6 results on '"Andrija Vinković"'
Search Results
2. Influence of the Processing Parameters on the Aroma Profile and Chemical Composition of Conventional and Ecological Cabernet Sauvignon Red Wines during Concentration by Reverse Osmosis
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Ivana Ivić, Mirela Kopjar, Jasmina Obhođaš, Andrija Vinković, Jurislav Babić, Josip Mesić, and Anita Pichler
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conventional and ecological Cabernet Sauvignon ,reverse osmosis ,aroma profile ,chemical composition ,processing parameters ,retention ,Chemical technology ,TP1-1185 ,Chemical engineering ,TP155-156 - Abstract
Wine aroma represents one of the most important quality parameters and it is influenced by various factors, such as climate conditions, viticulture and vinification techniques, storage conditions, etc. Wines produced from conventionally and ecologically grown grapes of the same variety have different chemical compositions and aroma profiles. The composition of wine can also be influenced by the additional treatment of wine, such as the concentration of wine by reverse osmosis (RO). The aim of this study was to investigate the influence of four different pressures (2.5, 3.5, 4.5 and 5.5 MPa) and two temperature regimes (with and without cooling) on the aroma profile and chemical composition of conventional and ecological Cabernet Sauvignon red wine during concentration by reverse osmosis. The results showed that different processing parameters influenced the permeate flux, the retentate temperature and the compounds retention. Higher working pressures (4.5 and 5.5 MPa) and the regime, with cooling, resulted in a higher retention of the total aroma compounds than the opposite processing parameters. The retention of individual compounds depended also on their chemical properties and their interactions with the membrane surface. The reverse osmosis membranes proved to be permeable for ethanol, acetic acid or undesirable 4-ethylphenol and 4-ethylguaiacol that made them applicable for their correction or removal.
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- 2022
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3. Concentration with Nanofiltration of Red Wine Cabernet Sauvignon Produced from Conventionally and Ecologically Grown Grapes: Effect on Volatile Compounds and Chemical Composition
- Author
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Ivana Ivić, Mirela Kopjar, Jasmina Obhođaš, Andrija Vinković, Dubravko Pichler, Josip Mesić, and Anita Pichler
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Cabernet Sauvignon red wine ,ecological wine ,conventional wine ,nanofiltration ,volatile compounds ,chemical composition ,Chemical technology ,TP1-1185 ,Chemical engineering ,TP155-156 - Abstract
Ecological viticulture represent an upward trend in many countries. Unlike conventional viticulture, it avoids the use of chemical fertilizers and other additives, minimizing the impact of chemicals on the environment and human health. The aim of this study was to investigate the influence of nanofiltration (NF) process on volatiles and chemical composition of conventional and ecological Cabernet Sauvignon red wine. The NF process was conducted on laboratory Alfa Laval LabUnit M20 (De Danske Sukkerfabrikker, Nakskov, Denmark) equipped with six NF M20 membranes in a plate module, at two temperature regimes, with and without cooling and four pressures (2.5, 3.5, 4.5 and 5.5 MPa). Different processing parameters significantly influenced the permeate flux which increased when higher pressure was applied. In initial wines and obtained retentates, volatile compounds, chemical composition and elements concentration were determined. The results showed that the higher pressure and retentate cooling was more favourable for total volatiles retention than lower pressure and higher temperature. Individual compound retention depended on its chemical properties, applied processing parameters and wine composition. Nanofiltration process resulted in lower concentrations of ethanol, acetic acid (>50%), 4-ethylphenol and 4-ethylguaiacol (>90%). Different composition of initial feed (conventional and ecological wine) had an important impact on retention of elements.
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- 2021
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4. Efficient removal of U(VI) from aqueous solution using the biocomposite based on sugar beet pulp and pomelo peel
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Mirza Nuhanović, Nerma Curić, Narcisa Smječanin, and Andrija Vinković
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Langmuir ,Aqueous solution ,Sorbent ,Chemistry ,Health, Toxicology and Mutagenesis ,Pulp (paper) ,Public Health, Environmental and Occupational Health ,Biosorption ,engineering.material ,Uranium (VI) ,Biocomposite ,Equilibrium ,Thermodynamics ,Desorption ,010403 inorganic & nuclear chemistry ,01 natural sciences ,Pollution ,0104 chemical sciences ,Analytical Chemistry ,Adsorption ,Nuclear Energy and Engineering ,engineering ,Radiology, Nuclear Medicine and imaging ,Spectroscopy ,Nuclear chemistry - Abstract
A biocomposite sorbent composed of sugar beet pulp and pomelo peel was utilized for the biosorption of uranium (VI) from the aqueous solution. Parameters such as solution pH, biocomposite amount, contact time, temperature and initial concentration of U(VI) ions on the adsorption performance of biocomposite sorbent was studied. The equilibrium data fitted best to the Langmuir’s isotherm model (qe, max = 79.36 mg g–1). Obtained thermodynamic and kinetic parameters demonstrated that the biosorption process is spontaneous, exothermic, and fitted best to the pseudo-second order. The desorption study revealed that uranium recovery by 0.1 M NaHCO3 was 99.24% in the first cycle for used biocomposite.
