles emitted from possible accretion disks around traversable wormholes as a first step to use X-ray reflection spectroscopy to search for astrophysical wormholes in active galactic nuclei. In the present paper, we extend that work and construct an XSPEC model for the whole relativistic reflection spectrum. We apply our model to XMM-Newton and NuSTAR observations of the supermassive object in MCG-6-30-15 and we check whether these observations prefer the hypothesis that the central body is a Kerr black hole or a traversable wormhole. We find that the two models provide equally good fits, so with the available data we cannot distinguish the black hole and wormhole scenarios., Comment: 10 pages, 7 figures. v2: refereed version

We analyze simultaneous observations with NuSTAR and Swift of the black hole binary GX 339-4 in which we clearly detect both a strong thermal component and prominent relativistic reflection features. We employ NKBB and RELXILL_NK, which are the state of the art of, respectively, the thermal and reflection models to test the Kerr black hole hypothesis. We obtain unprecedented precise measurements of the Johannsen deformation parameter $\alpha_{13}$: $\alpha_{13} = -0.012_{-0.039}^{+0.011}$ (lamppost coronal geometry) and $\alpha_{13} = -0.010_{-0.018}^{+0.024}$ (broken power-law emissivity profile) at a 90% confidence level, where the Kerr metric corresponds to $\alpha_{13} = 0$. We investigate the systematic uncertainties by fitting the data with different models., Comment: 10 pages, 5 figures. v2: refereed version

Asymptotically safe quantum gravity is a promising candidate scenario to provide a UV extension for the effective quantum field theory of Einstein's gravity. The theory has its foundations on the very successful framework of quantum field theory, which has been extensively tested for electromagnetic and nuclear interactions. However, observational tests of asymptotically safe quantum gravity are more challenging. Recently, a rotating black hole metric inspired by asymptotically safe quantum gravity has been proposed, and this opens the possibility of astrophysical tests of the theory. In the present paper, we show the capabilities of X-ray reflection spectroscopy to constrain the inverse dimensionless fixed-point value $\gamma$ from the analysis of a Suzaku observation of the X-ray binary GRS 1915+105. We compare these constraints with those obtained from black hole imaging., Comment: 11 pages, 6 figures. v2: refereed version

Characterizing variation in reproductive output is foundational to understanding the demography of a population and determining management strategies. Doing so is paramount when the species of interest is threatened with extinction. The red-crowned roofed turtle (Batagur kachuga) and the three-striped roofed turtle (Batagur dhongoka) are severely threatened by overharvesting and habitat loss. Despite their imperiled status, there are very few published studies on species ecology and life history to enable effective conservation; the 3 published studies that are available were completed nearly 3 decades ago. We herein provide information on variation in reproductive output for these turtles in the Chambal River of North India. Generalized linear models and analyses of variance were fitted to data on nesting density, fecundity, and egg volume. The number of nests showed an overall decline across 3 seasons (2007, 2008, and 2010) over a 4-yr duration with the highest number of nests observed in the m...

The present study was undertaken to evaluate the effects of silver nitrate (AgNO 3 ) and biosynthesized silver nanoparticle (AgNps) on Cucumis sativus L seedlings. Results indicated that both the forms of silver significantly reduced the growth which may be accompanied due to increased accumulation of silver in plants (4708.2 ± 108.75 mg/kg). Both the treatments showed steep reduction (> in AgNO 3 treatments) in photosynthetic performance, total chlorophyll, carotenoids and total protein content and significantly ( P 2 O 2 , SOR; i.e. > in AgNO 3 treatment). The histochemical observations (NBT & DAB) of oxidative stress markers (H 2 O 2 and O 2 − ) were also in accordance with their total estimation of H 2 O 2 and O 2 − in both the treatments. Chlorophyll florescence parameters were also significantly ( P 3 and AgNps treatments and showed remarkable modifications.Though, both the treatments (AgNO 3 and AgNps) showed anatomical impacts on the root cortical cells, however, degeneration of cortical cells and disintegration of endodermis in AgNO 3 treatments were more prominent. Taking impacts of the both forms of silver together, present study suggests that the AgNO 3 is more toxic than AgNPs while potential risks of both forms is critical on the growth and development of Cucumis seedlings. We suggest further studies to explore the underlying mechanisms and to understand the effective levels of both forms of silver to be used in sustaining agricultural productions.

