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Synroc minerals have been studied since decades for immobilization of high-level radioactive wastes released from nuclear weapons and nuclear reactors. Among them, the zirconolite, due to its high radiation and aqueous resistance and high waste loading, is considered as a potential candidate for containment purposes. Though irradiation damage effects of swift heavy ions in the material remain a major concern of study, a single phase Nd-doped zirconolite samples prepared through conventional solid-state reaction were irradiated with 120 MeV Au+ ions to study radiation damage effects. Irradiation-induced effects were investigated using ex-situ XRD and micro-Raman spectroscopic techniques. Zirconolite has been observed to undergo amorphization which is confirmed through disappearance of characteristic x-ray diffraction peaks and appearance of broad diffuse scattering bands. Amorphization trend with fluence appeared linear at lower fluences followed by saturation at higher fluences inferring therewith the formation of ion tracks. The ion fluence dependent Raman examination was also found to be in line with the XRD observations. However, the presence of Raman modes, characteristic of zirconolite in the 100–1000 cm−1 region, showed intact behavior of the local structure. To sum up, the 120 MeV heavy Au+ ions developed columnar defects, vacancies and induced micro-strains that lead to the bonds distortion and eventually amorphization of the zirconolite though retaining local ordering.

Zirconolite, a potential matrix for the immobilization has been studied to investigate the doping behaviour of Ce in its structure to design a nuclear waste form that can accommodate both trivalent and tetravalent nuclear wastes. So, samples have been prepared as per the composition Ca0.8Ce0.2ZrTi1.8Al0.2O7 using solid-state method and analysed for their structural, micro-structural and chemical properties. A dense-packed structure was found in SEM with the phase of zirconolite-2M as confirmed by XRD and Raman techniques. Quantitative analysis of XPS inferred that the percentage of Ce(III) in the sample was about ~ 75% indicating the reduction of Ce at higher temperatures.

Effects of titanium substitution on electrical and magnetic properties of ceramics of barium ferrites having general formula BaTixFe12-xO19, with values of x as 0.00, 0.005, 0.01, 0.02 and 0.03 have been investigated. The compounds are synthesised using two step sintering solid-state rout and characterized by employing SEM and x-ray diffraction. All the titanium substituted compounds show hexagonal single phase symmetry. Gradual loss of saturation magnetization, significant increase in total polarization, rise in value of dielectric constant and upward trend in resistivity are the main parameters observed with titanium substitution on Fe ions. The Curie temperature shows declining trend with dopant concentration. The material is found to exhibit electrical behaviour at expense of its intrinsic magnetic characteristics paving way for Ti ion substitutions for controlled magnetic and electrical properties of barium ferrite.

The immobilization of minor actinides and alkaline-earth metal is a major concern in nuclear industry due to their long-term radioactive contribution to the high level waste (HLW). Materials having zirconolite, pyrochlore, and perovskite structure are promising candidates for immobilization of HLW. The zirconolite which exhibits high radiation stability and corrosion resistance behavior is investigated for its radiation stability against alpha particles in the present study. CaZrTi 2 O 7 pellets prepared using solid state reaction techniques, were irradiated with 30 keV He + ions for the ion fluence varying from 1 × 10 17 to 1 × 10 21 ions/m 2 . Scanning electron microscopy (SEM) images of the un-irradiated sample exhibited well separated grains with average size of about 6.8 μm. On the ion irradiation, value of the average grains size was about 7.1 μm, and change in the microstructure was insignificant. The X-ray photoelectron spectroscopy (XPS) studies showed a shift in the core level peak position (of Ca 2p, Ti 2p and Zr 3d) towards lower binding energy with respect to pristine sample as well as loss of oxygen was also observed for sample irradiated with the ion fluence of 1 × 10 20 ions/m 2 . These indicate a decrease in co-ordination number and the ionic character of M O bond. Moreover, core level XPS signal was not detected for sample irradiated with ion fluence of 1 × 10 21 ions/m 2 , suggesting surface damage of the sample at this ion fluence. However, X-ray diffraction (XRD) studies showed that zirconolite was not amorphized even on irradiation up to a fluence order of 1 × 10 21 ion/m 2 . But, significant decrease in peak intensity due to creation of defects and a marginal positive peak shift due to tensile strain induced by irradiation, were observed. Thus, XRD along with XPS investigation suggests that reduction, decrease in co-ordination number, and increase in covalency are responsible for the radiation damage in zirconolite.