13 results on '"Hellsing, Maja"'
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2. Interaction of Moringa oleifera seed protein with a mineral surface and the influence of surfactants
- Author
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Kwaambwa, Habauka M., Hellsing, Maja S., Rennie, Adrian R., and Barker, Robert
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- 2015
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3. Structural Characterization Study of a Lipid Nanocapsule Formulation Intended for Drug Delivery Applications Using Small-Angle Scattering Techniques.
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Urimi, Dileep, Hellsing, Maja, Mahmoudi, Najet, Söderberg, Christopher, Widenbring, Ronja, Gedda, Lars, Edwards, Katarina, Loftsson, Thorsteinn, and Schipper, Nicolaas
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- 2022
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4. A Bibliometric Study on Swedish Neutron Users for the Period 2006–2020.
- Author
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Barriga, Hanna, Cárdenas, Marité, Hall, Stephen, Hellsing, Maja, Karlsson, Maths, Pavan, Adriano, Peng, Ru, Strandqvist, Nanny, and Wolff, Max
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NEUTRONS ,NUCLEAR physics ,BIBLIOMETRICS ,NEUTRON scattering ,MATERIALS science - Abstract
The overriding objectives of the SNSS are to provide a forum for discussion and exchange of information related to neutron scattering, to stimulate the use of neutron techniques at present-day and future neutron sources, to promote cooperation in neutron science, and to strengthen and broaden the competence in neutron science in Sweden. From the analysis it seems that the current neutron access schemes available to Swedish based users adequately compensate for the loss of the Studsvik reactor as national facility, however, with a risk of a missing national center coordinating neutron related activities. The Swedish Neutron Scattering Society (SNSS) is an organization open to all those associated with Sweden who are using, or interested in the use of, neutron scattering techniques. Additionally, SNSS represents Swedish neutron scatterers in strategic discussions with funding agencies, universities, scattering communities, and neutron facilities. [Extracted from the article]
- Published
- 2021
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5. Salt induced polystyrene latex flocs investigated by neutron scattering.
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Kwaambwa, Habauka M., Hellsing, Maja S., Rennie, Adrian R., Bleuel, Markus, and Wasbrough, Matthew J.
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MORINGA , *FLOCCULATION , *SALT , *POLYSTYRENE , *FERRIC chloride , *ELECTROLYTES - Abstract
Studies with a model system consisting of polystyrene latex particles showed that the protein from seeds of Moringa trees adsorbs to the surface and causes flocculation as unusually dense aggregates. In this study, electrolytes sodium chloride (NaCl), ferric chloride (FeCl 3 ) and aluminium sulfate (Al 2 (SO 4 ) 3 ) have been used to aggregate model polystyrene particles. The study augments previous work using neutron scattering on the flocculation of polystyrene latex with protein from seeds of Moringa trees that had indicated higher floc dimension, d f , values as the concentration of particles increased. The measurements were made using ultra small-angle neutron scattering. Generally the fractal dimension, and thus the floc density, increased with particle concentration and salt concentration. Flocculation was apparent at much lower concentrations of FeCl 3 and Al 2 (SO 4 ) 3 than of NaCl. The values of d f were found not to simply scale with ionic strength for the three electrolytes studied with FeCl 3 being the most effective flocculating agent. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
6. Grazing-incidence small-angle neutron scattering from structures below an interface.
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Nouhi, Shirin, Hellsing, Maja S., Kapaklis, Vassilios, and Rennie, Adrian R.
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GRAZING incidence , *SMALL-angle neutron scattering , *COLLOIDS , *SOLID-liquid interfaces , *PENETRATION depth (Superconductors) - Abstract
Changes of scattering are observed as the grazing angle of incidence of an incoming beam increases and probes different depths in samples. A model has been developed to describe the observed intensity in grazing-incidence small-angle neutron scattering (GISANS) experiments. This includes the significant effects of instrument resolution, the sample transmission, which depends on both absorption and scattering, and the sample structure. The calculations are tested with self-organized structures of two colloidal samples with different size particles that were measured on two different instruments. The model allows calculations for various instruments with defined resolution and can be used to design future improved experiments. The possibilities and limits of GISANS for different studies are discussed using the model calculations. [ABSTRACT FROM AUTHOR]
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- 2017
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7. Sorption of perfluoroalkyl substances to two types of minerals.