A simple and facile way of using biogenic silver nanoparticles (BSNP) (10–20 nm) was developed for wound healing acceleration and suppression of wound infections. The BSNP were formulated in an ointment base, and the study to accelerate the wound healing process was conducted in a rat. The pH of the BSNP ointment, pH 6.8 ± 0.5, lies in normal pH range of the human skin, with good spreadability and diffusibility. The wound closure rate, as a percentage, was highest at day 3 for a BSNP ointment-treated wound at 22.77 ± 1.60%, while in an untreated control the rate was 10.99 ± 1.74%, for Betadine 14.73 ± 2.36% and for Soframycin 18.55 ± 1.37%, compared with day 0. A similar pattern of wound closure rate was found at days 7 and 11. The antibacterial activity of BSNP was evaluated against wound-infection-causing bacteria Staphylococcus aureus, Pseudomonas aeruginosa and Escherichia coli by the agar diffusion method. The total bacterial counts in the wound area were enumerated by the colony forming unit method. The lowest number of bacterial counts was found in the BSNP-treated wound compared with the other groups. BSNP treatment at 7.5% concentration enhanced migration of fibroblasts in a scratch assay. These findings reveal BSNP as an efficient contrivance for wound healing acceleration and as an eco-friendly alternative therapeutic antimicrobial agent.

We extend our previous work on tests of the Kerr black hole hypothesis using X-ray reflection spectroscopy and we infer observational constraints on the Johannsen deformation parameter $\epsilon_3$. We analyze a NuSTAR observation of the stellar-mass black hole in GS 1354-645, Suzaku data of the supermassive black holes in Ark 564, 1H0419-577, and PKS 0558-504, and some simultaneous XMM-Newton and NuSTAR observations of the supermassive black hole in MCG-6-30-15. All our measurements of $\epsilon_3$ are consistent with the Kerr metric and we find quite strong constraints from Ark 564 and MCG-6-30-15. We discuss the implications of our results and the next steps to improve our tests.

X-ray reflection spectroscopy is a promising technique for testing general relativity in the strong field regime, as it can be used to test the Kerr black hole hypothesis. In this context, the parametrically deformed black hole metrics proposed by Konoplya, Rezzolla \& Zhidenko (Phys. Rev. D93, 064015, 2016) form an important class of non-Kerr black holes. We implement this class of black hole metrics in \textsc{relxill\_nk}, which is a framework we have developed for testing for non-Kerr black holes using X-ray reflection spectroscopy. We perform a qualitative analysis of the effect of the leading order strong-field deformation parameters on typical observables like the innermost stable circular orbits and the reflection spectra. We also present the first X-ray constraints on some of the deformation parameters of this metric, using \textit{Suzaku} data from the supermassive black hole in Ark~564, and compare them with those obtained (or expected) from other observational techniques like gravitational waves and black hole imaging., Minor updates. Published at Phys. Rev. D 102, 124071 (2020)

We present the study of a sample of seven "bare" active galactic nuclei (AGN) observed with Suzaku. We interpret the spectrum of these sources with a relativistic reflection component and we employ our model RELXILL_NK to test the Kerr nature of their supermassive black holes. We constrain the Johannsen deformation parameters $\alpha_{13}$ and $\alpha_{22}$, in which the Kerr metric is recovered when $\alpha_{13} = \alpha_{22} = 0$. All our measurements are consistent with the hypothesis that the spacetime geometry around these supermassive objects is described by the Kerr solution. For some sources, we obtain quite strong constraints on $\alpha_{13}$ and $\alpha_{22}$ when compared to those found in our previous studies. We discuss the systematic uncertainties in our tests and the implications of our results., Comment: 15 pages, 12 figures. v2: refereed version

We present and analyze the variability of three Seyfert galaxies on intra-day timescales. We have analyzed in a uniform manner the 38 longest (>30 ks) observations made for NGC 4051, MCG-06–30–15 and NGC 4151 by XMM-Newton between 2000 and 2015. The nuclei were quite active during essentially all of these observations and the overall X-ray fluxes (0.3–10 keV) varied by an order of magnitude. Most of the observations do appear to show characteristic timescales, estimated through their auto-correlation functions, ranging between ∼2.9 ks and ∼45.3 ks. The hard (2–10 keV) and soft (0.3–2.0 keV) bands are very well correlated but consideration of their hardness ratios shows that the sources typically soften during flares. We also provide new estimates of the central black hole masses for these three AGNs that support the hypothesis that Narrow Line Seyfert 1 galaxies have relatively small central black holes.

