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The capabilities of radar altimetry to measure inland water bodies are well established, and several river altimetry datasets are available. Here we produced a globally distributed dataset, the Global River Radar Altimeter Time Series (GRRATS), using Envisat and Ocean Surface Topography Mission (OSTM)/Jason-2 radar altimeter data spanning the time period 2002–2016. We developed a method that runs unsupervised, without requiring parameterization at the measurement location, dubbed virtual station (VS) level, and applied it to all altimeter crossings of ocean-draining rivers with widths >900 m (>34 % of the global drainage area). We evaluated every VS, either quantitatively for VS locations where in situ gages are available or qualitatively using a grade system. We processed nearly 1.5 million altimeter measurements from 1478 VSs. After quality control, the final product contained 810 403 measurements distributed over 932 VSs located on 39 rivers. Available in situ data allowed quantitative evaluation of 389 VSs on 12 rivers. The median standard deviation of river elevation error is 0.93 m, Nash–Sutcliffe efficiency is 0.75, and correlation coefficient is 0.9. GRRATS is a consistent, well-documented dataset with a user-friendly data visualization portal, freely available for use by the global scientific community. Data are available at https://doi.org/10.5067/PSGRA-SA2V1 (Coss et al., 2016).

Transient absorption spectroscopy, cyclic voltammetry, and DFT calculations were used to describe charge transfer processes in a series of 5,10,15,20-tetrakis(N-methylpyridinium-n-yl) porphyrins (TMPyPn, n= 4,3,2) and TMPyPn/p-sulfonatocalix[m]arene (clxm, m= 4,6,8) complexes. Excitation of TMPyPnis accompanied by an increasing electron density at the methylpyridinium substituents in the order TMPyP2 < TMPyP3 < TMPyP4. The quenching of the excited singlet states of the complexes increases with the number of ionized phenolic groups of clxmand can be correlated with the partial transfer of the electron density from O−to the peripheral methylpyridinium substituents rather than to the porphyrin ring. [ABSTRACT FROM AUTHOR]

NASA and the French space agency, CNES, with contributions from the Canadian Space Agency (CSA) and United Kingdom Space Agency (UKSA) are developing new wide swath altimetry technology that will cover most of the world’s ocean and surface freshwater bodies. The proposed Surface Water and Ocean Topography (SWOT) mission will have the capability to make observations of surface water (lakes, rivers, wetland) heights and measurements of ocean surface topography with unprecedented spatial coverage, temporal sampling, and spatial resolution compared to existing technologies. These data will be useful for monitoring the hydrologic cycle, flooding, and characterizing human impacts on a changing environment. The applied science community is a key element in the success of the SWOT mission, demonstrating the high value of the science and data products in addressing societal issues and needs. The SWOT applications framework includes a working group made up of applications specialists, SWOT science team members, academics and SWOT Project members to promote applications research and engage a broad community of potential SWOT data users. A defined plan and a guide describing a program to engage early adopters in using proxies for SWOT data, including sophisticated ocean and hydrology simulators, an airborne analogue for SWOT (AirSWOT), and existing satellite datasets, are cornerstones for the program. A user survey is in development and the first user workshop was held in 2015, with annual workshops planned. The anticipated science and engineering advances that SWOT will provide can be transformed into valuable services to decision makers and civic organizations focused on addressing global disaster risk reduction initiatives and potential science-based mitigation activities for water resources challenges of the future. With the surface water measurements anticipated from SWOT, a broad range of applications can inform inland and coastal managers and marine operators of terrestrial and oceanic phenomena relevant to their work.