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The RADIX (Rapid Access Drilling and Ice eXtraction) optical dust logger is part of the exploratory drilling system developed at the University of Bern. It was previously untested because no RADIX borehole reached to the depth of the required bubble-free ice. In June 2023, we tested the logger with an adapter for the large EastGRIP (East Greenland Ice-core Project) deep borehole. An excellent dust record was obtained for the Bølling-Allerød-Younger Dryas-Early Holocene period. The light scattered by the dust in the ice around the borehole was slightly higher than the detection range of the logger, requiring a reduction in the sensitivity for future deployments. [ABSTRACT FROM AUTHOR]

We here describe, document, and make available a wide range of data sets used for annual-layer identification in ice cores from DYE-3, GRIP, NGRIP, NEEM, and EGRIP. The data stem from detailed measurements performed both on the main deep cores and shallow cores over more than 40 years using many different setups developed by research groups in several countries and comprise both discrete measurements from cut ice samples and continuous-flow analysis data. The data series were used for counting annual layers 60 000 years back in time during the construction of the Greenland Ice-Core Chronology 2005 (GICC05) and/or the revised GICC21, which currently only reaches 3800 years back. Now that the underlying data are made available (listed in Table 1) we also release the individual annual-layer positions of the GICC05 timescale which are based on these data sets. We hope that the release of the data sets will stimulate further studies of the past climate taking advantage of these highly resolved data series covering a large part of the interior of the Greenland ice sheet. [ABSTRACT FROM AUTHOR]

RADIX (Rapid Access Drilling and Ice eXtraction) is a prospecting drilling system that has been designed, realized and tested on polar ice sheets. The goal of RADIX is to provide rapid, deep access for sampling of ice and downhole physical measurements that inform about ice sheet age and history and the integrity of layering. A 20 mm access hole is drilled with a hydraulic coiled tubing system where the tube consists of a plastic hose. The ice cuttings are flushed to the surface in normal circulation, i.e., between the hose and borehole wall, and can be sampled for analysis. After drilling, a dedicated logger with a 15 mm diameter is deployed into the hole for measuring the geometric orientation of the hole, the temperature profile and the dust content in the surrounding ice (optical dust logger). The equipment has been tested and improved during six field projects in Greenland and Antarctica. It is designed to ultimately drill through a 3000 m ice sheet within roughly 1 week. The greatest depth reached so far was 324 m during the last field project at Little Dome C. [ABSTRACT FROM AUTHOR]

A rapid access drilling system has been designed, realized and tested on polar ice sheets. A 20-mm access hole is drilled with a hydraulic coiled tubing system where the tube consists of a plastic hose. The ice cuttings are flushed to the surface in forward circulation, i.e. between hose and borehole wall, and can be sampled for analysis. A dedicated logger with 15 mm diameter is deployed into the hole for measuring the geometric orientation of the hole, the temperature profile and the dust content in the surrounding ice (optical dust logger). The equipment has been tested and improved during 6 field projects in Greenland and Antarctica. It is designed to ultimately drill quickly through a 3000 m ice sheet. Routine performance has been established to a depth of 300 m. [ABSTRACT FROM AUTHOR]

