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The variation in heavy metal concentration in different environment is dependent on the emission source. Source identification of heavy metal plays an important role in providing solution to its contamination in the atmosphere. Hence, the objective of this paper is to engage enrichment factor (EF) approach to evaluate the source identification of potentially toxic heavy metals along the Benin-Ore-Sagamu Expressway in Nigeria in four sampling locations (A, B, C and D) that are denoted with high traffic congestion. The source identification of Cu, Zn, Mn, Ni, Pd, Cd, Cr and Pb contamination in the study area were determined using appropriate standard methods. The EF values indicated for Cu ranged from (2.3-5.9), Zn (0.48-0.86), Mn (0.29-0.49), Ni (1.27-4.03), Pd (37012.18-59922.57), Cd (1909.11-2844.81), Cr (4.56-7.76) and Pb (0.77-4.64). The results suggest crustal source enrichment for Zn and Mn while Cu, Ni, Cr and Pb were enriched moderately. However, the EF values for Pd and Cd were found to be greater than 50, indicating extremely severe enrichment. The findings of this study provide evidence of anthropogenic impact on heavy metals pollution in the study area that is attributed to the intense vehicular traffic.