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Magmatic volatile release was crucial for the build‐up and composition of the early atmosphere and thus for the origin and evolution of life. Even though the rate of intrusive to extrusive magma production on Earth is high, intrusive volatile release is commonly neglected in studies modeling the composition of the early atmosphere. This can mainly be attributed to the solubility of volatiles like H2O and CO2. The solubility is increasing with depth and thus is thought to prevent the release of these volatiles. However, due to the accumulation of H2O and CO2 within the melt during fractional crystallization, the solubility can be exceeded even at greater depths. In our study, we developed a novel numeric model to quantify the amount of H2O and CO2 that can be released from an intrusive system if we consider the process of fractional crystallization. Additionally, we take the possibility of melt ascent and the formation of hydrous minerals into account. According to our simulations, the release of H2O and CO2 from an intrusive magma body is possible within the whole lithosphere. However, the release strongly depends on the initial volatile budget, the formation of hydrous phases, the depth of the intrusion and the buoyancy of the melt. Considering all these factors, our study suggests that about 0%–85% H2O and 100% CO2 can be released from mafic intrusions. This renders the incorporation of the intrusive volatile release mandatory in order to determine the volatile fluxes and the composition of early Earth's atmosphere. Key Points: In our model, we quantify the release of H2O and CO2 from a magma body and its significance for early EarthWe examine the effect of fractional crystallization on the solubility and release of volatilesWe consider the buoyancy of the melt and the formation of hydrous minerals [ABSTRACT FROM AUTHOR]

Calcite and aragonite seas are commonly distinguished based on the prevailing primary mineralogy of ooids and carbonate cements over time. Secular oscillations of these seas are usually attributed to changes in ocean chemistry and paleoclimate. While the veracity of such oscillations has been verified by independent data and modeling approaches, the timing of the transition from one ocean state to the other remains poorly resolved. Here, the timing of the last aragonite-calcite sea transition is estimated by assessing the preservation of Early Jurassic ooids from the Trento Platform in northern Italy. Point counting of ooid-bearing limestones from four distinct stratigraphic levels provides a contrasting pattern: Hettangian and Sinemurian ooids are all poorly preserved and were probably predominantly originally aragonitic, whereas Pliensbachian and Toarcian ooids are excellently preserved, suggesting a primary calcitic mineralogy. Although calcitic ooids may have already been common in the Late Triassic, it is proposed that the last aragonite-calcite sea transition occurred in the Early Jurassic between the Sinemurian and Pliensbachian, at least in this subtropical region. Therefore, the selective extinction of aragonite-secreting organisms at the end-Triassic mass extinction cannot be attributed to secular changes in ocean chemistry. [ABSTRACT FROM AUTHOR]