Chlorofluorocarbons (CFCs) are ozone-depleting substances as well as strong greenhouse gases, and the control of their production and use under the Montreal Protocol has had demonstrable benefits to both mitigation of increasing surface UV radiation and climate forcing. A global ban on consumption came into force in 2010, but there is evidence of continuing emissions of certain CFCs from a range of sources. One compound has received little attention in the literature, namely CFC-114 (C2Cl2F4). Of particular interest here is the differentiation between CFC-114 (CClF2CClF2) and its asymmetric isomeric form CFC-114a (CF3CCl2F) as atmospheric long-term measurements in the peer-reviewed literature to date have been assumed to represent the sum of both isomers with a time-invariant isomeric speciation. Here we report the first long-term measurements of the two isomeric forms separately, and find that they have different origins and trends in the atmosphere. Air samples collected at Cape Grim (41°S), Australia, during atmospheric background conditions since 1978, combined with samples collected from deep polar snow (firn) enable us to obtain a near-complete record of both gases since their initial production and release in the 1940s. Both isomers were present in the unpolluted atmosphere in comparably small amounts before 1960. The mixing ratio of CFC-114 doubled from 7.9 to 14.8 parts per trillion (ppt) between the start of the Cape Grim record in 1978 and the end of our record in 2014, while over the same time CFC-114a trebled from 0.35 to 1.03ppt. Mixing ratios of both isomers are slowly decreasing by the end of this period. This is consistent with measurements of recent aircraft-based samples showing no significant interhemispheric mixing ratio gradient. We also find that the fraction of CFC-114a mixing ratio relative to that of CFC-114 increased from 4.2 to 6.9% over the 37-year period. This contradicts the current tacit assumption used in international climate change and ozone depletion assessments that both isomers have been largely co-emitted and that their atmospheric concentration ratio has remained approximately constant in time. Complementary observations of air collected in Taiwan indicate a persisting source of CFC-114a in South East Asia which may have been contributing to the changing balance between the two isomers. [ABSTRACT FROM AUTHOR]

Because the total air content (TAC) of polar ice is directly affected by the atmospheric pressure and temperature, its record in polar ice cores was initially considered as a proxy for past ice sheet elevation changes. However, the Antarctic ice core TAC record is known to also contain an insolation signature, although the underlying physical mechanisms are still a matter of debate. Here we present a high-resolution TAC record over the whole North Greenland Ice Core Project ice core, covering the last 120 000 years, which independently supports an insolation signature in Greenland. Wavelet analysis reveals a clear precession and obliquity signal similar to previous findings on Antarctic TAC, with a different insolation history. In our high-resolution record we also find a decrease of 4-6% (4-5mL kg-1) in TAC as a response to Dansgaard-Oeschger events (DO events). TAC starts to decrease in parallel to increasing Greenland surface temperature and slightly before CH4 reacts to the warming but also shows a two-step decline that lasts for several centuries into the warm interstadial. The TAC response is larger than expected considering only changes in air density by local temperature and atmospheric pressure as a driver, pointing to a transient firnification response caused by the accumulation-induced increase in the load on the firn at bubble close-off, while temperature changes deeper in the firn are still small. [ABSTRACT FROM AUTHOR]

Perfluorocarbons (PFCs) are very potent and longlived greenhouse gases in the atmosphere, released predominantly during aluminium production and semiconductor manufacture. They have been targeted for emission controls under the United Nations Framework Convention on Climate Change. Here we present the first continuous records of the atmospheric abundance of CF4 (PFC-14), C2F6 (PFC-116) and C3F8 (PFC-218) from 1800 to 2014. The records are derived from high-precision measurements of PFCs in air extracted from polar firn or ice at six sites (DE08, DE08-2, DSSW20K, EDML, NEEM and South Pole) and air archive tanks and atmospheric air sampled from both hemispheres. We take account of the age characteristics of the firn and ice core air samples and demonstrate excellent consistency between the ice core, firn and atmospheric measurements. We present an inversion for global emissions from 1900 to 2014. We also formulate the inversion to directly infer emission factors for PFC emissions due to aluminium production prior to the 1980s. We show that 19th century atmospheric levels, before significant anthropogenic influence, were stable at 34:1±0:3 ppt for CF4 and below detection limits of 0.002 and 0.01 ppt for C2F6 and C3F8, respectively. We find a significant peak in CF4 and C2F6 emissions around 1940, most likely due to the high demand for aluminium during World War II, for example for construction of aircraft, but these emissions were nevertheless much lower than in recent years. The PFC emission factors for aluminium production in the early 20th century were significantly higher than today but have decreased since then due to improvements and better control of the smelting process. Mitigation efforts have led to decreases in emissions from peaks in 1980 (CF4) or early-to-mid-2000s (C2F6 and C3F8) despite the continued increase in global aluminium production; however, these decreases in emissions appear to have recently halted. We see a temporary reduction of around 15% in CF4 emissions in 2009, presumably associated with the impact of the global financial crisis on aluminium and semiconductor production. [ABSTRACT FROM AUTHOR]

