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The paper presents the results of the synthesis and study of CuAl layered double hydroxides (LDHs) as well as their application as catalysts for the selective hydrogenation of crotonaldehyde. Phase-homogeneous LDHs were obtained by co-precipitation and mechanochemical methods, and critical parameters ensuring the formation of the target product were identified. In the case of coprecipitation, the formation of LDH is most affected by the pH of the reaction medium and the CO32−/Al3+ ratio. The optimal CO32−/Al3+ ratio is ca. 0.5–0.8 and pH 9.5–10.0. When mechanochemical synthesis is used, at 500 m·s−2 and 60 min, it is possible to obtain a single-phase CuAl LDH, whereas at higher energies, LDH is destroyed. The mechanochemical method makes it possible not only to reduce the synthesis time and the amount of alkaline wash water but also to obtain more dispersed copper particles with a higher hydrogenating activity. The conversion of 2-butenal (T = 80 °C, P = 0.5 MPa, 180 min, ethanol) for this sample was 99.9%, in contrast to 50.5% for the catalyst obtained by co-precipitation. It is important that, regardless of the conversion, both catalysts showed high selectivity (S = 90–95%) for the double bond hydrogenation. [ABSTRACT FROM AUTHOR]

Nickel catalysts with carbon-mineral supports derived from sapropel were synthesized; the effect exerted by the nature of the support (type of the initial sapropel) and active component precursor on the activity of the catalysts in the model reaction of liquid-phase nitrobenzene hydrogenation was studied. The catalysts, synthesized using the support with a smaller fraction of carbon, were more active irrespective of the precursor nature. The highest activity was observed for the catalysts synthesized from nickel nitrate and formate; nitrobenzene conversion was 65% and 51%, respectively, after 1 h of reaction. The catalysts retained high activity after six reaction cycles at 100% aniline selectivity. The presence of sulfur in the nickel precursor deteriorated the catalytic activity (convection less than 3%) due to formation of the sulfide phase. [ABSTRACT FROM AUTHOR]

Porous carbon–carbon composite materials (PCCCM) were synthesized by the alkaline dehydrochlorination of polyvinyl chloride solutions in dimethyl sulfoxide containing the modifying additives of a nanostructured component (NC): graphite oxide (GO), reduced graphite oxide (RGO) or nanoglobular carbon (NGC), with subsequent two-step thermal treatment of the obtained polyvinylene–NC composites (carbonization at 400 °C and carbon dioxide activation at 900 °C). The focus of the study was on the analysis and digital processing of transmission electron microscopy images to study local areas of carbon composite materials, as well as to determine the distances between graphene layers. TEM and low-temperature nitrogen adsorption studies revealed that the structure of the synthesized PCCCM can be considered as a porous carbon matrix in which either carbon nanoglobules (in the case of NGC) or carbon particles with the "crumpled sheet" morphology (in the case of GO or RGO used as the modifying additives) are distributed. Depending on the features of the introduced 5–7 wt.% nanostructured component, the fraction of mesopores was shown to vary from 11% to 46%, and SBET—from 791 to 1115 m2 g−1. The synthesis of PCCNC using graphite oxide and reduced graphite oxide as the modifying additives can be considered as a method for synthesizing a porous carbon material with the hierarchical structure containing both the micro- and meso/macropores. Such materials are widely applied and can serve as adsorbents, catalyst supports, elements of power storage systems, etc. [ABSTRACT FROM AUTHOR]

Changes in the structural and textural properties of NiAl-layered double hydroxides (LDHs) (with 2–4 molar ratios of metals) and state of nickel that occur in different steps of the synthesis of nickel catalysts were studied using XRD, thermal analysis, TPR, low-temperature nitrogen adsorption, XANES, EXAFS, and electron microscopy methods. Relations between nickel content, catalyst reduction conditions, state of nickel, and its catalytic properties were revealed. It was shown that the use of NiAl LDH as the catalyst precursor even at a high content of active metal allows for the obtaining of the dispersed particles of supported nickel that are active in the aqueous-phase hydrogenation of furfural. The catalyst activity and conversion of furfural were found to increase with elevation of the catalyst reduction temperature and the corresponding growth of the fraction of reduced nickel. However, a lower reduction temperature (500 °C) makes it possible to form smaller nickel particles with the size of 4–6 nm, and a high Ni content (Ni:Al = 4) can be used to obtain the active Ni@NiAlOx catalyst. Under mild reaction conditions (90 °C, 2.0 MPa), the furfural conversion reached 93%, and furfuryl alcohol was formed with the selectivity of 70%. Under more severe reaction conditions (150 °C, 3.0 MPa), complete conversion of furfural was achieved, and cyclopentanol and tetrahydrofurfuryl alcohol were the main hydrogenation products. [ABSTRACT FROM AUTHOR]