In this paper, the impact of thermally induced self-doping and phase transformation in TiO2 based resistive random-access memory (ReRAM) is discussed. Instead of a thin film, a vertically aligned one-dimensional TiO2 nanotube array (TNTA) was used as a switching element. Anodic oxidation method was employed to synthesize TNTA, which was thermally treated in the air at 350 °C followed by further annealing from 350 °C to 650 °C in argon. Au/TiO2 nanotube/Ti resistive switching devices were fabricated with porous gold (Au) top electrode. The x-ray diffraction results along with Raman spectra evidently demonstrate a change in phase of crystallinity from anatase to rutile, whereas photoluminescence spectra revealed the self-doping level in terms of oxygen vacancies (OV) and Ti interstitials (Tii) as the temperature of thermal treatment gets increased. The electrical characterizations establish the bipolar and electroforming free resistive switching in all the samples. Among those, the ReRAM sample S3 thermally treated at 550 °C displayed the most effective resistive switching properties with R OFF/R ON of 102 at a read voltage of −0.6 V and a SET voltage of −2.0 V. Moreover, the S3 sample showed excellent retention performance for over 106 s, where stable R OFF/R ON ≈ 107 was maintained throughout the experiment.

The increasing interest in flexible electronics and flexible displays raises questions regarding the inherent mechanical properties of the electronic materials used. Here, the mechanical behavior of thin-film transistors used in active-matrix displays is considered. The change of electrical performance of thin-film semiconductor materials under mechanical stress is studied, including amorphous oxide semiconductors. This study comprises an experimental part, in which transistor structures are characterized under different mechanical loads, as well as a theoretical part, in which the changes in energy band structures in the presence of stress and strain are investigated. The performance of amorphous oxide semiconductors are compared to reported results on organic semiconductors and covalent semiconductors, i.e., amorphous silicon and polysilicon. In order to compare the semiconductor materials, it is required to include the influence of the other transistor layers on the strain profile. The bending limits are investigated, and shown to be due to failures in the gate dielectric and/or the contacts. Design rules are proposed to minimize strain in transistor stacks and in transistor arrays. Finally, an overview of the present and future applications of flexible thin-film transistors is given, and the suitability of the different material classes for those applications is assessed.

The present study investigates the impact of different Cr(VI) (50–200 µM) treatments on Cucumis sativus L. seedlings which is worldwide grown in river catchments. Chromium (VI) treatments showed significant (P

Due to the adverse impacts of climate change on earth systems the research in this field has been profoundly taken a part in all scientific arenas since last few decades. The deleterious impacts of climate change on agricultural production are challenging the food security of the world in terms of quantity and quality both. Wheat, rice, maize, vegetables, fruits and fish-food provide food security for more than half of the world and are under immense pressure of changing climate. This review is an overview of the significant impacts associated with climate change on these food sources. In present synthesis, various phenological, physiological, biochemical and reproductive responses in major food crops have been summarized emphasizing the vulnerable growth and development stages. Winter and summer sensitivity responses, and morpho-biochemical acclimation patterns have also been summarized. Sustenance in wheat and rice production is evident but impacts of increasing temperatures are negating this on bio-physiological level impacts. Maize crops are experiencing more impacts on yield as compared to wheat and rice. Fruits and vegetable production is highly vulnerable to climate change at their reproductive stages and also due to more disease prevalence. Fisheries as a critical animal food source; is in extreme danger as apparent changes in their habitat and unmanageable environmental conditions are producing extreme losses. This review also provides an account of stress responses and useful adaptive measures. This synthesis may be helpful in understanding manifold dimensions and interactions of climate change impacts on selected major food sources of the world.