After the NEEM (Greenland) deep ice-core drilling was declared terminated with respect to developing stratigraphic climate reconstructions, efforts were turned toward collecting basal icesheet debris and, if possible, drilling into the bedrock itself. In 2010, several meters of banded debrisrich ice were obtained under normal ice-drilling operations with the NEEM version of the Hans Tausen (HT) drill, but further penetration was obstructed by a rock in the path of the drill head at 2537.36 m. During short campaigns in 2011 and 2012, attempts were made to penetrate further using various reinforced ice cutters mounted on the HT drill head, tailored to cut through rock. These had some success in penetrating coarse material, but produced severely damaged cutters. Additionally a 51 mm diameter diamond cutting tipped rock drill was adapted to fit the NEEM drill. With this device, several additional meters of core containing subglacial sediments, rocks and rock fragments were collected. With these tools 1.39 m of additional material were obtained during the 2011 field season, and 7.1 m during 2012. Subglacial water refreezing into the newly formed borehole hindered further penetration, and the bedrock interface was not reached before final closure of the NEEM Camp. [ABSTRACT FROM AUTHOR]

Ozone-depleting substances emitted through human activities cause large-scale damage to the stratospheric ozone layer, and influence global climate. Consequently, the production of many of these substances has been phased out; prominent examples are the chlorofluorocarbons (CFCs), and their intermediate replacements, the hydrochlorofluorocarbons (HCFCs). So far, seven types of CFC and six types of HCFC have been shown to contribute to stratospheric ozone destruction. Here, we report the detection and quantification of a further three CFCs and one HCFC. We analysed the composition of unpolluted air samples collected in Tasmania between 1978 and 2012, and extracted from deep firn snow in Greenland in 2008, using gas chromatography with mass spectrometric detection. Using the firn data, we show that all four compounds started to emerge in the atmosphere in the 1960s. Two of the compounds continue to accumulate in the atmosphere. We estimate that, before 2012, emissions of all four compounds combined amounted to more than 74,000 tonnes. This is small compared with peak emissions of other CFCs in the 1980s of more than one million tonnes each year. However, the reported emissions are clearly contrary to the intentions behind the Montreal Protocol, and raise questions about the sources of these gases. [ABSTRACT FROM AUTHOR]

The article presents a study on an accurate method to determine the depth of radio-echo sounding (RES) reflections. The researchers simultaneously measured density and dielectric properties along the European Project for Ice Coring in Antarctica (EPICA) in Dronning Maud Land (EDML) ice core using in the field gamma-attenuation profiling (GAP) and dielectric profiling (DEP). They also discussed the dependence of the calculation of the synthetic radargrams on the ice-core properties. They found that single conductivity peaks are responsible for most of the individual reflections in the deeper and intermediate parts of the ice sheet.

The article presents a study which investigated the temporal and spatial variation of stable-isotope ratios and accumulation rates in the hinterland of Neumayer station in East Antarctica. Different basic parameters were calculated from stable-isotope measurements and characterized using a global meteoric waterline (GMWL). Results showed that the air-sea interaction could influence the dieletrical profiles of the hinterland cores. It concluded that the accumulation rate at the summit of Halvfarryggen acts as a natural barrier for moisture-carrying air masses circulating in the region from east to west.