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- 2021
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5. The Growth and Sporulation of Bacillus subtilis in Nanotesla Magnetic Fields
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Jasmina Obhođaš, Karlo Nađ, Andrija Vinković, Robert Kollar, Jasna Hrenović, Željko Orlić, and Vladivoj Valkovic
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Physics ,biology ,Multiplication rate ,Bacillus subtilis ,equipment and supplies ,biology.organism_classification ,Agricultural and Biological Sciences (miscellaneous) ,Geomagnetic reversal ,Spore ,Magnetic field ,Space and Planetary Science ,Biophysics ,Nanotesla magnetic fields ,Geomagnetic reversals ,Human voyages into deep space ,human activities ,Order of magnitude - Abstract
The order of magnitude of increased growth, multiplication rate, and decreased sporulation of Bacillus subtilis after exposure to nanotesla magnetic fields (MFs) relative to control samples were observed experimentally. Earth’s total magnetic field intensity was reduced from 47.9 +– 0.4 mT to cover the range from 97.5 +– 1.7 nT to 1115 +– 158 nT in eight subsequent experiments by using three pairs of Helmholtz coils combined with Mu-metal shielding. The growth, multiplication rate, sporulation, and potassium content were measured in the probe and control containing B. subtilis cultures after 24 h of exposure to nanotesla and Earth’s magnetic fields, respectively. The observed effect is discussed with regard to its possible repercussions on Earth’s living species during geomagnetic reversals that occurred when the magnetic field was much weaker than the field that exists today. In addition, effects on future manned voyages into deep space, an environment with reduced magnetic field intensity, are considered.
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- 2021
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6. Analysis of carbon in sediments using fast neutron activation analysis (FNAA)
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Vladivoj Valkovic, Jasmina Obhođaš, Karlo Nađ, Andrija Vinković, and Davorin Sudac
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FNAA, Loss-on-Ignition, Sediment, The Black Sea ,chemistry ,Stratigraphy ,Radiochemistry ,Environmental science ,chemistry.chemical_element ,Neutron activation analysis ,Carbon ,Earth-Surface Processes - Abstract
Purpose: Measurement of carbon in cores of undisturbed sediments may provide valuable information on historical trends in sea primary production and carbonate precipitation which can be related to climate changes. Since core sediments are usually subjected to a different analysis, it is important to preserve the sample. Anon-destructive technique for carbon measurement in sedimentsbased on Fast Neutron Activation Analysis (FNAA) has been developed, which might replace the Loss-on-Ignition (LOI) as a conventional method for carbon analysis. Materials and methods: Method was tested on sediment samples collected from the Western Black Sea at depths up to 22 m. A surface sample and a corecut in centimeter intervals were freeze-dried. Samples weighing between 60 and 300 g were irradiated with the portable neutron generator. Gamma rays from 12C(n, n'γ)12C nuclear reaction were collected between 2000 and 4000 s by LaBr3:Ce detector. Standards for direct comparison and construction of the calibration line were prepared as mixtures of different amounts of quartz sand and graphite powder. FNAA results for total carbon (TC) were verified by LOIat 1000°C.LOIat 450°C and treatment with 1 M HCl were used to separate inorganic carbon (IC) and organic carbon(OC), respectively, followed by the FNAA measurements. Results and discussion: Climate effects on physical and biological marine processes are evident as historical changes in carbon flux to sediments. Carbon in sediments is found in the form of the OC produced byphotosynthetic organisms and as IC produced by calcifying organismsand precipitated as calcite. The FNAA is usually applied to samples weighing more than 1 kg. The method was optimized to reduce the minimum weight of the sample to 60 g, after subsequent adaptation of the set-up geometry.Carbon content measured in cores and surface sediment was between 2.8 and 6.1 wt%. OC constituted up to 84% of TC measured in the core.FNAA measurements were in good agreement with LOI analysis. Conclusions: The results have shown that FNAA can be used for the non-destructive determination of carbon in sediments in samples weighing ≥ 60g.FNAA is non-destructive, robust and fast in comparison to conventional methods for carbon determination such as LOI.The disadvantage is a relatively high MDL of 1%.
- Published
- 2019
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