Early blight, caused by Alternaria solani is one of the most devastating disease affecting to the Solanum lycopersicum (tomato), reducing its productivity by 80%. The present study illustrates the synthesis of nanoemulsion using peppermint oil for potent antimicrobial activity against A. solani. A peppermint oil based nanoemulsion (PNE) was synthesized which was further characterized by Dynamic Light Scattering and Transmission Electron Microscopy. The nano-droplets present in nanoemulsion were spherical in shape with average size

The iron line and the continuum-fitting methods are currently the two leading techniques for measuring black hole spins with electromagnetic radiation. They can be naturally extended for probing the spacetime geometry around black holes and testing general relativity in the strong field regime. In the past couple of years, there has been significant work to use the iron line method to test the nature of black holes. In this Letter, we use the continuum-fitting method and we show its capability of constraining the spacetime geometry around black holes by analyzing 17 RXTE data of the X-ray binary LMC X-1., Comment: 7 pages, 3 figures. v2: refereed version

Astrophysical black hole systems are the ideal laboratories for testing Einstein's theory of gravity in the strong field regime. We have recently developed a framework which uses the reflection spectrum of black hole systems to perform precision tests of general relativity by testing the Kerr black hole hypothesis. In this paper, we analyze XMM-Newton and NuSTAR observations of the supermassive black hole in the Seyfert 1 galaxy MCG-06-30-15 with our disk reflection model. We consider the Johannsen metric with the deformation parameters $\alpha_{13}$ and $\alpha_{22}$, which quantify deviations from the Kerr metric. For $\alpha_{22} = 0$, we obtain the black hole spin $0.928 < a_* < 0.983$ and $-0.44 < \alpha_{13} < 0.15$. For $\alpha_{13} = 0$, we obtain $0.885 < a_* < 0.987$ and $-0.12 < \alpha_{22} < 1.05$. The Kerr solution is recovered for $\alpha_{13} = \alpha_{22} = 0$. Thus, our results include the Kerr solution within statistical uncertainties. Systematic uncertainties are difficult to account for, and we discuss some issues in this regard., Comment: 10 pages, 7 figures. v2: title slightly changed, arXiv version shorter than published version

We detected a possible quasi-periodic oscillation (QPO) of ~ 71 days in the 0.1 -- 300 GeV gamma-ray Fermi-LAT light curve of the high redshift flat spectrum radio quasar B2 1520+31. We identify and confirm that quasi-period by Lomb Scargle periodogram (LSP), and weighted wavelet z-transform (WWZ) analyses. Using this QPO period, and assuming it originates from accretion-disc fluctuations at the innermost stable circular orbit, we estimate the central supermassive black hole mass to range between ~ 5.4 * 10$^{9}$ M$_{\odot}$ for a non-rotating black hole and ~ 6.0 * 10$^{10}$ M$_{\odot}$ for a maximally rotating black hole. We briefly discuss other possible radio-loud active galactic nuclei emission models capable of producing a gamma-ray QPO of such a period in a blazar., 6 pages, 4 figures, Submitted to MNRAS

Einstein's theory of general relativity was proposed over 100 years ago and has successfully passed a large number of observational tests in the weak field regime. However, the strong field regime is largely unexplored, and there are many modified and alternative theories that have the same predictions as Einstein's gravity for weak fields and present deviations when gravity becomes strong. RELXILL_NK is the first relativistic reflection model for probing the spacetime metric in the vicinity of astrophysical black holes and testing Einstein's gravity in the strong field regime. Here we present our current constraints on possible deviations from Einstein's gravity obtained from the black holes in 1H0707-495, Ark 564, GX 339-4, and GS 1354-645., 8 pages, 6 figures. Talk given at the "International Conference on Quantum Gravity" (26-28 March 2018, Shenzhen, China). To appear in the conference proceedings

