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1. Azoarene activation for Schmidt-type reaction and mechanistic insights

Author

Fan-Tao Meng, Ya-Nan Wang, Xiao-Yan Qin, Shi-Jun Li, Jing Li, Wen-Juan Hao, Shu-Jiang Tu, Yu Lan, and Bo Jiang

Subjects
Science
Abstract

The Schmidt reaction enables nitrogen insertion across an aldehyde or ketone substrate by frequently using azide reagents. Here, the authors show a Schmidt reaction of aryldiazonium salts as a replacement of azide reagents to access skeletally diverse cyclic lactams.

Published
2022
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