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The paper presents the results of experimental study of the solubility (VLE-properties) of crystalline tricosane in pure and modified supercritical carbon dioxide over the temperature range from (308.15 to 315.15) K and at the pressures from (8.00 to 20.32) MPa using the dynamic method. Modification of carbon dioxide fluid was performed by adding several organic solvents, such as dimethylsulfoxide, ethanol, acetone, and chloroform. It was found that using the fluid co-solvents at the concentration of 5 wt. % improves the tricosane solubility by a factor of two. The measurement results have been described by the Penga–Robinson equation of state. [ABSTRACT FROM AUTHOR]

Of the 57 species of the economically important genus Hypericum (St. John's Wort; Clusiaceae) occurring in China, only a small percentage have been previously phytochemically investigated. As part of our continuing research on the phytochemistry of Hypericum, the chemical compositions of volatiles isolated from 12 Chinese species were determined. Volatile constituents were isolated by microdistillation of dried and ground aerial material from flowering plants and subsequently analyzed by GC/MS. The major component(s) were identified as follows: ar-curcumene (12.6%) and β-selinene (16.3%) in H. acmosepalum; γ-muurolene (11.3%), β-selinene (16.3%) and caryophyllene oxide (18.7%) in H. beanii; α-terpineol (11.5%) and β-pinene (29.2%) in H. calycinum; cis-eudesma-6,11-diene (11.4%) in H. choisyanum; α-pinene (10.4%) and caryophyllene oxide (12.7%) in H. forrestii; cis-β-guiaene (10.7%) and γ-muurolene (12.4%) in H. kouytchense; β-selinene (11.4%) and eudesmadienone (10.8%) in H. lancasteri; cuparene (24.8%) and γ-muurolene (16.8%) in H. leschenaultii; tricosane (13.3%) and myrcene (10.4%) in H. monogynum; β-selinene (14.7%) in H. patulum; β-selinene (18.5%) in H. pseudohenryi; and γ-muurolene (10.7%) and δ-cadinene (10.2%) in H. X moserianum. [ABSTRACT FROM AUTHOR]

Chemical signals originating from the ovaries of gravid females of Musca domestica (Diptera: Cyclorrhapha: Muscidae) attract ovipositing females to common egg-laying sites. Behavioral experiments indicated that females preferred to oviposit in fermented wheat bran containing ovaries from reproductively mature houseflies. Females preferred to oviposit in fermented wheat bran than wet wheat bran. This effect was additive with the attraction to housefly ovaries. Solvent extracts from housefly ovaries were attractive to gravid females. Extracts obtained with hexane were most attractive to gravid females for egg laying, and extracts obtained with ethyl acetate attracted more egg laying than extracts obtained by dichloromethane. Gas chromatography (GC) and gas chromatography coupled with mass spectrometry (GC–MS) analysis showed that tricosane and (Z)-9-tricosene were the main components of the hexane extracts. Both tricosane and (Z)-9-tricosene were shown to elicit dose-dependent aggregation of gravid females in oviposition bioassays, but high doses of either chemical were not attractive. [ABSTRACT FROM AUTHOR]

The essential oil of fresh aerial parts of Senecio giganteus Desf. (Asteraceae), obtained by hydrodistillation in a Clevenger-type apparatus, is analyzed by GC-MS. Eighteen compounds are characterized representing 82.8% of the essential oil with α-pinene (19.4%), 6,10,14-trimethyl-2-pentadecanone (19.1%), pentacosane (16.9%), and tricosane (11.9%) as the main components. [ABSTRACT FROM AUTHOR]

The essential oils of bracts and inflorescences of cultivated Tilia tomentosa and T. cordata from Greece and Romania, respectively, were investigated. Essential oils were obtained by hydrodistilation and analyzed using GC and GC/MS. The oils of from the inflorescences of T. tomentosa and T. cordata were characterized by a high percentage of hydrocarbons (32.3% and 60.4%, respectively) with tricosane being the main component (21.5% and 31.3%). Isocyclocitral (15.3%) and hotrienol (11.5%) were characterized as the main oxygenated monoterpenes of T. tomentosa and T. cordata inflorescences oils, respectively. Linalool (13.1%) and hexahydrofarnesyl acetone (17.7%) were the major constituents in bract oil of T. tomentosa, whereas the bract oil of T. cordata was characterized by the predominance of hydrocarbons (87.4%) with tricosane (32.2%) being the main constituent. [ABSTRACT FROM AUTHOR]

The essential oil, isolated by hydrodistillation from fresh flowers of Spartium junceum L., was investigated by GC and GC/MS. The 24 main constituents of the samples were identified; the main components of the oil were kairomonal compounds, tricosane (22.9%), tetracosane (8.9%) and pentacosane (16.1%), constituting altogether almost 48% of total composition. These hydrocarbons constitute an important aspect governing the sensitivity of the insects in plant host selection. [ABSTRACT FROM AUTHOR]

The essential oils of the inflorescences of Orchis italica and Orchis quadripunctata were analyzed by GC and GC/MS. Thirty-two compounds were identified and the major components were linear hydrocarbons (mainly tricosane and pentacosane) and linear aldehydes (mainly nonanal). [ABSTRACT FROM AUTHOR]