Einstein's theory of general relativity has been extensively tested in weak gravitational fields, mainly with experiments in the Solar System and observations of radio pulsars, and current data agree well with the theoretical predictions. Nevertheless, there are a number of scenarios beyond Einstein's gravity that have the same predictions for weak fields and present deviations only when gravity becomes strong. Here we try to test general relativity in the strong field regime. We fit the X-ray spectrum of the supermassive black hole in Ark 564 with a disk reflection model beyond Einstein's gravity, and we are able to constrain the black hole spin $a_*$ and the Johannsen deformation parameters $\alpha_{13}$ and $\alpha_{22}$ separately. For $\alpha_{22} = 0$, we find $a_* > 0.96$ and $-1.0 < \alpha_{13} < 0.2$ with a 99% confidence level. For $\alpha_{13} = 0$, we get $a_* > 0.96$ and $-0.1 < \alpha_{22} < 0.9$ with a 99% confidence level. Our measurements are thus consistent with the hypothesis that the supermassive compact object in Ark 564 can be described by the Kerr metric., Comment: 7 pages, 2 figures. v2: refereed version

We found a possible ~ 1 hour quasi-periodic oscillation (QPO) in a ~ 55 ks X-ray observation of the narrow-line Seyfert 1 galaxy MCG--06--30--15 made with the XMM-Newton EPIC/pn detector in the energy range 0.3 -- 10 keV. We identify a total modulation of ~ 16% in the light curve and find a $\simeq$ 3670~s quasi-period using Lomb-Scargle periodogram (LSP) and weighted wavelet Z-transform (WWZ) techniques. Our analyses of eight light curves of MCG--06--30--15, indicated the possible presence of an oscillation during one of them. The LSP indicates a statistically significant ($\simeq$ 3$\sigma$) QPO detection. A WWZ analysis shows that the signal at this possible roughly 3670s period is present, and rather persistent, throughout the observation; however, a signal around 8735s is more persistent. We briefly discuss models that can produce X-ray QPOs with such periods in narrow line Seyfert 1 galaxies, as both other claimed QPO detections in this class of AGN had very similar periods., Comment: 5 pages, 4 figures, Published in A&A Letters

© 2017 The Authors. New Phytologist © 2017 New Phytologist Trust Developmental responses to auxin are regulated by facilitated uptake and efflux, but detailed molecular understanding of the carrier proteins is incomplete. We have used pharmacological tools to explore the chemical space that defines substrate preferences for the auxin uptake carrier AUX1. Total and partial loss-of-function aux1 mutants were assessed against wild-type for dose-dependent resistance to a range of auxins and analogues. We then developed an auxin accumulation assay with associated mathematical modelling to enumerate accurate IC50 values for a small library of auxin analogues. The structure activity relationship data were analysed using molecular field analyses to create a pharmacophoric atlas of AUX1 substrates. The uptake carrier exhibits a very high level of selectivity towards small substrates including the natural indole-3-acetic acid, and the synthetic auxin 2,4-dichlorophenoxyacetic acid. No AUX1 activity was observed for herbicides based on benzoic acid (dicamba), pyridinyloxyacetic acid (triclopyr) or the 6-arylpicolinates (halauxifen), and very low affinity was found for picolinic acid-based auxins (picloram) and quinolinecarboxylic acids (quinclorac). The atlas demonstrates why some widely used auxin herbicides are not, or are very poor substrates. We list molecular descriptors for AUX1 substrates and discuss our findings in terms of herbicide resistance management.

We discuss in this paper the present state and future perspectives of thin-film oxide transistors for flexible electronics. The application case that we focus on is a flexible health patch containing an analog sensor interface as well as digital electronics to transmit the acquired data wirelessly to a base station. We examine the electronic performance of amorphous Indium-Gallium-Zinc-Oxide (a-IGZO) during mechanical bending. We discuss several ways to further boost the electronic transistor performance of n-type amorphous oxide semiconductors, by modifying the semiconductor or by improving the transistor architecture. We show analog and digital circuits constructed with several architectures, all based on n-type-only amorphous oxide technology. From circuit point of view, the discovery of a p-type amorphous semiconductor matching known n-type amorphous semiconductors would be of great importance. The present best-suited p-type is SnO, but it is poly-crystalline in nature and shows some ambipolarity due to the presence of n-type SnO2. In search of a better p-type semiconductor, preferably amorphous, we present recent insights into the band structure of potential amorphous oxide p-type semiconductors.

