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In this work, linear and nonlinear optical parameters of zinc borotellurite glasses doped with Gd3+ have been studied for all-optical switching applications. A series of gadolinium zinc borotellurite glasses were synthesized by using conventional melt quenching technique. Optical absorption spectra were recorded by UV–vis spectroscopy. From the optical absorption spectra, the cut-off wavelength, optical band gap, Urbach energy and refractive index have been determined and are related to the structural changes in the glass systems. The nonlinear optical properties of Gd3+ doped glasses are investigated by using Z-scan technique. The values of nonlinear refractive index and absorption coefficient with closed and opened apertures of the Z-scan, respectively, were determined for proper utilization in nonlinear optical devices. Keywords: Gadolinium, Rare earth, Borotellurite glass, Optical band gap, Refractive index, Nonlinear optical properties