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1. Direct Allylation of Active Methylene Compounds with Allylic Alcohols by Use of Palladium/Phosphine‐Borane Catalyst System.

Author

Shimizu, Aika, Hirata, Goki, Onodera, Gen, and Kimura, Masanari

Subjects
*ALLYLATION, *ALLYL alcohols, *PALLADIUM phosphines, *BORANES, *METHYLENE compounds
Abstract

Abstract: The C−C bond formation between active methylene compounds and allylic alcohols has been newly developed by using a palladium complex as a catalyst together with a phosphine‐borane ligand. The best phosphine‐borane ligand for this direct allylation has been revealed to be Ph2P(CH2)4(9‐BBN) to produce a variety of desirable allylated products in high yields. [ABSTRACT FROM AUTHOR]

Published
2018
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