The most direct method of investigating past variations of the atmospheric CO2 concentration before 1958, when continuous direct atmospheric CO2 measurements started, is the analysis of air extracted from suitable ice cores. Here we present a new detailed CO2 record from the Dronning Maud Land (DML) ice core, drilled in the framework of the European Project for Ice Coring in Antarctica (EPICA) and some new measurements on a previously drilled ice core from the South Pole. The DML CO2 record shows an increase from about 278 to 282 parts per million by volume (ppmv) betweenad1000 andad1200 and a fairly continuous decrease to a mean value of about 277 ppmv aroundad1700. While the new South Pole measurements agree well with DML at the minimum atad1700 they are on average about 2 ppmv lower during the periodad1000–1500. Published measurements from the coastal high-accumulation site Law Dome are considered as very reliable because of the reproducibility of the measurements, high temporal resolution and an accurate time scale. Other Antarctic ice cores could not, or only partly, reproduce the pre-industrial measurements from Law Dome. A comparison of the trends of DML and Law Dome shows a general agreement. However we should be able to rule out co-variations caused by the same artefact. Two possible effects are discussed, first production of CO2 by chemical reactions and second diffusion of dissolved air through the ice matrix into the bubbles. While the first effect cannot be totally excluded, comparison of the Law Dome and DML record shows that dissolved air diffusing to bubbles cannot be responsible for the pre-industrial variation. Therefore, the new record is not a proof of the Law Dome results but the first very strong support from an ice core of the Antarctic plateau. [ABSTRACT FROM AUTHOR]

Abstract: Reconstructions of past atmospheric concentrations of greenhouse gases provide unique insight into the biogeochemical cycles and the past radiative forcing in the Earth''s climate system. We present new measurements of atmospheric nitrous oxide along the ice cores of the North Greenland Ice Core Project and Talos Dome sites. Using records of several other ice cores, we are now able to establish the first complete composite nitrous oxide record reaching back to the beginning of the previous interglacial about 140,000yr ago. On the basis of such composite ice core records, we further calculate the radiative forcing of the three most important greenhouse gases carbon dioxide, methane and nitrous oxide during more than a full glacial–interglacial cycle. Nitrous oxide varies in line with climate, reaching very low concentrations of about 200 parts per billion by volume during Marine Isotope Stages 4 and 2, and showing substantial responses to millennial time scale climate variations during the last glacial. A large part of these millennial time scale variations can be explained by parallel changes in the sources of methane and nitrous oxide. However, as revealed by high-resolution measurements covering the Dansgaard/Oeschger events 17 to 15, the evolution of these two greenhouse gases may be decoupled on the centennial time scale. Carbon dioxide and methane concentrations do not reach interglacial levels in the course of millennial time scale climate variations during the last glacial. In contrast, nitrous oxide often reaches interglacial concentrations in response to both, glacial terminations and Dansgaard/Oeschger events. This indicates, from a biogeochemical point of view, similar drivers in both temporal cases. While carbon dioxide and methane concentrations are more strongly controlled by climate changes in high latitudes, nitrous oxide emissions changes may mainly stem from the ocean and/or from soils located at low latitudes. Accordingly, we speculate that high latitudes could play the leading role to trigger glacial terminations. [Copyright &y& Elsevier]

Abstract: The atmospheric evolution of eight non-methane hydrocarbons (ethane, acetylene, propane, n-butane, isobutane, n-pentane, isopentane and benzene) and five alkyl nitrates (2-propyl, 2-butyl, 3-methyl-2-butyl and the sum of 2+3-pentyl nitrates) are reconstructed for the latter half of the 20th century based on Arctic firn air measurements. The reconstructed trends of the non-methane hydrocarbons (NMHCs) show increasing concentrations from 1950 to a maximum in 1980 before declining towards the end of last century. These observations provide direct evidence that NMHCs in the northern hemisphere have declined substantially during the period 1980–2001. Benzene concentrations show a smaller increase between 1950 and 1980 than the other NMHCs indicating that additional sources of benzene, other than fossil fuel combustion, were likely important contributors to the benzene budget prior to and during this period. The declining benzene concentrations from 1980 to 2001 would suggest that biomass burning is unlikely to be important in the benzene budget as biomass burning emissions were reportedly increasing over the same period. Methyl and ethyl nitrate show growth patterns in the firn that suggested perturbation by in-situ production from an unidentified mechanism. However, the higher alkyl nitrates show evidence for increasing concentrations from 1950 to maxima in the mid 1990s before decreasing slightly toward the end of the last century. The differing atmospheric evolution of the alkyl nitrates relative to their parent hydrocarbons indicate an increase in their production efficiency per hydrocarbon molecule. Using a steady state analysis of hydrocarbon oxidation and alkyl nitrate production and loss we show that reactive nitrogen oxide (NOx) concentrations in the northern hemisphere have likely increased considerably between 1950 and 2001. [Copyright &y& Elsevier]