Abstract: A facile direct deposition approach for the preparation of recyclable Pd/C catalysts simply by stirring a solution of tris(dibenzylideneacetone)dipalladium(0) with a suitable carbon material was evaluated. An extraordinarily rapid catalyst preparation procedure (<5 min) under mild conditions and its excellent performance in cross‐coupling and hydrogenation reactions were demonstrated. The key point for catalyst design is the direct deposition of Pd0 centers onto the highly accessible surface area and the avoidance of ill‐defined PdII/Pd0 states. [ABSTRACT FROM AUTHOR]

• Controllable activity and selectivity of Pd/C hydrogenation catalysts. • Effect of the carbon support on the structure and catalytic properties of Pd NPs. • Effect of the Pd precursor on the structure and catalytic properties of Pd NPs. • Addition of a second metal and the synergistic effect in Pd-based bimetallic catalysts. Carbon-supported palladium catalysts are widely used for hydrogenation of various organic compounds in the fine chemical industry. The nanoscale geometry and electronic structure of supported Pd nanoparticles play a crucial role in providing the necessary catalytic properties. To improve catalytic activity and selectivity of Pd nanoparticles, it is possible to fine tune their intrinsic properties (e.g., size and oxidation state) by controlling the chemical transformations at different stages of catalyst preparation. Recent years have seen considerable advancement in developing new catalyst preparation techniques as well as in understanding the mechanism of active site formation. This review summarizes some of the existing approaches to regulating the catalytic properties of carbon-supported palladium by variation of the carbon support, the composition of palladium precursor and its reduction conditions, as well as the addition of a second active metal. The data presented may be useful for researchers developing efficient Pd/C catalysts for hydrogenation of polyfunctional organic compounds. [ABSTRACT FROM AUTHOR]

• MgAl-layered hydroxides were synthesized on the surface of γ-Al 2 O 3 using its Al atoms. • Modification of alumina changed the mechanism of [PtCl 6 ]2− anchoring. • Adsorption occurs with localization of 2–4 nm platinum particles in the MgAl-phase. • Catalyst with supported LDH provides a higher stability in propane dehydrogenation. Layered magnesium-aluminum hydroxides of hydrotalcite-like structure were synthesized on the surface of γ-Al 2 O 3. The synthesis was performed via the interaction of aluminum and magnesium hydroxides and carbonate ions in the pores of alumina support. Novelty of the approach was that the synthesis involved the boehmite phase AlO(OH) that formed directly on the surface of γ-Al 2 O 3 under hydrothermal conditions. This approach provides fixation of the forming layered phase on the surface of initial support and retains textural parameters of the support. The formation of a layered structure on the γ-Al 2 O 3 surface was confirmed by XRD analysis and electron microscopy studies. Investigation of the H 2 [PtCl 6 ] anchoring on γ-Al 2 O 3 with supported magnesium-aluminum hydroxide by UV–vis DRS, 195Pt NMR and HRTEM showed that platinum was adsorbed on the surface as chloride forms of the complexes with a low degree of hydrolysis even at a low metal content. Catalytic properties of the synthesized supported platinum catalysts were examined in a model reaction of propane dehydrogenation. In comparison with the alumina-platinum catalyst, the modified sample showed a better stability at a somewhat higher yield of propylene because the formation of heavy products was suppressed. [ABSTRACT FROM AUTHOR]

Carbon nanofibers (CNFs) have been rapidly synthesized on the surface of low-cost commercial chlorinated polymers (chlorinated polyvinyl chloride, polyvinyl chloride), which contains iron compounds, under the action of a high power ion beam at room temperature. Organic (Fe(C 5 H 5 ) 2 ) and inorganic (FeCl 3 ⋅6H 2 O и Fe(NO 3 ) 3 ·9H 2 O) iron compounds were used as catalytic additions. SEM, TEM and Raman spectroscopy were used to investigate the morphologies and structure of irradiated polymers. CNFs had a most probable diameter in the range 50–90 nm and a maximum length of up to 10 μm. The maximum CNFs growth rate was estimated as 160 μm/μs. A possible growth mechanism for CNFs is discussed. [ABSTRACT FROM AUTHOR]

The palladium catalysts prepared using carbon nanoglobules (CNGs) as the support and containing no more than 2 wt% Pd were shown to be highly effective for the liquid-phase hydrogenation of ethyl 4-nitrobenzoate under mild conditions. Regardless of the kind of CNGs and the catalyst preparation method, the most of the Pd/CNGs catalysts allow achieving a complete conversion of substrate giving benzocaine in a 100% yield. The Pd/CNGs catalyst is easily recycled many times without loss of its catalytic performance. The results obtained may be useful for the development of effective Pd/C catalysts for chemoselective hydrogenation of various nitroarenes. [ABSTRACT FROM AUTHOR]

Highlights: [•] Increase the fraction of bridging OH groups and concentration of Lewis acid sites. [•] Preferential formation of outer-sphere complexes. [•] Changes in the dispersion and electronic state of supported Pt. [•] Effect of hydrothermal treatment of the support on catalytic properties of Pt/Al2O3. [ABSTRACT FROM AUTHOR]