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Abstract Titanium dioxide (TiO2) nanoparticles were prepared through Rosmarinus-officinalis leaf extracts at 90 and 200°C. In this research, the degradations of methylene blues by using TiO2 nanoparticles Sun light radiations were studied. The synthesized materials were characterized using XRDs, UV-Vis, PL, SEM, TEM, EDS and XPS. The results displayed that bio-synthesis temperatures intrude the shapes and sizes of TiO2 nanoparticles. For TiO2-90, micrographs show separable crystalline with irregular morphologies and agglomerate cubic particles. For the other TiO2-200 sample, SEM and TEM micro-imaging shows crumbly agglomerated cubic structures. The XRD shows that the intense peaks observed at angles of 25.37°, 37.19°, 47.81° and 53.89° confirming a highly crystalline oriented as (004), (200), and (105) planes respectively. The optical properties of TiO2 nanoparticles synthesized were conveyed by PL and UV-Vis. The energy band gap calculated was 3.0 eV for both samples; that indicates heating temperature didn’t influence the band gap of the samples. The elemental composition Ti and O2 is shown by EDS and XPS. Photo-catalytic experiments discovered that TiO2-90 nanoparticles were well-organized in photo-degradations of MB, likened to TiO2-200. The great activities of TiO2-90 were because of better physicochemical characteristics associated with TiO2-200 effectively degrading MB under photo-light. Photo-degradations of dye under sunlight as plentifully obtainable energy sources by TiO2, synthesized by simpler techniques, can be hopeful to grow an eco-friendly and economical process.

Abstract This research works discuss about the effective utilization of waste Ramie Root, that has been in reinforced polyester composites, powdered fillers that have not been treated are used. Four different composites plate were formed with compression moulding technique process consisting of 20, 30 and 40% of Powdered Ramie Root with 80, 70 and 60% unsaturated polyester resin, respectively. The maximum mechanical properties were observed for the composite with 30:70 weight volume percentages of milled ramie root synthetic reinforced polyester. The findings show that the glass transition temperature, storage modulus, and loss factors all rise when the composition of composites changes. Additionally, the powder cohesion force (bonding strength) has a greater impact on dynamic mechanical properties. Thermo-gravimetric the inclusion of Ramie Root powder caused the thermal deterioration peak of the composite to move from 370 °C to 418 °C, according to analysis (TGA) conducted under flowing oxygen. According to the measurement of water absorption, the ideal weight ratio of Fiber: Unsaturated Polyester Resin is 30:70, which modifies the fibres’ surfaces and ensures optimal adhesion between the fibre and matrix in composite materials. Scanning electron microscopic investigation is done to ascertain the fracture behaviour of the composite. As a result of their stability, high tensile strength, and bending stiffness, the produced composites can be used in light-load applications by material technologists.

Abstract Titanium dioxide nanoparticles (TiO2 NPs) were prepared by Caricaceae (Papaya) Shell extracts. The Nanoparticles were analyzed by UV–Vis spectrums, X-ray diffractions, and energy-dispersive X-rays spectroscopy analyses with a scanning electron microscope. An antifungal study was carried out for TiO2 NP in contradiction of S. sclerotiorums, R. necatrixs and Fusarium classes that verified a sophisticated inhibitions ratio for S. sclerotiorums (60.5%). Germs of pea were individually preserved with numerous concentrations of TiO2 NPs. An experience of TiO2 NPs (20%, 40%, 80% and 100%), as well as mechanisms that instigated momentous alterations in seed germinations, roots interval, shoot lengths, and antioxidant enzymes, were investigated. Associated with controls, the supreme seeds germinations, roots and plant growth were perceived with the treatments of TiO2 NPs. Super-oxide dis-mutase and catalase activities increased because of TiO2 NPs treatments. This advocates that TiO2 Nanoparticles may considerably change antioxidant metabolisms in seed germinations.

