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1. Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations

Author

Nahum R. Pineda, Ernesto Schulz Lang, Andressa Lunardi, Sailer Santos dos Santos, Camila Nunes Cechin, Bárbara Tirloni, Robert A. Burrow, Tanize Bortolotto, Paulo Piquini, and Roberta Cargnelutti

Subjects
Chemistry, Polymer chemistry, Materials Chemistry, Zinc compounds, Zinc selenite, General Chemistry, Spectroscopy, Catalysis, Structural chemistry
Abstract

Novel tetranuclear zinc compounds, [Zn4(μ-SeO3)2(μ4-SeO3)2(bipy)4]·11H2O (1) and [Zn4(μ-SeO3)2(μ4-SeO3)2(phen)4]·9H2O (2), which are the first examples of organically templated zinc selenite compounds containing closed-frameworks, have been synthesized via solvothermal processes. The compounds were characterized by spectroscopy, crystallographic methods and DFT calculations.

Published
2020
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