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In an attempt to understand the findings presented in the Comment by Greaves et al. (2023, https://doi.org/10.1029/2023GL103539), we followed their data analysis methodology, omitting the hot and cold‐load calibrations that are an important part of the standard SOFIA GREAT instrument calibration procedure. This process requires scaling of the Venus off‐source spectra by an arbitrary factor, which in turn introduces residuals of the intrinsic receiver bandpass shape as spurious components in the resulting line/continuum spectra. Although these additional artifacts can be reduced via Fourier‐domain spectral filtering, their removal depends on an ill‐constrained interpolation of the Venus continuum across the PH3 spectral line positions, resulting in an unreliable final spectrum. We therefore conclude that the PH3 lines claimed to be detected in the Comment by Greaves et al. (2023, https://doi.org/10.1029/2023GL103539) originate from data/analysis artifacts, and confirm our original result that there is no evidence for phosphine in the SOFIA Venus data. Plain Language Summary: We performed observations using a unique, flying telescope—the Stratospheric Observatory for Infrared Astronomy (SOFIA)—to search for a gas called phosphine in the atmosphere of Venus, which has been suggested to be an indicator for life. The observations, published by Cordiner et al. (2022, https://doi.org/10.1029/2022gl101055), were analyzed carefully but showed no evidence of phosphine. Our findings were called into question in the Comment by Greaves et al. (2023, https://doi.org/10.1029/2023GL103539), who claimed to find phosphine lines in the SOFIA observations after following an unconventional data analysis method. We have investigated their method, and conclude that it is likely to introduce spurious signals into the data, so the claimed phosphine detection is therefore not significant. Key Points: The revised calibration procedure adopted by Greaves et al. (2023, https://doi.org/10.1029/2023GL103539) introduces additional receiver artifacts into the SOFIA 4G2 Venus spectraThe claimed PH3 detection is likely a result of this, combined with interpolation artifacts that occur during subsequent Fourier filteringWe confirm our original conclusion that there is no evidence for phosphine in the SOFIA GREAT Venus data [ABSTRACT FROM AUTHOR]

The presence of phosphine (PH3) in the atmosphere of Venus was reported by Greaves et al. (2021, https://doi.org/10.1038/s41550-020-1174-4), based on observations of the J = 1–0 transition at 267 GHz using ground‐based, millimeter‐wave spectroscopy. This unexpected discovery presents a challenge for our understanding of Venus's atmosphere, and has led to a reappraisal of the possible sources and sinks of atmospheric phosphorous‐bearing gases. Here we present results from a search for PH3 on Venus using the German REceiver for Astronomy at Terahertz Frequencies instrument aboard the Stratospheric Observatory for Infrared Astronomy aircraft, over three flights conducted in November 2021. Multiple PH3 transitions were targeted at frequencies centered on 533 and 1,067 GHz, but no evidence for atmospheric PH3 was detected. Through radiative transfer modeling, we derived a disk‐averaged upper limit on the PH3 abundance of 0.8 ppb in the altitude range 75–110 km, which is more stringent than previous ground‐based studies. Plain Language Summary: We performed observations using a unique, flying telescope—the Stratospheric Observatory for Infrared Astronomy—to search for a gas called phosphine (PH3) in the atmosphere of Venus, which has been suggested to be an indicator for life. Our observations showed no evidence of PH3, in contrast to the original claim, and we provide a stringent upper limit on its abundance. Two other recent studies using different telescopes also found no evidence for PH3 on Venus, in agreement with our present result. Key Points: A recent detection of phosphine (PH3) (a possible biomarker) on Venus at millimeter wavelengths has been called into question by subsequent workWe performed far‐infrared spectroscopic observations of Venus using the German REceiver for Astronomy at Terahertz Frequencies instrument onboard the Stratospheric Observatory for Infrared Astronomy aircraftPH3 was not detected, and a strict upper limit on its atmospheric abundance of 0.8 ppb was derived between 75 and 110 km [ABSTRACT FROM AUTHOR]