Nanotechnology is a cutting-edge field of science with the potential to revolutionize today’s technological advances including industrial applications. It is being utilized for the welfare of mankind; but at the same time, the unprecedented use and uncontrolled release of nanomaterials into the environment poses enormous threat to living organisms. Silver nanoparticles (AgNPs) are used in several industries and its continuous release may hamper many physiological and biochemical processes in the living organisms including autotrophs and heterotrophs. The present review gives a concentric know-how of the effects of AgNPs on the lower and higher autotrophic plants as well as on heterotrophic microbes so as to have better understanding of the differences in effects among these two groups. It also focuses on the mechanism of uptake, translocation, accumulation in the plants and microbes, and resulting toxicity as well as tolerance mechanisms by which these microorganisms are able to survive and reduce the effects of AgNPs. This review differentiates the impact of silver nanoparticles at various levels between autotrophs and heterotrophs and signifies the prevailing tolerance mechanisms. With this background, a comprehensive idea can be made with respect to the influence of AgNPs on lower and higher autotrophic plants together with heterotrophic microbes and new insights can be generated for the researchers to understand the toxicity and tolerance mechanisms of AgNPs in plants and microbes.

In this study, the authors report on high-quality amorphous indium-galliunv-zinc oxide thinfilm transistors (TFTs) based on a single-source dual-layer concept processed at temperatures down to ISCC. The dual-layer concept allows the precise control of local charge carrier densities by varying the 02/Ar gas ratio during sputtering for the bottom and top layers. Therefore, extensive annealing steps after the deposition can be avoided. In addition, the dual-layer concept is more robust against variation of the oxygen flow in the deposition chamber. The charge carrier density in the TFT channel is namely adjusted by varying the thickness of the two layers whereby the oxygen concentration during deposition is switched only between no oxygen for the bottom layer and very high concentration for the top layer. The dual-layer TFTs are more stable under bias conditions in comparison with single-layer TFTs processed at low temperatures. Finally, the applicability of this dual-layer concept in logic circuitry such as 19-stage ring oscillators and a TFT backplane on polyethylene naphthalate foil containing a quarter video graphics array active-matrix organic lightemitting diode display demonstrator is proven.

In this paper, we constrain dark energy models using a compendium of observations at low redshifts. We consider the dark energy as a barotropic fluid, with the equation of state a constant as well the case where dark energy equation of state is a function of time. The observations considered here are Supernova Type Ia data, Baryonic Acoustic Oscillation data and Hubble parameter measurements. We compare constraints obtained from these data and also do a combined analysis. The combined observational constraints put strong limits on variation of dark energy energy density with redshift. For varying dark energy models, the range of parameters preferred by the supernova type Ia data is in tension with the other low redshift distance measurements., 15 pages, More detailed discussion

Industrialization, urbanization, and agricultural practices have created noxiousity of xenobiotics compounds in the atmosphere, seriously affecting the health of all living systems. The hazards created by such compounds are alarming and must be controlled/treated through bioremediation, a safe, economical, and rapid method for the treatment of almost all types of xenobiotic compounds. Microbial systems mainly bacteria, fungi, yeast, actinomycetes, and algae have diversified enzyme system for metabolizing such compounds into nontoxic forms and mineralizing up to the level of plant nutrients. The knowledge of such xenobiotics compounds, their existence and persistence in natural ecosystem, risk created by such compounds, biomagnifications, and biodegradation/bioremediation are essential for its effective control from different ecosystems. A very comprehensive classification of compounds and their degrading/metabolizing microbial enzymes along with the list of microorganisms has been discussed which is very essential for the environmental scientists, microbiologist, biochemist as well as agricultural scientist for their awareness and adopting remedial measures. Several new xenobiotic compounds are being synthesized in the natural ecosystem through polymerization and other organic reactions which must be identified and treated with specific suitable microbial consortia of different tolerance capabilities to temperature, pH, O2, etc. The current scenario of bioremediation of xenobiotics compounds is greatly facilitated by the consortia of competent strain of various groups of microorganisms having the ability to coexist for longer periods without affecting their growth and metabolism, resulting in better remediation from natural ecosystem. The industrial effluents and solid waste treatment as well as field application of such microorganisms are showing effective results; therefore, large-scale cultivation and long-term preservation of these microorganisms either alone or in consortium are another area of research for safe and effective applications.