Abstract: CO2 measurements on the EPICA (European Project for Ice Coring in Antarctica) DML ice core in depth levels just below the bubble ice–clathrate ice transformation zone (1230–2240m depth) were performed. In the youngest part (1230–1600m), they reveal variations of up to 25ppmv around the mean atmospheric concentration within centimetres, corresponding to a snow deposition interval of a few years. Similar results are found at corresponding depth regions of the Dome C and the Talos Dome ice cores. Since we can exclude all hitherto known processes altering the concentration of CO2 in ice cores, we present a hypothesis about spatial fractionation of air components related to episodically increasing clathrate formation followed by diffusion processes from bubbles to clathrates. This hypothesis is supported by optical line-scan observations and by O2/N2 measurements at the same depth where strong CO2 variations are detected. Below the clathrate formation zone, this small-scale fractionation process is slowly smoothed out, most likely by diffusion, regaining the initial mean atmospheric concentration. Although this process compromises the representativeness of a single CO2 measurement on small ice samples in the clathrate formation zone of an ice core, it does not affect the mean atmospheric CO2 concentration if CO2 values are averaged over a sufficiently long depth scale (>10cm in case of the EPICA DML ice core). [ABSTRACT FROM AUTHOR]

Abstract: Large temperature variations on millennial time scales in Greenland characterised the last ice age. Abrupt warmings, known as Dansgaard–Oeschger (DO) events, can be traced in the δ 18Oice record of Greenland ice cores. However, it has been shown that δ 18Oice is not a direct temperature proxy. Measurements of the isotopic composition of gases trapped in the ice can be used to calibrate the paleothermometer. Here we present a continuous temperature record based on high resolution δ 15N measurements and firn model studies. It covers a sequence of 9 DO events (9–17) during the time period from 38 to 64 kyr BP for which temperature changes of 8 to 15 °C were estimated. The difference between the modern and the glacial δ 18Oice–T relationship can be explained by a combination of source temperature changes and changes in the annual distribution of precipitation. A detailed comparison of the temperature evolution with reconstructions of the atmospheric methane (CH4) concentration shows that CH4 rises lag temperature increases at the onset of DO events by 25 to 70 yr within data resolution. The strong correlation between Greenland temperature and CH4 on millennial and submillennial time scales suggests that variations on these time scales were probably of hemispheric extent. [Copyright &y& Elsevier]

High resolution records of atmospheric CO2 concentration during the Holocene are obtained from the Dome Concordia and Dronning Maud Land (Antarctica) ice cores. These records confirm that the CO2 concentration varied between 260 and 280 ppmv in the Holocene as measured in the Taylor Dome ice core. However, there are differences in the CO2 records most likely caused by mismatches in timescales. Matching the Taylor Dome timescale to the Dome C timescale by synchronization of CO2 indicates that the accumulation rate at Taylor Dome increased through the Holocene by a factor two and bears little resemblance to the stable isotope record used as a proxy for temperature. This result shows that different locations experienced substantially different accumulation changes, and casts doubt on the often-used assumption that accumulation rate scales with the saturation vapor pressure as a function of temperature, at least for coastal locations. [Copyright &y& Elsevier]