We use both new and archival ALMA data of three energy lines each of CN and HCN to explore intensity ratios in dense gas in NGC 3256, NGC 7469, and IRAS 13120-5453. The HCN (3–2)/HCN (1–0) intensity ratio varies in NGC 3256 and NGC 7469, with superlinear trends of 1.53 ± 0.07 and 1.55 ± 0.05, respectively. We find an offset to higher HCN (3–2)/HCN (1–0) intensity ratios (∼0.8) in IRAS 13120-5453 compared to NGC 3256 (∼0.3−0.4) and NGC 7469 (∼0.3−0.5). The HCN (4–3)/HCN (3–2) intensity ratio in NGC 7469 has a slope of 1.34 ± 0.05. We attribute the variation within NGC 3256 to excitation associated with the northern and southern nuclei. In NGC 7469, the variations are localized to the region surrounding the active galactic nucleus. At our resolution (∼700 pc), IRAS 13120-5453 shows little variation in the HCN intensity ratios. Individual galaxies show nearly constant CN (2–1)/CN (1–0) intensity ratios. We find an offset to lower CN (2–1)/CN (1–0) intensity ratios (∼0.5) in NGC 3256 compared to the other two galaxies (∼0.8). For the CN (3–2)/CN (2–1) intensity ratio, NGC 7469 has a superlinear trend of 1.55 ± 0.04, with the peak localized towards the active galactic nucleus. We find high (∼1.7) CN (1–0)/HCN (1–0) intensity ratios in IRAS 13120-5453 and in the northern nucleus of NGC 3256, compared to a more constant ratio (∼1.1) in NGC 7469 and non-starbursting regions of NGC 3256. [ABSTRACT FROM AUTHOR]

The aim of this work is to study structure and gas kinematics in the photodissociation regions (PDRs) around the compact H  ii regions S235 A and S235 C. We observe the [C  ii ], [13C  ii ], and [O  i ] line emission, using SOFIA/upGREAT, and complement them by data of HCO+ and CO. We use the [13C  ii ] line to measure the optical depth of the [C  ii ] emission, and find that the [C  ii ] line profiles are influenced by self-absorption, while the [13C  ii ] line remains unaffected by these effects. Hence, for dense PDRs, [13C  ii ] emission is a better tracer of gas kinematics. The optical depth of the [C  ii ] line is up to 10 in S235 A. We find an expanding motion of the [C  ii ]-emitting layer of the PDRs into the front molecular layer in both regions. Comparison of the gas and dust columns shows that gas components visible neither in the [C  ii ] nor in low- J CO lines may contribute to the total column across S235 A. We test whether the observed properties of the PDRs match the predictions of spherical models of expanding H  ii region + PDR + molecular cloud. Integrated intensities of the [13C  ii ], [C  ii ], and [O  i ] lines are well represented by the model, but the models do not reproduce the double-peaked [C  ii ] line profiles due to an insufficient column density of C+. The model predicts that the [O  i ] line could be a more reliable tracer of gas kinematics, but the foreground self-absorbing material does not allow using it in the considered regions. [ABSTRACT FROM AUTHOR]

We derive molecular-gas-phase 12C/13C isotope ratios for the central few hundred parsecs of the three nearby starburst galaxies NGC 253, NGC 1068, and NGC 4945 making use of the λ ∼ 3 mm 12CN and 13CN N = 1–0 lines in the ALMA Band 3. The 12C/13C isotopic ratios derived from the ratios of these lines range from 30 to 67 with an average of 41.6 ± 0.2 in NGC 253, from 24 to 62 with an average of 38.3 ± 0.4 in NGC 1068, and from 6 to 44 with an average of 16.9 ± 0.3 in NGC 4945. The highest 12C/13C isotopic ratios are determined in some of the outskirts of the nuclear regions of the three starburst galaxies. The lowest ratios are associated with the northeastern and southwestern molecular peaks of NGC 253, the northeastern and southwestern edge of the mapped region in NGC 1068, and the very center of NGC 4945. In the case of NGC 1068, the measured ratios suggest inflow from the outer part of NGC 1068 into the circum-nuclear disk through both the halo and the bar. Low 12C/13C isotopic ratios in the central regions of these starburst galaxies indicate the presence of highly processed material. [ABSTRACT FROM AUTHOR]

