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• Grout injection produced effects similar to those induced by tunnels excavation. • Protective barrier significantly reduced tunnel-induced ground settlement. • Simulating grout injection ensures agreement between observed and computed settlements. • Simulating side activities as wished-in-place may yield inaccurate predictions. Line C of Rome underground will cross the city from southeast to northwest, with a total length of about 25 km, passing through the historical city centre. This is a difficult environment due to many archaeological finds and pre-existing buildings of great historical value. Along stretch T3 of the line two conventional tunnels connect the TBMs launching pit to the new San Giovanni station. They run for a length of 140 m at a depth of about 25 m and reach the station passing at a short distance from the ancient Aurelian Walls (3rd century CE). Excavation of these tunnels was carried out following a three-stage procedure: (i) excavation of two small diameter tunnels (D = 3 m) using a mini slurry shield machine; (ii) soil improvement via cement grouting using tubes à manchettes installed radially from the mini-tunnels; and (iii) conventional excavation of the two running tunnels in the improved soil. An extensive monitoring system was set to control ground movements induced throughout the excavation process. This paper presents the displacement measured at the ground surface during the construction activities, highlighting the effects induced by grouting. The effectiveness of a protective barrier, made by a line of piles, in reducing the movements induced by tunnelling in the Aurelian Walls is also assessed. A 2D FE back-analysis is finally presented, showing that a satisfactory description of the observed behaviour can only be obtained by simulating the volume changes induced by the cement grouting. [ABSTRACT FROM AUTHOR]

This paper reports on a compact, portable, and selective chemical sensor for hazardous vapors at trace levels, which is under development and validation within the EU project H2020 "RISEN". Starting from the prototype developed for a previous EU project, here, we implemented an updated two-stage purge and trap vapor pre-concentration system, a more compact MEMS- based fast gas-chromatographic separation module (Compact-GC), a new miniaturized quartz-enhanced photoacoustic spectroscopy (QEPAS) detector, and a new compact laser source. The system provides two-dimensional selectivity combining GC retention time and QEPAS spectral information and was specifically designed to be rugged, portable, suitable for on-site analysis of a crime scene, with accurate response in few minutes and in the presence of strong chemical background. The main upgrades of the sensor components and functional modules will be presented in detail, and test results with VOCs, simulants of hazardous chemical agents, and drug precursors will be reported and discussed. [ABSTRACT FROM AUTHOR]

The seismic performance of earth dams can nowadays be performed via dynamic analyses using constitutive models of sufficient accuracy in describing cyclic soil behavior. However, a number of assumptions different from soil model affect the problem as a whole. In this paper, a 2D model of a simplified homogeneous earth dam is developed, to assess the influence of bedrock compliance, vertical component of ground motion, stabilizing berms, and initial pore water pressure distribution on its seismic performance, thus providing some guidance on the choices that should be adopted for a safe assessment of the seismic performance of existing earth dams. [ABSTRACT FROM AUTHOR]

The C Line of the Rome underground underpasses the historical city center, facing significant problems for the presence of archaeological artefacts and the necessity to prevent damage to the historical and monumental heritage. This paper describes the field performance of a 30-m-deep excavation that has been constructed at a short distance from the Aurelian Walls at Porta Asinaria (third century). An extensive instrumentation program was conducted during construction, as well as field observations including deflection of the diaphragm walls, ground movements, pore water pressures, settlements, and rotation of the Aurelian Walls. Observed ground settlements and diaphragm wall displacements were smaller than those monitored in other case histories worldwide, inducing no damage to the Aurelian Walls. The lessons learned from this case study showed that a stiff retaining system and a strict control of the construction sequence were the key to minimize the effects of a deep excavation with millennia of history at risk. [ABSTRACT FROM AUTHOR]