Abstract The current study assesses the prospect of using R. Communis seed oil as a substitute fuel for diesel engines. Biodiesel is prepared from the R. Communis plant seed oil by a single-step base catalytic transesterification procedure. The investigation deals with the Physico-chemical characteristics of R. Communis biodiesel and has been associated with the base diesel. It has been perceived that the characteristics of biodiesel are well-matched with the base diesel under the ASTM D6751 limits correspondingly. R. Communis biodiesel is blended in different proportions with base diesel such as D10, D20, D30, D40, D50 and D100 and is tested in a Kirloskar TV1 single-cylinder, 4 blows DI engine under altered loading conditions. Outcomes demonstrate that BTE and BSFC for D10 as well as D20 are similar to base diesel. BSFC indicates that the precise BSFC of base diesel, D10, D20, D30, D40 and D50 was 0.87, 1.70, 2.60, 3.0, 3.4, and 3.5 kg/kW-hr, respectively. The extreme BTE at full load condition for base diesel, D10, D20, D30, D40, D50 and D100 are 28.2%, 28.1%, 27.9%, 25.5%, 24.1%, and 23.6% , respectively. In the case of engine emissions, R. Communis biodiesel blends provided an average decrease in hydrocarbon (HC), Carbon-monoxide (CO) and carbon dioxide (CO2) associated with base diesel. Nevertheless, R. Communis biodiesel blends discharged high stages of nitrogen oxide (NOx) compares to base diesel. Base diesel, D10, D20, D30, D40, D50, and D100 had UBHC emissions of 45 ppm, 40 ppm, 44 ppm, 46 ppm, 41 ppm, and 43 ppm, respectively. The reduction in CO emissions for D10, D20, D30, D40, D50 and D100 are 0.13%, 0.14%, 0.17%, 0.18% and 0.21% respectively. The dissimilarity in NOx attentiveness within brake powers for D10, D20, D30, D40, and D50 and base diesel are 50-ppm, 100 ppm, 150 ppm, 250 ppm, 350 ppm, and 500 ppm, respectively. The dissimilarity of CO2 emanation with reverence to break powers for the base-diesel, D10, D20, D30, D40, D50, and D100 are 4.8%, 4.9%, 4.8%, 4.56%, 4.9% and 5.1%, respectively. The present research provides a way for renewable petrol blends to substitute diesel for powering diesel engines in that way dropping the reliance on fossil fuels.

The exploration of Coulomb blockade oscillations in plasmonic nanoparticle dimers is the subject of this study. When two metal nanoparticles are brought together at the end of their journey, tunnelling current prevents an infinite connection dipolar plasmon and an infinite amplification in the electric fields throughout the hot spot in between nanoparticles from occurring. One way to think about single-electron tunnelling through some kind of quantum dot is to think about Coulomb blockage oscillations in conductance. The electron transport between the dot and source is considered. The model of study is the linear conductance skilled at describing the basic physics of electronic states in the quantum dot. The linear conductance through the dot is defined as G=lim⟶0I/V in the limit of infinity of small bias voltage. We discuss the classical and quantum metallic Coulomb blockade oscillations. Numerically, the linear conductance was plotted as a function gate voltage. The Coulomb blockade oscillation occurs as gate voltage varies. In the valleys, the conductance falls exponentially as a function gate voltage. As a result of our study, the conductance is constant at high temperature and does not show oscillation in both positive and negative gate voltages. At low temperature, conductance shows oscillation in both positive and negative gate voltages.

The influence of bath temperature on nano-manufactured PbSe (lead selenide) films was successfully generated by utilizing CBD on the acid solution’s metal surface tool. Pb (NO3)2 was employed as a lead ion source as a precursor, while Na2O4Se was used as a selenide ion source. The XRD characterization revealed that the prepared samples are the property of crystalline structure (111), (101), (100), and (110) Miller indices. The scanning electron microscope indicated that the particles have a rock-like shape. There was a decrement of energy bandgap that is from 2.4 eV to 1.2 eV with increasing temperature 20°C–85°C. Thin films prepared at 85°C revealed the best polycrystal structure as well as homogeneously dispersed on the substrate at superior particle scales. The photoluminescence spectrophotometer witnessed that as the temperature of the solution bath increases from 20°C to 85°C, the average strength of PL emission of the film decreases. The maximum photoluminescence strength predominantly exists at high temperatures because of self-trapped exciton recombination, formed from O2 vacancy and particle size what we call defect centres, for the deposited thin films at 45°C and 85°C. Therefore, the finest solution temperature is 85°C.