We investigate the mechanism of charge transport in indium gallium zinc oxide (a-IGZO), an amorphous metal-oxide semiconductor. We measured the field-effect mobility and the Seebeck coefficient (S=ΔV/ΔT) of a-IGZO in thin-film transistors as a function of charge-carrier density for different temperatures. Using these transistors, we further employed a scanning Kelvin probe-based technique to determine the density of states of a-IGZO that is used as the basis for the modeling. After comparing two commonly used models, the band transport percolation model and a mobility edge model, we find that both cannot describe the full properties of the charge transport in the a-IGZO semiconductor. We, therefore, propose a model that extends the mobility edge model to allow for variable range hopping below the mobility edge. The extended mobility edge model gives a superior description of the experimental results. We show that the charge transport is dominated by variable range hopping below, rather than by bandlike transport above the mobility edge. © 2012 American Physical Society.

Thin-film transistors (TFTs), which use zinc oxide (ZnO) as an active layer, were fabricated and investigated in detail. The transport properties of ZnO deposited by spray pyrolysis (SP) on a TFT structure are studied in a wide range of temperatures, electrical conditions (i.e., subthreshold, above-threshold linear, and saturation regions), and at different channel lengths. It is shown that ZnO deposited by SP is a nanocrystalline material; its field-effect mobility is temperature activated and increases with carrier concentration. On the basis of this analysis, we propose the multiple-trapping-and-release (MTR)-transport mechanism to describe the charge transport in ZnO. By means of numerical simulations, we prove that MTR is a suitable approach, and we calculate the density of states. We show that the tail states extend in a wide range of energy and that they strongly influence the transport properties. Finally, an analytical physical-based DC model is proposed and validated with experiments and numerical simulations. The model is able to reproduce the measurements on devices with different channel length in a wide range of bias voltages and temperatures by means of a restricted number of parameters, which are linked directly to the physical properties of the ZnO semiconductor. For the first time, the charge transport in the ZnO is investigated by means of the MTR, and a consistent analysis based on experiments, numerical simulations, and analytical modeling is provided.

A target application for plastic RFID tags is Electronic Product Coding (EPC). The EPC-specifications set some demanding requirements for RFID tags. In this work, we review the work that has been done to fulfill some of these specifications. We describe a complete 64-bit RFID tag that is inductively-coupled at a base carrier frequency of 13.56 MHz, and transmits data at rates below 1 kb/s. Next, we demonstrate 8-bit RFID transponder chips having data rates of 50 kb/s, an important milestone for organic RFID tags in view of EPC specifications.

Complementary thin-film transistor circuits composed of 6,13-bis(triisopropyl-silylethynyl) pentacene (TIPS-PEN) and a rylene carboxylic diimide derivative for p- and n-channel thin-film transistors (TFTs) were fabricated on flexible foils. The so-called staggered TFT configuration is used, meaning that the semiconductors layers are deposited last. The work-function of the injecting gold electrodes were modified using several self-assembled monolayers (SAMs). For optimized contacts the mobility of the n- and p-channel TFTs was 0.5 cm 2/Vs and 0.2 cm 2/Vs, respectively. Strongly degraded performance is obtained when the n-channel material was printed on contacts optimized for the p-channel TFT, and vice versa. This illustrates that for CMOS circuits we need careful work-function engineering to allow proper injection for both electrons and holes. We show for the first time that by using a bimolecular mixture for the SAM we can systematically vary the work function, and demonstrate how this affects the performance of discrete n-type and p-type transistors, as well as CMOS inverters and ring oscillators. Under optimal processing conditions we realized complementary 19-stage ring oscillators with 10 μs stage delay operating at 20 V.