In the last decades, Italy has experienced several strong earthquakes, triggering the attention on the high seismic risk associated with the potential instability of large existing earth dams. Under intense seismic events, dam response depends on various factors including the geometry and the type of water retention scheme. This paper explores the influence of these factors, comparing the seismic performance of two idealized earth dams: a homogeneous dam and a zoned dam. The simplified models adopted in the analyses are representative of these two classes of earth dams, often adopted in the sixties to design various dams located in southern Italy. The idealized models, here examined in detail, have comparable heights and foundation soil conditions, differing in terms of water retention scheme. The seismic response of the dams was evaluated through time‐domain nonlinear dynamic analyses in which the same input ground motion, represented by real‐time histories, was applied at the base of the models. It is shown that for highly inelastic systems, such as those at hand, duration of input motion should be accounted for in addition to compatibility criteria with a design elastic response spectrum. Also, different slopes of dam flanks, shear strength mobilization at the end of dam construction and high stiffness contrast at the shells‐core contacts are shown to result in different deformation patterns at the end of earthquake loading. Some peculiarities in the behavior of these classes of earth dams are highlighted in the paper, providing a guidance for the rational assessment of their seismic performance. [ABSTRACT FROM AUTHOR]

Background: Plant water resource management is one of the main future challenges to fight recent climatic changes. The knowledge of the plant water content could be indispensable for water saving strategies. Terahertz spectroscopic techniques are particularly promising as a non-invasive tool for measuring leaf water content, thanks to the high predominance of the water contribution to the total leaf absorption. Terahertz quantum cascade lasers (THz QCL) are one of the most successful sources of THz radiation. Results: Here we present a new method which improves the precision of THz techniques by combining a transmission measurement performed using a THz QCL source, with simple pictures of leaves taken by an optical camera. As a proof of principle, we performed transmission measurements on six plants of Vitis vinifera L. (cv "Colorino"). We found a linear law which relates the leaf water mass to the product between the leaf optical depth in the THz and the projected area. Results are in optimal agreement with the proposed law, which reproduces the experimental data with 95% accuracy. Conclusions: This method may overcome the issues related to intra-variety heterogeneities and retrieve the leaf water mass in a fast, simple, and non-invasive way. In the future this technique could highlight different behaviours in preserving the water status during drought stress. [ABSTRACT FROM AUTHOR]

Compensation grouting is often employed as a mitigation technique to reduce the settlements induced by tunneling. The efficiency of compensation grouting, defined as the ratio of the volume of heave induced at the ground surface to the volume of injected grout, is strongly dependent on grout properties, injection characteristics, and soil properties. In clayey soils, site observations and laboratory tests show high values of compensation efficiency immediately after injection. However, the efficiency can decrease with time if positive excess pore-water pressures develop in the soil during the injection process. Conversely, in sandy soils, a loss of volume occurs because of pressure filtration of the grout during and soon after the injection process, which reduces the compensation efficiency. This paper describes an analytical model that can be used to evaluate the volume loss produced by pressure filtration of cement-bentonite grouts as a function of soil, grout, and injection parameters. The magnitude of pressure filtration is evaluated as the grout efficiency, which is given by the ratio of the volumes of the final grout body to the injected grout. Results show that the grout efficiency increases with decreasing soil permeability and with increasing grout bentonite content. The result of a grout injection test on a silty soil is back-analyzed using this approach in which the grout efficiency is first evaluated through the proposed filtration model and then used to calibrate a numerical simulation of the test. The good agreement between experimental data and computed results shows that prediction of the efficiency of compensation grouting can be improved using the proposed approach. [ABSTRACT FROM AUTHOR]

Terahertz (THz) spectroscopy and imaging have been heralded for some time as potentially revolutionary techniques for biomedical applications. Label-free detection of molecules and recognition of molecular events are often mentioned as the most exciting possibilities. A crucial practical goal, however, is the ability to perform such measurements on tiny amounts of biological fluids or even on individual organic structures. Living cells, for instance, have diameters at most of some tens of micrometers, i.e. at least λ/10 even for few-THz radiation. Furthermore, all analyses relevant for a biological perspective must be performed in a water environment, which presents a strong absorption across the whole THz spectral range, severely limiting the penetration of the electromagnetic field. Here, it is shown how both issues can be overcome with a lab-on-a-chip approach based on a microfluidic platform coupled to a plasmonic antenna. Using a quantum cascade laser as THz illumination source, liquid volumes down to the picoliter range are probed, and direct operation on individual 10-µm diameter microparticles flowing in water is shown. The present demonstration opens the way to the development of THz biosensing of individual living cells and small probe volumes. [ABSTRACT FROM AUTHOR]