Chitosan is biopolymer of glucosamine residues, nontoxic, biodegradable and friendly to environment and it also helps to enhance crop production due to their bioactivities. The present experiment was conducted to assess the efficacy of chitosan on the growth and yield related attributes of mulberry, Morus sp. with various concentrations such as 25, 50, 75, 100 and 125 ppm. The chitosan was sprayed thrice on 15, 30 and 45 days after pruning (DAP) on the foliage of three different mulberry varieties namely V1, MR2 and G4. The result revealed that, irrespective of varieties, the foliar application of chitosan at 75 ppm significantly increased the biometric as well as yield related attributes of mulberry over other concentrations. Among the three varieties, V1 showed more response to chitosan application than G4 and MR2. At 75 ppm, chitosan showed marked effect on VI variety of mulberry and significantly increased shoot length (170.67 cm), number of shoots per plant (9.03), number of leaves per shoot (29.48), leaf area (220.26 cm2) and leaf area index (2.72) were observed when compared with control. The application of chitosan at 75 ppm significantly enhanced the yield traits namely weight of 100 leaves (448.10 g), leaf shoot ratio (1.45) and leaf yield (14.01 MT/ha/harvest) in V1.

Taylor’s spatial frame (TSF) and Ilizarov external fixators (IEF) are two circular external fixator commonly used to address complex deformity and fractures. There is currently no data available comparing the biomechanical properties of these two external fixators. This study looks into the mechanical characteristics of each system. TSF rings with 6 oblique struts, 4 tube connectors, 4 threaded rods, and 6 threaded rods were compared to a standard IEF rings with 4 threaded rods. Compression and torsional loading was performed to the frame as well as construct with Polyvinylchloride tubes. TSF rings with 4 tube connectors had the highest stiffness (3288 N/mm) while TSF rings with 6 struts was the least stiff. The situation was reversed for torsion where TSF rings with 6 oblique struts had the highest torsional stiffness (82.01 Nm/Degree) and frame Ilizarov rings with 4 threaded rods the least. Standard TSF construct of two ring with 6 oblique struts have better torsional stiffness and lower axial stiffness compared to the standard IEF.

Zincum metallicum, a holistic homeopathic medicine, has a huge characteristic range of action in the treatment of diseases and the maintenance of health systems. It helps build the immune system. Oxidative stress is a known factor in chronic diseases. Zinc in the form of Zincum metallicum or any other form acts as an antioxidant by reducing oxidative stress and helping to treat many conditions. Some of this Zincum metallicum is potent in treating various diseases caused by oxidative stress or sedentary lifestyle. Zincum metallicum has been shown to treat polycystic ovarian syndrome (PCOS) by regulating insulin resistance and lipid levels in women with PCOS and improving ovarian function. It is also helpful for the reproductive organs as it improves sperm count in men and ovarian function in women. Zincum metallicum not only treats the disease, but also acts on other organs to improve the metabolic activity of the system. Since Zincum metallicum acts on the central nervous system, it helps in the treatment of various diseases related to the nervous system, such as Parkinson's disease. Zincum metallicum helps in the treatment of liver related diseases such as hepatitis, liver cirrhosis. Mild zinc deficiencies are likely to cause chronic metabolic disorders resulting in health complications. Zincum metallicum is great for treating metabolic disorders. [ABSTRACT FROM AUTHOR]

