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The Bohaun gold deposit in County Galway, western Ireland, is located in the Caledonian orogenic belt, proximal to a major accretionarv boundary. The mineralization is hosted in a normal extensional fault, representing a zone of repeated extension and vein infilling of open cavities, within clastic sedimentary rocks that have only reached the late diagenetic zone of low-grade metamorphism. The mineralization consists of undeformed veins, stockworks, and breccias. Quartz dominates all the veins and commonly shows multiple growth stages and a variety of classic epithermal textures, including comb, plumose, and banded, indicative of low confining pressures. The veins have a simple mineralogy made up of quartz-sericite-chlorite with minor sulfides, hematite, rare visible gold, with a high silver content (up to 41 wt %), and late barite and dolomite. Vein quartz is associated with two tluids compositions: type I with moderate to high salinity (8.0-23.6 wt % NaCl equiv) and type II with low to moderate salinity (0.0-7.8 wt % NaCl equiv). CO2 contents in both fluid types are <3.5 wt percent. The majority of fluid inclusion homogenization temperatures range from 126° to 257°C and geologically constrained depth estimates (≤5 km) indicate maximmn fluid inclusion trapping temperatures between 175° and 245°C. The geodynamic setting of Bohaun, which is located in a deformed continental margin of an allochthonous terrane, is typical of orogenic gold deposits. However, an orogenic association for the Bohaun mineralization is discounted on the basis of fluid inclusion evidence, atypical vein textures, gold grain composition, and undeformed veins. While vein textures locally resemble those found in epithermal quartz- adularia mineralization, there is no obvious magmatic association and alteration is restricted to the veins and immediate host rocks. The origin of the gold at Bohaun remains enigmatic. However, we favor an association with widespread Carboniferous or later mineralizing fluids and a model which involves transport and deposition of gold from a basinal brine-type fluid, in a similar fashion to red-bed Au-Pd mineralization. Bohaun provides further evidence that low temperature brines may be capable of generating economic-grade gold mineralization, independent of other fluids. [ABSTRACT FROM AUTHOR]

Over the last decade there has been an increasing interest in deep-sea mineral resources that may contribute to future raw metal supply. However, before seafloor massive sulfides (SMS) can be considered as a resource, alteration and weathering processes that may affect their metal tenor have to be fully understood. This knowledge cannot be obtained by assessing the surface exposures alone. Seafloor drilling is required to gain information about the third dimension. In 2016, three extinct seafloor massive sulfide mounds, located in the Trans-Atlantic Geotraverse (TAG) hydrothermal area of the Mid-Atlantic Ridge were drilled. A mineralogical and textural comparison of drill core and surface-grab samples revealed that in recent ceased mounds high-temperature copper assemblages typical for black smoker chimneys are still present whereas in longer extinct mounds the mineralogy is pre-dominated by an iron mineral assemblage. Zinc becomes remobilized early in the mound evolution and forms either a layer in the upper part of the mound or has been totally leached from its interior. Precipitation temperatures of sphalerite calculated using the Fe/Zn ratio can help to identify these remobilization processes. While the Fe/Zn ratios of primary sphalerites yield temperatures that are in very good agreement with fluid temperatures measured in white smokers, calculated temperatures for sphalerites affected by remobilization are too high for SMS. Overall drilling of SMS provides valuable information on the internal structure and mineralogy of the shallow sub-surface, however, additional drilling of SMS, at a greater depth, is required to fully understand the processes affecting SMS and their economic potential. [ABSTRACT FROM AUTHOR]

We present enigmatic toroidal carbonate concretions retrieved from 700 m water depth from two sites in the upper plateau of the Rio Grande Rise. The concretions have a diameter of ~15 cm and a central hole of ~5 cm, and were observed on top of loose bioclastic sand over an area of ~30 m2 at 0.5–1.5 m from one another. They consist of brown, porous, bioclastic grainstone, lacking internal structures. Grains consist of sand (< 3% coarse, 30% medium, 35% fine, 25% very fine), composed mainly by planktonic foraminiferal tests, and < 10% lime mud. The observed foraminiferal species indicate initial deposition of the sand in an open ocean setting. Biostratigraphy suggests an age no older than Pleistocene. Petrographic thin sections and SEM reveal that the fossiliferous grainstone contains intraclastic micritic cement and isopachous rim cement made of bladed magnesian calcite. δ18O values range from +1.5 to +3.3‰ (V-PDB) and increase with the degree of cementation, while δ13C ranges from +0.5 to +2.3‰ irrespective of cementation. The cementation of the grainstones is likely to have taken place in the marine phreatic environment. Carbonate precipitation induced by methane oxidation or (subaerial) meteoric diagenesis are ruled out based on both cement fabric and isotopic composition. Plausible causes for the toroidal shape of these structures could be: 1) sediment excavation by organisms, or 2) cementation within biofilms around burrows, followed by selective seafloor erosion. However, unveiling the actual formation mechanisms warrants further investigation. • First report of toroidal carbonate concretions from the Rio Grande Rise. • The concretions consist of grainstone dominated by planktic foraminifera. • Biostratigraphy suggests an age no older than Pleistocene. • Cement fabric and stable isotopes suggest formation by marine phreatic diagenesis. • No contribution of methane-derived carbonate is found. [ABSTRACT FROM AUTHOR]

• High-frequency Pb isotope variations in Fe-Mn crusts measured by LA-MC-ICP-MS. • LA-MC-ICP-MS allows a 1.5–2 order of magnitude gain in temporal resolution. • Time-frequency analysis shows imprint of climatic precession on Pb isotopes. • Geochemical variations related to differential weathering of Western African Craton. • New complementary dating tool for oceanic oxide deposits with ka resolution. Hydrogenetic ferromanganese crusts are considered a faithful record of the isotopic composition of seawater influenced by weathering processes of continental masses. Given their ubiquitous presence in all oceans of the planet at depths of 400–7000 meters, they form one of the most well-distributed and accessible records of water-mass mixing and climate. However, their slow accumulation rate and poor age constraints have to date limited their use to explore 100 ka paleoclimatic phenomena. Here it is shown how the Pb isotope signature and major element content of a Fe-Mn crust from the north-east Atlantic responded to changes in the intensity and geographic extent of monsoonal rainfall over West Africa, as controlled by climatic precession during the Paleocene. The studied high-spatial resolution (4 μm) laser-ablation multi-collector inductively coupled plasma mass spectrometer (LA-MC-ICP-MS) Pb isotope data is a nearly 2 order of magnitude improvement in spatial and temporal resolution compared to micro-drill subsamples. The record demonstrates cyclicity of the 206Pb/204Pb and 208, 207Pb/206Pb ratios at the scale of single Fe-Mn oxide laminae, in conjunction with variations in the Fe/Mn ratio, Al, Si and Ti content. Time-frequency analysis and astronomical tuning of the Pb isotope data demonstrates the imprint of climatic precession (∼20 ka) modulated by eccentricity (∼100 and 405 ka), yielding growth rates of 1.5–3.5 mm/Ma consistent with previous chemostratigraphic age models. In this context, boreal summer at the perihelion causes stronger insolation over West Africa, resulting in more intense and geographically extended monsoonal rainfalls compared to aphelion boreal summer conditions. This, in turn, influences the balance between the weathering endmembers feeding the north-east Atlantic basin. These results provide a new approach for calibrating Fe-Mn crust records to astronomical solutions, and allow their isotopic and chemical archive to be exploited with an improved temporal resolution of 1000–5000 years. [ABSTRACT FROM AUTHOR]