Context. Understanding the nuclear growth and feedback processes in galaxies requires investigating their often obscured central regions. One way to do this is to use (sub)millimeter line emission from vibrationally excited HCN (HCN-vib), which is thought to trace warm and highly enshrouded galaxy nuclei. It has been suggested that the most intense HCN-vib emission from a galaxy is connected to a phase of nuclear growth that occurs before the nuclear feedback processes have been fully developed. Aims. We aim to investigate if there is a connection between the presence of strong HCN-vib emission and the development of feedback in (ultra)luminous infrared galaxies ((U)LIRGs). Methods. We collected literature and archival data to compare the luminosities of rotational lines of HCN-vib, normalized to the total infrared luminosity, to the median velocities of 119 μm OH absorption lines, potentially indicating outflows, in a total of 17 (U)LIRGs. Results. The most HCN-vib luminous systems all lack signatures of significant molecular outflows in the far-infrared OH absorption lines. However, at least some of the systems with bright HCN-vib emission have fast and collimated outflows that can be seen in spectral lines at longer wavelengths, including in millimeter emission lines of CO and HCN (in its vibrational ground state) and in radio absorption lines of OH. Conclusions. We conclude that the galaxy nuclei with the highest LHCN − vib/LIR do not drive wide-angle outflows that are detectable using the median velocities of far-infrared OH absorption lines. This is possibly because of an orientation effect in which sources oriented in such a way that their outflows are not along our line of sight also radiate a smaller proportion of their infrared luminosity in our direction. It could also be that massive wide-angle outflows destroy the deeply embedded regions responsible for bright HCN-vib emission, so that the two phenomena cannot coexist. This would strengthen the idea that vibrationally excited HCN traces a heavily obscured stage of evolution before nuclear feedback mechanisms are fully developed. [ABSTRACT FROM AUTHOR]

We report the first detection in the interstellar medium (ISM) of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Centre quiescent molecular cloud G + 0.693. The Z-isomer has a column density of (2.0 ± 0.6) × 1014 cm−2 and an abundance of 1.5 × 10−9. The relative abundance ratio between the isomers is [Z/E]∼6. This value cannot be explained by the two chemical formation routes previously proposed (gas phase and grain surface), which predicts abundances ratios between 0.9 and 1.5. The observed [Z/E] ratio is in good agreement with thermodynamic equilibrium at the gas kinetic temperature (130−210 K). Since isomerization is not possible in the ISM, the two species may be formed at high temperature. New chemical models, including surface chemistry on dust grains and gas-phase reactions, should be explored to explain our findings. Whatever the formation mechanism, the high abundance of Z-HNCHCN shows that precursors of adenine are efficiently formed in the ISM. [ABSTRACT FROM AUTHOR]

Aiming to characterise the properties of the molecular gas in the ultra-luminous infrared galaxy Mrk 273 and its outflow, we used the NOEMA interferometer to image the dense-gas molecular tracers HCN, HCO+, HNC, HOC+ and HC3N at ∼86 GHz and ∼256 GHz with angular resolutions of 4ʺ̣9 × 4ʺ̣5 (∼3.7 × 3.4 kpc) and 0ʺ̣61 × 0ʺ̣55 (∼460 × 420 pc). We also modelled the flux of several H2O lines observed with Herschel using a radiative transfer code that includes excitation by collisions and far-infrared photons. The disc of the Mrk 273 north nucleus has two components with decoupled kinematics. The gas in the outer parts (R ∼ 1.5 kpc) rotates with a south-east to north-west direction, while in the inner disc (R ∼ 300 pc) follows a north-east to south-west rotation. The central 300 pc, which hosts a compact starburst region, is filled with dense and warm gas, and contains a dynamical mass of (4 −5) × 109 M⊙, a luminosity of L′HCN = (3–4) × 108 K km s−1 pc2, and a dust temperature of 55 K. At the very centre, a compact core with R ∼ 50 pc has a luminosity of LIR = 4 × 1011 L⊙ (30% of the total infrared luminosity), and a dust temperature of 95 K. The core is expanding at low velocities ∼50–100 km s−1, probably affected by the outflowing gas. We detect the blue-shifted component of the outflow, while the red-shifted counterpart remains undetected in our data. Its cold and dense phase reaches fast velocities up to ∼1000 km s−1, while the warm outflowing gas has more moderate maximum velocities of ∼600 km s−1. The outflow is compact, being detected as far as 460 pc from the centre in the northern direction, and has a mass of dense gas ≤8 × 108 M⊙. The difference between the position angles of the inner disc (∼70°) and the outflow (∼10°) indicates that the outflow is likely powered by the AGN, and not by the starburst. Regarding the chemistry in Mrk 273, we measure an extremely low HCO+/HOC+ ratio of 10 ± 5 in the inner disc of Mrk 273. [ABSTRACT FROM AUTHOR]

