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Cooking conditions affect oil properties and consequently, the quality of the derived biodiesel. Nevertheless, little information regarding the impact of the cooking process on biodiesel properties is currently available, especially for palm biodiesel. Therefore, this study examined the effect of cooking temperature, time of use, and length of reuse, on selected properties of biodiesel produced from palm-based waste cooking oils (WCO). Several WCO collected from restaurants belonging to four categories, namely fried chicken restaurants, fast food restaurants, snack producers, and typical restaurants, were subjected to base-catalyzed transesterification. The biodiesel yield was calculated, and the produced biodiesel was characterized as to its kinematic viscosity, calorific value, and cetane number. As a result, palm-based WCO performed better than other WCO in terms of biodiesel yield regardless of the conditions that they experienced, achieving almost 95% in some cases. The yield decreased as the cooking temperature and length of reuse moved upward, whereas the kinematic viscosity was sensitive only to the length of reuse, rising with increasing reuse. Non-compliance with biodiesel standards and technical requirements was observed in a few cases. The calorific value did not significantly change unless the cooking conditions were severe. The cetane number dropped as use and reuse decreased, remaining better compared to petrodiesel (70.2 ± 3.2 on average). Typical restaurants would generate the most suitable WCO to produce biodiesel, i.e., yield: 93.1 ± 0.2%; kinematic viscosity: 5.0 ± 0.3 mm2/s; calorific value: 39.9 ± 0.1 MJ/kg; density: 919 ± 9 kg/m3; and cetane number: 67.4 on average. This is consistent with the less severe cooking conditions employed at these restaurants.

The panela industry is one of the most important Agro Industries in Colombia, making it the largest per- capita consumer and the second largest producer worldwide. The fuel used in this process is traditionally the sugarcane bagasse (SB) which is a byproduct of milling. However, due to the low efficiency of panela furnaces additional fuel is required such as wood, used rubber tires and coal. The fixed-bed furnaces inefficiency is mainly due to incomplete combustion of SB caused by the influence of process variables. Therefore, the aim of this work was to study the influence of particle size (PS) and moisture content (MC) over the combustion stages of SB in fixed-bed furnaces. A three-level factorial design was proposed for PS and MC of SB where the temperature and gas concentration were considered as response variables to evaluate the furnace performance. The results obtained in this work show that if the MC increases then the SB yield in the combustion is decreased. On the other hand, the increasing PS can counteract the effect of the MC of SB.

La pirólisis de llantas usadas se presenta como una excelente alternativa para el tratamiento de estos residuos, dado su potencial para la producción de compuestos de alto valor agregado. El caucho de llantas usadas fue sometido a pirólisis intermedia en atmósfera inerte a una presión de trabajo de 1 bar relativo, usando un reactor de lecho fijo. El objetivo principal es la maximización del rendimiento de las corrientes de líquido (aceite) y sólido (carbón) durante la pirólisis. Las variables de proceso como tamaño de partícula, tiempo de reacción y temperatura fueron analizadas permitiendo estudiar su impacto en el rendimiento de los productos. Los modelos analizados para los rendimientos de aceite y carbón evidencian que la variable con menor influencia sobre las corrientes es el tamaño de partícula. Con base en los modelos planteados se observa que las mejores condiciones para la maximización de los productos dependen de la adecuada combinación de temperatura y tiempo de reacción.

This work is aimed to study the wax deposition process on the internal surface of oil production pipelines and the influence of parameters such as flow rate and pipe wall temperature on the deposit thickness for a light crude oil with high paraffinic content considering three different temperature boundary conditions on the pipe wall; two of which assumed a profile temperature on the boundary, fact that has not been considered in previous works, and the third a constant value. The analysis was conducted assuming pseudo steady conditions on the fluid phase. The finite differences method was applied to solve the differential equation system and the solution was implemented numerically using the C++ programming language. The model was validated with the experimental results reported by Singh et al. (2000) and subsequently used to simulate the growth of the paraffin deposits as a function of flow rate and pipe temperature. The results showed that increased flow rates reduce the maximum deposit thickness, as it spreads on a longer distance in the pipe when considering a constant wall temperature or the axial thermal gradient with a positive slope, and the opposite effect is observed when considering the axial thermal gradient with a negative slope.

ABSTRACT A simulation of a pilot plant delayed coking reactor was performed using an in-house computational fluid dynamics (CFD) code. The reactor was modeled as a three-phase dynamic system where the coke is the porous solid phase, the vacuum residue the liquid phase and the distillable product the gas phase. Equations of continuity, momentum, and energy proposed to describe the coking dynamic process where discretized employing the finite volume method and the domain was defined by a 2D structured axisymmetric grid. A PEA algorithm was developed to account for the drag between the fluid phases, and a modified SIMPLEC algorithm achieved the pressure-velocity coupling. The CFD simulator was programmed in C++ code for Linux operating system; all the graphics were constructed in ParaView visualization platform. A full run of 12 hours and the cooling of the resulting coke bed for three different vacuum residues were simulated, the results were compared with experimental data and a good agreement was observed, the simulator demonstrated great potential to be scaled up to industrial level.