Multibit memory devices based on the ferroelectric copolymer P(VDF-TrFE) (poly-(vinylidenefluoride-trifluoroethylene)) are presented. Multilevel microstructures are fabricated by thermal imprinting of spin-coated ferroelectric polymer film using a rigid Si template. Multibit storage in capacitors and thin-film transistor memory is realized by implementing imprinted ferroelectric polymer films as the insulator and gate dielectric layers, respectively. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Short-channel zinc oxide (ZnO) thin-film transistors (TFTs) are investigated in a wide range of temperatures and bias conditions. Scaling down the channel length, the TFT performance is seriously affected by contact resistances, which depend on gate voltage and temperature. To account for the contact resistances, the transistor is ideally split in three parts. The contact regions are modeled as two separate transistors with a fixed channel length and an exponential distribution of localized states, whereas the channel is treated as reported in Part I. The overall model reproduces the measured characteristics at different channel length, with a single set of physical and geometrical parameters. It can be readily implemented in a circuit simulator. Numerical simulations confirm the validity of the model approach and are used to evaluate the impact of nonidealities at the electrode/semiconductor interface.

In this work a technology to fabricate low-voltage amorphous gallium-indium-zinc oxide thin film transistors (TFTs) based integrated circuits on 25 mu m foils is presented. High performance TFTs were fabricated at low processing temperatures (< 150 degrees C) with field effect mobility around 17 cm(2)/V s. The technology is demonstrated with circuit building blocks relevant for radio frequency identification applications such as high-frequency functional code generators and efficient rectifiers. The integration level is about 300 transistors. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3579529] ispartof: Applied Physics Letters vol:98 issue:16 status: published

In this chapter, fully integrated organic RFID tags are demonstrated. These tags are inductively-coupled at a base frequency of 13.56 MHz and can be read out at distances up to 10 cm, which is the expected readout distance for proximity readers. We also demonstrate next generation transponder chips, fabricated in a dual-gate technology. The additional gate, backgate, is used to control the threshold voltage and allows integration into more robust unipolar, dual-VT transponder chips. Finally, we realized an 8-bit transponder chip having data rates that are EPC-compatible. This has been achieved in our thin-film transistor technology by introducing a high-k Al2O 3 gate dielectric, by scaling the channel lengths down to 2 mm and by reducing the overlap capacitance of the parasitic source-gate and drain-gate capacitors. © 2011 Springer Science+Business Media B.V.

Dual gate organic thin film transistors based on solution processable fluorinated 5,11 bis(triethylsilylethynyl) anthradithiophene semiconductor were fabricated. Top (Teflon, εr =2.1) and bottom (SiO2, εr =3.9) gate dielectrics with different dielectric constants were chosen. Top gate mobilities >1 cm2 /Vs and bottom gate mobilities >0.1 cm2/V s were achieved. Temperature dependent mobility measurements show thermally activated charge transport and a comparative analysis is performed in the framework of two models representing polaron hopping as well as hopping in Gaussian density of states (DOS), respectively. © 2011 American Institute of Physics.

A Sec14-nodulin protein model is used to identify the nodulin domain as a novel phosphoinositide effector module with a role in controlling lateral organization of phosphoinositide. The domain organization of Sec14-nodulin proteins suggests a versatile principle for the bit mapping of membrane surfaces into high-definition lipid-signaling screens., Polarized membrane morphogenesis is a fundamental activity of eukaryotic cells. This process is essential for the biology of cells and tissues, and its execution demands exquisite temporal coordination of functionally diverse membrane signaling reactions with high spatial resolution. Moreover, mechanisms must exist to establish and preserve such organization in the face of randomizing forces that would diffuse it. Here we identify the conserved AtSfh1 Sec14-nodulin protein as a novel effector of phosphoinositide signaling in the extreme polarized membrane growth program exhibited by growing Arabidopsis root hairs. The data are consistent with Sec14-nodulin proteins controlling the lateral organization of phosphatidylinositol 4,5-bisphosphate (PtdIns(4,5)P2) landmarks for polarized membrane morphogenesis in plants. This patterning activity requires both the PtdIns(4,5)P2 binding and homo-oligomerization activities of the AtSfh1 nodulin domain and is an essential aspect of the polarity signaling program in root hairs. Finally, the data suggest a general principle for how the phosphoinositide signaling landscape is physically bit mapped so that eukaryotic cells are able to convert a membrane surface into a high-definition lipid-signaling screen.