We present an unbiased spectral line survey towards the Galactic Centre (GC) quiescent giant molecular cloud, G+0.693 using the GBT and IRAM 30  telescopes. Our study highlights an extremely rich organic inventory of abundant amount of nitrogen (N)-bearing species in a source without signatures of star formation. We report the detection of 17 N-bearing species in this source, of which eight are complex organic molecules. A comparison of the derived abundances relative to H2 is made across various Galactic and extragalactic environments. We conclude that the unique chemistry in this source is likely to be dominated by low-velocity shocks with X-rays/cosmic rays also playing an important role in the chemistry. Like previous findings obtained for O-bearing molecules, our results for N-bearing species suggest a more efficient hydrogenation of these species on dust grains in G+0.693 than in hot cores in the Galactic disc, as a consequence of the low-dust temperatures coupled with energetic processing by X-ray/cosmic ray radiation in the GC. [ABSTRACT FROM AUTHOR]

NGC 4945 is one of the nearest (D ≈ 3.8 Mpc; 1″ ≈ 19 pc) starburst galaxies. To investigate the structure, dynamics, and composition of the dense nuclear gas of this galaxy, ALMA band 3 (λ ≈ 3−4 mm) observations were carried out with ≈2″ resolution. Three HCN and two HCO+ isotopologues, CS, C3H2, SiO, HCO, and CH3C2H were measured. Spectral line imaging demonstrates the presence of a rotating nuclear disk of projected size 10″ × 2″ reaching out to a galactocentric radius of r ≈ 100 pc with position angle PA = 45° ± 2°, inclination i = 75° ± 2° and an unresolved bright central core of size ≲2″. The continuum source, representing mostly free-free radiation from star forming regions, is more compact than the nuclear disk by a linear factor of two but shows the same position angle and is centered 0.′′39 ± 0.′′14 northeast of the nuclear accretion disk defined by H2O maser emission. Near the systemic velocity but outside the nuclear disk, both HCN J = 1 → 0 and CS J = 2 → 1 delineate molecular arms of length ≳15″ (≳285 pc) on opposite sides of the dynamical center. These are connected by a (deprojected) ≈ 0.6 kpc sized molecular bridge, likely a dense gaseous bar seen almost ends-on, shifting gas from the front and back side into the nuclear disk. Modeling this nuclear disk located farther inside (r ≲100 pc) with tilted rings provides a good fit by inferring a coplanar outflow reaching a characteristic deprojected velocity of ≈50 km s−1. All our molecular lines, with the notable exception of CH3 C2H, show significant absorption near the systemic velocity (≈571 km s−1), within the range ≈500–660 km s−1. Apparently, only molecular transitions with low critical H2 density (ncrit ≲ 104 cm−3) do not show absorption. The velocity field of the nuclear disk, derived from CH3 C2H, provides evidence for rigid rotation in the inner few arcseconds and a dynamical mass of Mtot = (2.1 ± 0.2) × 108 M⊙ inside a galactocentric radius of 2.′′45 (≈45 pc), with a significantly flattened rotation curve farther out. Velocity integrated line intensity maps with most pronounced absorption show molecular peak positions up to ≈1.′′5 (≈30 pc) southwest of the continuum peak, presumably due to absorption, which appears to be most severe slightly northeast of the nuclear maser disk. A nitrogen isotope ratio of 14N/15N ≈ 200–450 is estimated. This range of values is much higher then previously reported on a tentative basis. Therefore, because 15N is less abundant than expected, the question for strong 15N enrichment by massive star ejecta in starbursts still remains to be settled. [ABSTRACT FROM AUTHOR]