- Author
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Hellsing, Maja S., Josefsson, Sarah, Hughes, Arwel V., and Ahrens, Lutz
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FLUOROALKYL compounds , *SORPTION , *SOIL mineralogy , *NEUTRON scattering , *CHAIN length (Chemistry) , *ELECTROSTATIC interaction - Abstract
The sorption of perfluoroalkyl substances (PFASs) was investigated for two model soil mineral surfaces, alumina (Al 2 O 3 ) and silica (SiO 2 ), on molecular level using neutron scattering. The PFASs were selected (i.e. perfluorohexanoic acid (PFHxA), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), and perfluorooctane sulfonic acid (PFOS)) to examine the role of hydrophobic chain length and hydrophilic functional group on their sorption behaviour. All four PFASs were found to sorb to alumina surface (positively charged) forming a hydrated layer consisting of 50% PFASs. The PFAS solubility limit, which decrease with chain length, was found to strongly influence the sorption behaviour. The sorbed PFAS layer could easily be removed by gentle rinsing with water, indicating release upon rainfall in the environment. No sorption was observed for PFOA and PFOS at silica surface (negatively charged), showing electrostatic interaction being the driving force in the sorption process. [ABSTRACT FROM AUTHOR]
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- 2016
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8. Structure of flocs of latex particles formed by addition of protein from Moringa seeds.
- Author
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Hellsing, Maja S., Kwaambwa, Habauka M., Nermark, Fiona M., Nkoane, Bonang B.M., Jackson, Andrew J., Wasbrough, Matthew J., Berts, Ida, Porcar, Lionel, and Rennie, Adrian R.
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MOLECULAR structure , *LATEX , *ADDITION reactions , *MORINGA , *SEED proteins , *PLANT extracts - Abstract
Proteins extracted from the seeds of Moringa trees are effective flocculents for particles dispersed in water and are attractive as a natural and sustainable product for use in water purification. Studies with a model system consisting of polystyrene latex particles have shown that the protein adsorbs to the surface and causes flocculation as unusually dense aggregates. Small-angle neutron scattering that exploits contrast matching of deuterated latex particles dispersed in D 2 O to highlight bound protein has shown that the adsorbed amount reaches about 3 mg m −2 . The particles form very compact flocs that are characterized by fractal dimensions that approach the theoretical maximum of 3. Ultra small-angle neutron scattering allows these flocs to be characterized for a range of particle and protein concentrations. Proteins from two species of Moringa trees were investigated. The protein from Moringa stenopetala seeds gave rise to slightly lower fractal dimensions compared to Moringa oleifera , but still much larger than values observed for conventional ionic or polymeric flocculents that are in the range 1.75–2.3. Compact flocs are desirable for efficient separation of impurities and dewatering of sludge as well as other applications. A trend of increasing fractal dimension with particle concentration was observed when M. stenopetala seed protein was used and this resembles the behaviour predicted in Brownian dynamics simulation of flocculation. [ABSTRACT FROM AUTHOR]
- Published
- 2014
- Full Text
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9. Learning about SANS instruments and data reduction from round robin measurements on samples of polystyrene latex.
- Author
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Rennie, Adrian R., Hellsing, Maja S., Wood, Kathleen, Gilbert, Elliot P., Porcar, Lionel, Schweins, Ralf, Dewhurst, Charles D., Lindner, Peter, Heenan, Richard K., Rogers, Sarah E., Butler, Paul D., Krzywon, Jeffery R., Ghosh, Ron E., Jackson, Andrew J., and Malfois, Marc
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POLYSTYRENE , *MULTIPLE scattering (Physics) , *SCATTERING (Mathematics) , *SCATTERING (Physics) , *DATA reduction , *AUTOMATIC data collection systems - Abstract
Measurements of a well-characterized `standard' sample can verify the performance of an instrument. Typically, small-angle neutron scattering instruments are used to investigate a wide range of samples and may often be used in a number of configurations. Appropriate `standard' samples are useful to test different aspects of the performance of hardware as well as that of the data reduction and analysis software. Measurements on a number of instruments with different intrinsic characteristics and designs in a round robin can not only better characterize the performance for a wider range of conditions but also, perhaps more importantly, reveal the limits of the current state of the art of small-angle scattering. The exercise, followed by detailed analysis, tests the limits of current understanding as well as uncovering often forgotten assumptions, simplifications and approximations that underpin the current practice of the technique. This paper describes measurements of polystyrene latex, radius 720 Å, with a number of instruments. Scattering from monodisperse, uniform spherical particles is simple to calculate and displays sharp minima. Such data test the calibrations of intensity, wavelength and resolution as well as the detector response. Smoothing due to resolution, multiple scattering and polydispersity has been determined. Sources of uncertainty are often related to systematic deviations and calibrations rather than random counting errors. The study has prompted development of software to treat modest multiple scattering and to better model the instrument resolution. These measurements also allow checks of data reduction algorithms and have identified how they can be improved. The reproducibility and the reliability of instruments and the accuracy of parameters derived from the data are described. [ABSTRACT FROM AUTHOR]
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- 2013
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10. Note: Sample cells to investigate solid/liquid interfaces with neutrons.
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Rennie, Adrian R., Hellsing, Maja S., Lindholm, Eric, and Olsson, Anders
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SOLID-liquid interfaces , *NEUTRON reflectivity , *GRAZING incidence , *SMALL-angle scattering , *SCATTERING (Physics) - Abstract
The design of sample cells to study solid/liquid interfaces by neutron reflection is presented. Use of standardized components and a modular design has allowed a wide range of experiments that include grazing incidence scattering and conventional small-angle scattering. Features that reduce background scattering are emphasized. Various flow arrangements to fill and replenish the liquid in the cell as well as continuous stirring are described. [ABSTRACT FROM AUTHOR]
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- 2015
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11. Sticking particles to solid surfaces using Moringa oleifera proteins as a glue.