Field experiments were conducted at Thalingipalayam block (Avinashi, block), Tamil Nadu (India) during kharif and rabi seasons of 2011-2012 to study the effect of recycling of seriwaste compost (organic manure) with other organics and inorganics on the productivity of maize crop. The experiments were laid out in randomized block design with three replications. Two source of organic manures, viz. seriwaste compost + animal and poultry wastes were imposed along with Nitrogen (N), Phosphorus (P), Potassium (K) levels (150:75:75 kg/ha), viz. 100% of Recommended Dose of Fertilizer (RDF) (T1), 75% of RDF + 25% organic manure (T2), 50% of RDF + 50% organic manure (T3), 25% of RDF + 75% organic manure (T4), 100% of RDF+75% of organic manure (T5), 100% organic manure alone (T6) and absolute control (T7). Organic manures applied to crop of maize with different levels of NPK to all plots. The results revealed that 100% RDF + 75% organic manure were increased the growth and, yield attributes, yield and nutrients, which was followed by 50% RDF +50% organic manure with enhanced B/C ratio.

Right from the olden days, many products have been made according to foundry practices in order to generate prosperity in the societies in which they operate while reaping these types of benefits through the operation of foundries. It is alarming that the emissions released by foundries affect human health. Therefore, foundries installed Pollution Control devices (PCDs), in accordance with this development; researchers examined the effectiveness of these PCDs in controlling emissions from foundries in different parts of the world. The emission control obtained by installing these PCDs is explained in this article based on the data gathered from the survey. The cartridge filter equipped with an induction furnace reduced the concentration of SPM to less than 20 mg/Nm3. This result of the investigation indicates that the cartridge filter built into the induction furnace achieves the best efficiency in controlling contaminants from iron foundries. Interestingly, the operation of the cartridge filter has yet to be documented. Therefore, the construction operation, the performance of the cartridge filter, and its efficiency in achieving contaminations control in foundries are described. This will provide useful information on the use of cartridge filters in an induction furnace to reduce Iron foundry emissions. [ABSTRACT FROM AUTHOR]

Polycystic ovary syndrome (PCOS) is a multifactorial endocrine disorder which is characterized by chronic anovulation. Irregular periods, hirsutism, weight gain are the other signs of PCOS. The prevalence of PCOS worldwide is between 6% and 26% while in India it was 3.7% to 22.5%. PCOS is the most prevailing female endocrine disorder and the preeminent cause of infertility. Risk factors that contribute to the development of PCOS include genetics, neuroendocrine system, sedentary lifestyle, diet, and obesity. Modern medicine has found many ways to heal. Synthetic drugs such as metformin and oral contraceptive pills were available in the market, but because of their side effects, people depend on traditional and herbal medicines. This review provides a detailed approach to different types of traditional and natural systems for the treatment and management of PCOS. Different approaches to managing PCOS include the traditional system of drugs, herbal remedies, herbs, and Phyto-ingredients that have proven their potential in treating PCOS. Traditional medicine includes Unani, Ayurveda, Siddha, naturopathy, yoga, and homeopathy. In addition to treatment, yoga also has potential in treating PCOS. [ABSTRACT FROM AUTHOR]

Correction for 'The corrosion inhibition of stainless steel by ferrocene–polyoxometalate hybrid molecular materials – experimental and first principles studies' by G. Sruthi et al., Phys. Chem. Chem. Phys., 2020, 22, 3329–3344, DOI: 10.1039/C9CP06284J. [ABSTRACT FROM AUTHOR]

The choice of appropriate discount rate for comparing the long-term health benefits of policies is a complex issue. This study contributes to this sparsely researched issue from the perspective of developing countries by estimating the implicit discount rate that workers reveal through their willingness to incur death risks on-the-job and quantity-adjusted value of life of workers using an original data set from the Indian labor market. The estimated real discount rate ranges from 7.6 to 9.7 per cent, which is closer to the financial market rate for the study period and consistent with earlier studies from developed nations. The estimated value of life ranges are Rs. 24.3–26.5 (US $1.34–1.47) million. The results of the study can aid policy makers, international agencies, and researchers in evaluating health projects in India and other developing nations. [ABSTRACT FROM AUTHOR]