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Silver cluster‐based solids have garnered considerable attention owing to their tunable luminescence behavior. While surface modification has enabled the construction of stable silver clusters, controlling interactions among clusters at the molecular level has been challenging due to their tendency to aggregate. Judicious choice of stabilizing ligands becomes pivotal in crafting a desired assembly. However, detailed photophysical behavior as a function of their cluster packing remained unexplored. Here, we modulate the packing pattern of Ag12 clusters by varying the nitrogen‐based ligand. CAM‐1 formed through coordination of the tritopic linker molecule and NC‐1 with monodentate pyridine ligand; established via non‐covalent interactions. Both the assemblies show ligand‐to‐metal‐metal charge transfer (LMMCT) based cluster‐centered emission band(s). Temperature‐dependent photoluminescence spectra exhibit blue shifts at higher temperatures, which is attributed to the extent of the thermal reverse population of the S1 state from the closely spaced T1 state. The difference in the energy gap (ΔEST) dictated by their assemblies played a pivotal role in the way that Ag12 cluster assembly in CAM‐1 manifests a wider ΔEST and thus requires higher temperatures for reverse intersystem crossing (RISC) than assembly of NC‐1. Such assembly‐defined photoluminescence properties underscore the potential toolkit to design new cluster‐ assemblies with tailored optoelectronic properties. [ABSTRACT FROM AUTHOR]

B MATERIALS AND METHODOLOGY: b 21 healthy newborn piglets were divided into 3 cohorts to either receive normal saline vehicles (control group A, n=6), bicuculine 4mg/kg IV (seizure group B, n= 7) to induce seizures or bicuculine 4mg/kg IV followed by phenobarbitone loading dose 20mg/kg after 10 min of continuous electrical seizures (treated seizure group C, n=8) over two time points 3h apart. Electrographic seizures were identified in 296 (33.9%) newborns, in which 26 (10.6%) had status epilepticus, 170 (69.7%) repetitive seizures and 48 (19.7%) single seizure. A comparison of treatment pathways for seizures in newborns across rural and non-rural level... B Dickman J b SP 1 sp , Carrasco McCaul M SP 1 sp I SP 1 sp University Of Wisconsin School Of Medicine And Public Health, Madison, United States i B BACKGROUND: b Seizures are more common during the neonatal period than at any other age, occurring at a rate of 1.10-5.5 per 1,000 live births. Amplitude integrated electroencephalography combined with raw electroencephalography and video imaging (video aEEG/EEG) provides real-time screening for seizure detection. The survey collected information regarding the evaluation of neonatal seizures, anti-seizure medication availability, electroencephalogram (EEG) monitoring methods, and if and how an official treatment pathway for neonatal seizure patients was established at their institution. [Extracted from the article]

Security has always been of paramount importance to humans. In the absence of a sense of security at one's workplace, home or anywhere else, people feel uneasy and vulnerable. With the improvement of modern technology, along with the lack of time at hand, the need for faster, efficient, accurate as well as low-cost security techniques is more than ever. Image Captioning for Video Surveillance System is proposed to develop visual systems that generate contextual descriptions about objects in images, and then use these descriptions to provide information of the scene that needs to be secured. The proposed system uses a neural network model composed of a Convolutional Neural Network (CNN) and Long Short-Term Memory (LSTM) to caption the incoming video feed. The main significance of this paper is in integrating the system with Discrete Wavelet Transform (DWT), which is applied on the incoming video feed, so that the compressed LL band frames transferred wirelessly to the model are smaller in comparison, leading to less transfer time and faster processing by the model. [ABSTRACT FROM AUTHOR]