Nanolithography techniques enable the fabrication of complex nanodevices that can be used for biosensing purposes. However, these devices are normally supported by a substrate and their use is limited to in vitro applications. Following a top-down procedure, we designed and fabricated composite inductance-capacitance (LC) nanoresonators that can be detached from their substrate and dispersed in water. The multimaterial composition of these resonators makes it possible to differentially functionalize different parts of the device to obtain stable aqueous suspensions and multi-sensing capabilities. For the first time, we demonstrate detection of these devices in an aqueous environment, and we show that they can be sensitized to their local environment and to chemical binding of specific molecular moieties. The possibility to optically probe the nanoresonator resonance in liquid dispersions paves the way to a variety of new applications, including injection into living organisms for in vivo sensing and imaging. [ABSTRACT FROM AUTHOR]

This paper reports on a portable selective chemical sensor for hazardous vapors at trace levels, which combines a two-stage purge and trap vapor pre-concentration system, a Micro-Electro-Mechanical-System (MEMS) based fast gas-chromatographic (FAST-GC) separation column and a miniaturized quartz-enhanced photoacoustic spectroscopy (QEPAS) detector. The integrated sensing system provides two-dimensional selectivity combining GC retention time and QEPAS spectral information, and was specifically designed to be rugged and suitable to be deployed on unmanned robotic ground vehicles. This is the first demonstration of a miniaturized QEPAS device used as spectroscopic detector downstream of a FAST-GC separation column, enabling real-world analyses in dirty environments with response time of a few minutes. The main modules of the GC/QEPAS sensor device will be described in detail together with the system integration, and successful test results will be reported and discussed. [ABSTRACT FROM AUTHOR]

Water availability is a major limiting factor in plant productivity and plays a key role in plant species distribution over a given area. New technologies, such as terahertz quantum cascade lasers (THz-QCLs) have proven to be non-invasive, effective, and accurate tools for measuring and monitoring leaf water content. This study explores the feasibility of using an advanced THz-QCL device for measuring the absolute leaf water content in Corylus avellana L., Laurus nobilis L., Ostrya carpinifolia Scop., Quercus ilex L., Quercus suber L., and Vitis vinifera L. (cv. Sangiovese). A recently proposed, simple spectroscopic technique was used, consisting in determining the transmission of the THz light beam through the leaf combined with a photographic measurement of the leaf area. A significant correlation was found between the product of the leaf optical depth (τ) and the leaf surface area (LA) with the leaf water mass (Mw) for all the studied species (Pearson's r test, p ≤ 0.05). In all cases, the best fit regression line, in the graphs of τLA as a function of Mw, displayed R2 values always greater than 0.85. The method proposed can be combined with water stress indices of plants in order to gain a better understanding of the leaf water management processes or to indirectly monitor the kinetics of leaf invasion by pathogenic bacteria, possibly leading to the development of specific models to study and fight them. [ABSTRACT FROM AUTHOR]

Marine environments are currently subject to strong ecological pressure due to local and global anthropic stressors, such as pollutants and atmospheric inputs, which also cause ocean acidification and warming. These strains can result in biogeochemical cycle variations, environmental pollution, and changes in benthic-pelagic coupling processes. Two new devices, the Amerigo Lander and the Automatic Benthic Chamber (CBA), have been developed to measure the fluxes of dissolved chemical species between sediment and the water column, to assess the biogeochemical cycle and benthic-pelagic coupling alterations due to human activities. The Amerigo Lander can operate in shallow as well as deep water (up to 6000 m), whereas the CBA has been developed for the continental shelf (up to 200 m). The lander can also be used to deploy a range of instruments on the seafloor, to study the benthic ecosystems. The two devices have successfully been tested in a variety of research tasks and environmental impact assessments in shallow and deep waters. Their measured flux data show good agreement and are also consistent with previous data. [ABSTRACT FROM AUTHOR]