Aims. We aim to better understand the imprints that the nuclear activity in galaxies leaves in the molecular gas. Methods. We used the IRAM 30m telescope to observe the frequency range ∼[86-116] GHz towards the central regions of the starburst galaxies M83, M82, and NGC253, the galaxies hosting an active galactic nucleus (AGN) M51, NGC1068, and NGC7469, and the ultra-luminous infrared galaxies (ULIRGs) Arp 220 and Mrk 231. Assuming local thermodynamic equilibrium (LTE), we calculated the column densities of 27 molecules and 10 isotopologues (or their upper limits in case of non-detections). Results. Among others, we report the first tentative detections of CH3CHO, HNCO, and NS in M82 and, for the first time in the extragalactic medium, HC5N in NGC253. Hα recombination lines were only found in M82 and NGC253. Vibrationally excited lines of HC3N were only detected in Arp 220. CH3CCH emission is only seen in the starburst-dominated galaxies. By comparison of the fractional abundances among the galaxies, we looked for the molecules that are best suited to characterise the chemistry of each group of galaxies (starbursts, AGNs and ULIRGs), as well as the differences among galaxies within the same group. Conclusions. Suitable species for characterising and comparing starburst galaxies are CH3OH and HNCO as tracers of large-scale shocks, which dominate early to intermediate starburst stages, and CH3CCH, c-C3H2, and HCO as tracers of UV fields, which control the intermediate-to-old or post starburst phases. M83 shows signs of a shock-dominated environment. NGC253 is characterised by both strong shocks and some UV fields. M82 stands out for its bright photo-dissociated region tracers, which indicate an UV fielddominated environment. Regarding AGNs, the abundances of HCN and CN (previously claimed as enhanced in AGNs) in M51 are similar to those in starburst galaxies, while the HCN/HCO+ ratio is high in M51 and NGC1068, but not in NGC7469.We did not find a correlation between the HCN/CS ratio (recently claimed as a possible starburst/AGN discriminator) and the AGN activity. However, a high enough spatial resolution to separate their circumnuclear disks from the surrounding star-forming regions is needed to find molecular abundance trends in AGNs. High abundances of H13CN and HC3N, as well as a similarity between the column densities of 13CO and C18O, are representative of the molecular interstellar medium in the ULIRGs. Furthermore, the chemistry of Arp 220 points towards a more starburst-dominated environment, while that of Mrk 231 more resembles the AGNs of our sample. [ABSTRACT FROM AUTHOR]

Aims. We observe the dense gas tracer CS in two nearby starburst galaxies to determine how the conditions of the dense gas varies across the circumnuclear regions in starburst galaxies. Methods. Using the IRAM-30m telescope, we mapped the distribution of the CS(2-1) and CS(3-2) lines in the circumnuclear regions of the nearby starburst galaxies NGC3079 and NGC6946. We also detected formaldehyde (H2CO) and methanol (CH3OH) in both galaxies. We marginally detect the isotopologue C34S. Results. We calculate column densities under LTE conditions for CS and CH3OH. Using the detections accumulated here to guide our inputs, we link a time and depth dependent chemical model with a molecular line radiative transfer model; we reproduce the observations, showing how conditions where CS is present are likely to vary away from the galactic centres. Conclusions. Using the rotational diagram method for CH3OH, we obtain a lower limit temperature of 14 K. In addition to this, by comparing the chemical and radiative transfer models to observations, we determine the properties of the dense gas as traced by CS (and CH3OH). We also estimate the quantity of the dense gas. We find that, provided there are between 105 and 106 dense cores in our beam, for both target galaxies, emission of CS from warm (T = 100-400 K), dense (n(H2) = 105-6 cm-3) cores, possibly with a high cosmic ray ionisation rate (ζ = 100 ζ0) best describes conditions for our central pointing. In NGC6946, conditions are generally cooler and/or less dense further from the centre, whereas in NGC3079, conditions are more uniform. The inclusion of shocks allows for more effcient CS formation, which means that gas that is less dense by an order of magnitude is required to replicate observations in some cases. [ABSTRACT FROM AUTHOR]

Context. The nearby Sy 1 galaxy NGC 1097 represents an ideal laboratory for exploring the molecular chemistry in the surroundings of an active galactic nucleus (AGN). Aims. Exploring the distribution of different molecular species allows us to understand the physical processes affecting the interstellar medium both in the AGN vicinity and in the outer star forming molecular ring. Methods. We carried out 3 mm ALMA observations that include seven different molecular species, namely HCN, HCO+, CCH, CS, HNCO, SiO, HC3N, and SO, as well as the 13C isotopologues of the first two. Spectra were extracted from selected positions and all species were imaged over the central 2 kpc (~30") of the galaxy at a resolution of ~2.2" × 1.5" (150 pc × 100 pc). Results. HCO+ and CS appear to be slightly enhanced in the star forming ring. CCH shows the largest variations across NGC 1097 and is suggested to be a good tracer of both obscured and early stage star formation. HNCO, SiO, and HC3N are significantly enhanced in the inner circumnuclear disk surrounding the AGN. Conclusions. Differences in the molecular abundances are observed between the star forming ring and the inner circumnuclear disk. We conclude that the HCN/HCO+ and HCN/CS differences observed between AGN-dominated and starburst (SB) galaxies are not due to a HCN enhancement due to X-rays, but rather this enhancement is produced by shocked material at distances of 200 pc from the AGN. Additionally, we claim that lower HCN/CS is a combination of a small underabundance of CS in AGNs, together with excitation effects, where a high density gas component (~106 cm-3) may be more prominent in SB galaxies. However, the most promising are the differences found among the dense gas tracers that, at our modest spatial resolution, seem to outline the physical structure of the molecular disk around the AGN. In this picture, HNCO probes the well-shielded gas in the disk, surrounding the dense material moderately exposed to the X-ray radiation traced by HC3N. Finally SiO might be the innermost molecule in the disk structure. [ABSTRACT FROM AUTHOR]

