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Mineral matter in coals has been found to host valuable elements including germanium, lithium and rare-earth elements (REE), but such content of Australian coals remains under-explored. The aim of this paper is to provide a proof-of-concept study that determines elemental concentrations in the mineral matter of the high-ash, Fort Cooper Coal Measures (FCCM), Bowen Basin, Queensland. Coal in the FCCM has good coking properties but has not been extensively explored owing to its high ash content. This study performs a preliminary assessment of the elements from the coal portion that would typically become waste after washing or combustion. Given that the needs for industrial extraction methods will change over time, cataloguing and documenting the elemental composition of coal may assist future development of multiple products for the benefit of both the coal and mineral industries. This preliminary study has revealed similar elevations of REE and higher-than-average crustal concentrations of lithium, bismuth and scandium in some of the samples. Further analyses will be required on a larger dataset to better understand elemental associations and explore spatial patterns of elemental content that may indicate localised enrichments. Understanding the potential of valuable elements in the FCCM may stimulate interest in multiple-product-coal (or elemental-coal) mining in this under-exploited resource and further encourage the reduction of waste from other Australian coals at the wash-plant stage. [ABSTRACT FROM AUTHOR]

Inaccuracies in spatial modelling of coal properties can impact coal resource and reserve estimates. Geostatistical methods which account for compositional data have previously been recommended as a preferred method for modelling of coal properties. These methods can quantify uncertainty, can use auxiliary information to improve estimates, and ensure that compositional data (such as coal proximate analysis) is modelled in a mathematically consistent way. However, geostatistical methods have drawbacks in that have rigid statistical assumptions about the distribution and stationarity of the target variable and require variogram interpretation which can be onerous when then number of domains and target variables are numerous. Due to these drawback, inverse distance weighting (a simple deterministic method) remains the most popular method for modelling coal properties in Australian resource estimates. To address the drawbacks of geostatistical methods, a machine learning approach based on the quantile regression forest algorithm is proposed as an alternative method to spatially model coal properties. This newly proposed method, accounts for spatial arrangement of data, requires minimal pre-processing steps, can quantify uncertainty and can easily incorporate auxiliary information of various types. To evaluate the performance of this method, the accuracy of predictions of coal proximate analysis properties, and coal density are compared to the predictions of inverse distance weighting and regression kriging. All methods incorporate isometric log ratio transform and back-transform of data in order to account for the compositional nature of coal proximate analysis. Data from an active coal mine in the Bowen Basin, Queensland Australia was used as basis of the results. A unique feature of the mine site in this basin is the presence of intrusion which impacts coal quality properties to various degrees. Using evaluation metrics from leave-one-out cross-validation, this paper demonstrates that quantile regression forest has higher accuracy, lower bias and higher precision than inverses distance weighting across all coal properties. The paper also shows that results of the new method are very similar or better than regression kriging. It is also demonstrated that the prediction maps produced by quantile regression forest could be used to more accurately map out coal impacted by intrusion compared to inverse distance weighting, and that inverse distance weighting overestimates the impact of intrusion and intrusion extent. A drawback of the method compared to inverse distance weighting, is that it is more computationally demanding, less intuitive and is currently not available in existing geological packages. [ABSTRACT FROM AUTHOR]

Abstract: Late Permian age samples of black coal from the coeval Bandanna Formation and Baralaba Coal Measures of Queensland''s Bowen Basin, as well as Carboniferous coal from Germany''s Ruhr Basin, were investigated. This paper presents scanning electron microscope (SEM) analysis of the mode of occurrence of minerals within these coals, and characterisation of the natural fractures present within the samples. The coal samples located proximal to orogenic fronts in both basins are structurally complex, with multiple generations of mineralisation evident. Stable isotope analyses of carbonates from selected samples indicate that methanogenesis-related CO2 reduction has occurred at two of the Bowen Basin sampling locations. Ankerite precipitated from a magmatic fluid or basinal brine is associated with significant sulphide mineralisation within brecciated Ruhr coal proximal to major fault intersections with anticlines, and has been meteorically altered to ferroan calcite and sulphates in coal from immediately below the Carboniferous/Cretaceous unconformity. Similar alteration has occurred within a Bowen Basin coal sample close to the present day land surface. Variation of mineralisation within both the cleats and the coal matrix occurs on a fine scale, with crystals of multiple mineral species often being present within micrometres of each other. [Copyright &y& Elsevier]