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1. Enantiospecific synthesis of sex pheromone of the obscure mealybug from pantolactone via tandem conjugate addition/cyclization

Author

Laxmikant Datrange, Debnath Bhuniya, D. Srinivasa Reddy, Samir Vyas, and Hajare Atul Kashinath

Subjects
chemistry.chemical_classification, Tandem, Double bond, Chemistry, Stereochemistry, Organic Chemistry, Biochemistry, Cascade reaction, Sex pheromone, Drug Discovery, Pheromone, Stereoselectivity, Enantiomer, Conjugate
Abstract

An efficient synthesis of an enantiomer of insect’s natural pheromone is reported starting from chiral pool d-(−)-pantolactone. Highly stereoselective tandem conjugate addition/cyclization sequence and hydrogenation of exocyclic double bond are the key steps in the present synthesis.

Published
2010
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