Search

Your search keyword '"Stronach, Michael W."' showing total 3 results
Start Over Author "Stronach, Michael W." Search Limiters Peer Reviewed
3 results on '"Stronach, Michael W."'

1. Physical organic chemistry of transition metal carbene complexes. 2.1 Kinetics and mechanism of...

Author

Bernasconi, Claude F. and Stronach, Michael W.

Subjects
*CARBENES, *AMINES
Abstract

Reports on a kinetic study of the aminolysis of [methoxy(phenyl)carbene]pentacarbonylchromium(0) with five primary aliphatic amines. Indication of general base catalysis; Change in rate-limiting step; Mechanism similar to ester aminolysis; Responsibility for general base catalysis with carbene complex.

Published
1993
Full Text
View/download PDF

2. Large steric effect in the substitution reaction of amines with phosphoimidazolide-activated...

Author

Kanavarioti, Anastassia and Stronach, Michael W.

Subjects
*ALIPHATIC compounds, *AMINES, *STRUCTURE-activity relationships
Abstract

Presents a study of the kinetics of reaction of a series of primary and secondary aliphatic amines. Survival of materials in a prebiotic medium; Reactivity difference as explaining non-detection of substitution products of secondary amino groups of polyamines.

Published
1995
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results