- Author
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Nouhi, Shirin, Pascual, Marc, Hellsing, Maja S., Kwaambwa, Habauka M., Skoda, Maximilian W.A., Höök, Fredrik, and Rennie, Adrian R.
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MORINGA oleifera , *PLANT protein analysis , *ADHESION , *POLYSTYRENE , *ATOMIC force microscopy - Abstract
Experimental studies have been made to test the idea that seed proteins from Moringa oleifera which are novel, natural flocculating agents for many particles could be used to promote adhesion at planar interfaces and hence provide routes to useful nanostructures. The proteins bind irreversibly to silica interfaces. Surfaces that had been exposed to protein solutions and rinsed were then exposed to dispersions of sulfonated polystyrene latex. Atomic force microscopy was used to count particle density and identified that the sticking probability was close to 1. Measurements with a quartz crystal microbalance confirmed the adhesion and indicated that repeated exposures to solutions of Moringa seed protein and particles increased the coverage. Neutron reflectivity and scattering experiments indicate that particles bind as a monolayer. The various results show that the 2S albumin seed protein can be used to fix particles at interfaces and suggest routes for future developments in making active filters or improved interfaces for photonic devices. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
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12. Interactions of perfluoroalkyl substances with a phospholipid bilayer studied by neutron reflectometry.
- Author
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Nouhi, Shirin, Ahrens, Lutz, Campos Pereira, Hugo, Hughes, Arwel V., Campana, Mario, Gutfreund, Philipp, Palsson, Gunnar K., Vorobiev, Alexei, and Hellsing, Maja S.
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PHOSPHOLIPIDS , *FUNCTIONAL groups , *SULFONAMIDES , *BILAYER lipid membranes , *NEUTRON reflectometry - Abstract
The interactions between perfluoroalkyl substances (PFASs) and a phospholipid bilayer (1,2-dimyristoyl-sn-glycero-3-phosphocholine) were investigated at the molecular level using neutron reflectometry. Representative PFASs with different chain length and functional groups were selected in this study including: perfluorobutane sulfonate (PFBS), perfluorohexanoate (PFHxA), perfluorohexane sulfonate (PFHxS), perfluorononanoate (PFNA), perfluorooctane sulfonate (PFOS), and perfluorooctane sulfonamide (FOSA). All PFASs were found to interact with the bilayer by incorporation, indicating PFAS ability to accumulate once ingested or taken up by organisms. The interactions were observed to increase with chain length and vary with the functional group as SO 2 NH 2 (FOSA) > SO 2 O − (PFOS) > COO − (PFNA). The PFAS hydrophobicity, which is strongly correlated with perfluorocarbon chain length, was found to strongly influence the interactions. Longer chain PFASs showed higher tendency to penetrate into the bilayer compared to the short-chain compounds. The incorporated PFASs could for all substances but one (PFNA) be removed from the lipid membrane by gentle rinsing with water (2 mL min −1 ). Although short-chain PFASs have been suggested to be the potentially less bioaccumulative alternative, we found that in high enough concentrations they can also disturb the bilayer. The roughness and disorder of the bilayer was observed to increase as the concentration of PFASs increased (in particular for the high concentrations of short-chain substances i.e. PFHxA and PFBS), which can be an indication of aggregation of PFASs in the bilayer. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
- View/download PDF
13. Controlling adsorption of albumin with hyaluronan on silica surfaces and sulfonated latex particles.
- Author
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Berts, Ida, Fragneto, Giovanna, Porcar, Lionel, Hellsing, Maja S., and Rennie, Adrian R.
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ALBUMINS , *HYALURONIC acid , *SILICA , *SURFACE chemistry , *SULFONATION - Abstract
Polysaccharides are known to modify binding of proteins at interfaces and this paper describes studies of these interactions and how they are modified by pH. Specifically, the adsorption of human serum albumin on to polystyrene latex and to silica is described, focusing on how this is affected by hyaluronan. Experiments were designed to test how such binding might be modified under relevant physiological conditions. Changes in adsorption of albumin alone and the co-adsorption of albumin and hyaluronan are driven by electrostatic interactions. Multilayer binding is found to be regulated by the pH of the solution and the molecular mass and concentration of hyaluronan. Highest adsorption was observed at pH below 4.8 and for low molecular mass hyaluronan (≤150 kDa) at concentrations above 2 mg ml −1 . On silica with grafted hyaluronan, albumin absorption is reversed by changes in solvent pH due to their strong electrostatic attraction. Albumin physisorbed on silica surfaces is also rinsed away with dilute hyaluronan solution at pH 4.8. The results demonstrate that the protein adsorption can be controlled both by changes of pH and by interaction with other biological macromolecules. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
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