Search

The influence of the structural type and of the textural and acid properties of the zeolite on the catalyst selectivity in synthesis of a mixture of liquid hydrocarbons with increased content of isoalkanes from dimethyl ether was examined. The synthesis of liquid hydrocarbons enriched in triptane in the course of gasoline production from CO and H2 via dimethyl ether in the presence of La-H-Y zeolite was performed for the first time. Excess hydrogen in the system and relatively short contact time of the catalyst with the feed favor an increase in the triptane yield. Additional modification with palladium leads to optimization of the acid properties of the La-H-Y zeolite and, as a consequence, to an increase in the triptane content of the gasoline from 2.0 to 9.4 wt %. [ABSTRACT FROM AUTHOR]

The effect of the method of introduction of zinc cations and the zinc content in a nanocrystalline zeolite of the ZSM-5 type on the physicochemical and catalytic properties of the material in DME conversion to a mixture of liquid synthetic hydrocarbons has been studied. Zinc is introduced into the catalysts both during the zeolite synthesis and the ion exchange (ZnnAlmNZ5 and ZnnZ5, respectively). The use of nanocrystalline ZnnAlmNZ5 zeolites provides the formation of a mixture of liquid hydrocarbons with a high selectivity of no less than 90%; the liquid hydrocarbons contain more than 70% of isoparaffins and a small amount of aromatic compounds. An increase in the zinc loading of the ZnnAlmNZ5 zeolite from 0.9 to ~3% leads to an increase in the methanol content in the aqueous phase of the liquid product, an increase in the selectivity for liquid hydrocarbons, and a slight increase in the concentration of aromatic and unsaturated hydrocarbons in the mixture. In the presence of the ZnnZ5/Al2O3 catalyst with Zn introduced by ion exchange, the methanol content in the aqueous phase and the aromatics content in the liquid hydrocarbon mixture are significantly higher. The ZnnAlmNZ5 nanozeolites are characterized by a more developed external surface, a higher concentration of mesopores, and higher acidity. [ABSTRACT FROM AUTHOR]