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1. Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives

Author

Michihisa Ueda, Kjell Jorner, Young Mo Sung, Tadashi Mori, Qi Xiao, Dongho Kim, Henrik Ottosson, Takuzo Aida, and Yoshimitsu Itoh

Subjects
Science
Abstract

Baird’s rule applies to cyclic π-conjugated molecules in their excited state, yet a quantification of the involved energetics is elusive. Here, the authors show the ring inversion kinetics of two nonplanar and chiral [4n]annulenes to support Baird’s rule from an energetic point of view.

Published
2017
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