Carbon and oxygen isotope ratios are excellent measures of nuclear processing, but few such data have been taken toward extragalactic targets so far. Therefore, using the IRAM 30-m telescope, CN and CO isotopologues have been measured toward the nearby starburst galaxy NGC 253 and the prototypical ultraluminous infrared galaxy Mrk 231. Toward the center of NGC 253, the CN and 13CN N = 1 → 0 lines indicate no significant deviations from expected local thermodynamical equilibrium after accounting for moderate saturation effects (10 and 25%) in the two detected spectral components of the main species. Including calibration uncertainties, which dominate the error budget, the 12C/13C ratio becomes 40 ± 10. This is larger than the ratio in the central molecular zone of the Galaxy, suggesting a higher infall rate of poorly processed gas toward the central region. Assuming that the ratio also holds for the CO emitting gas, this yields 16O/18O = 145 ± 36 and 16O/17O = 1290 ± 365 and a 32S/34S ratio close to the one measured for the local interstellar medium (20–25). No indication of vibrationally excited CN is found in the lower frequency fine structure components of the N = 1 → 0 and 2 → 1 transitions at rms noise levels of 3 and 4mK (15 and 20mJy) in 8.5km s−1 wide channels. Peak line intensity ratios between NGC 253 and Mrk 231 are ∼100 for 12C16O and 12C18O J = 1 → 0, while the ratio for 13C16O J = 1 → 0 is ∼250. This and similar 13CO and C18O line intensities in the J = 1 → 0 and 2 → 1 transitions of Mrk 231 suggest 12C/13C ∼ 100 and 16O/18O ∼ 100, in agreement with values obtained for the less evolved ultraluminous merger Arp 220. Also, when accounting for other (scarcely available) extragalactic data, 12C/13C ratios appear to vary over a full order of magnitude, from >100 in ultraluminous high redshift galaxies to ∼100 in more local such galaxies to ∼40 in weaker starbursts that are not undergoing a large scale merger to 25 in the central molecular zone of the Milky Way. With 12C being predominantly synthesized in massive stars, while 13C is mostly ejected by longer lived lower mass stars at later times, this is qualitatively consistent with our results of decreasing carbon isotope ratios with time and rising metallicity. It is emphasized, however, that both infall of poorly processed material, initiating a nuclear starburst, and the ejecta from newly formed massive stars (in particular in the case of a top-heavy stellar initial mass function) can raise the carbon isotope ratio for a limited amount of time. [ABSTRACT FROM AUTHOR]

Context. Multi-molecule observations towards an increasing variety of galaxies have been showing that the relative molecular abundances are affected by the type of activity. However, these studies are biased towards bright active galaxies, which are typically in interaction. Aims. We study the molecular composition of one of the most isolated galaxies in the local Universe where the physical and chemical properties of their molecular clouds have been determined by intrinsic mechanisms. Methods. We present 3 mm broad band observations of the galaxy CIG 638, extracted from the AMIGA sample of isolated galaxies. The emission of the J = 1-0 transitions of CCH, HCN, HCO+, and HNC are detected. Integrated intensity ratios between these line are compared with similar observations from the literature towards active galaxies including starburst galaxies (SB), active galactic nuclei, luminous infrared galaxies (LIRG), and GMCs in M33. Results. A significantly high ratio of CCH with respect to HCN, HCO+, and HNC is found towards CIG 638 when compared with all other galaxies where these species have been detected. This points to either an overabundance of CCH or to a relative lack of dense molecular gas as supported by the low HCN/CO ratio, or both. Conclusions. The data suggest that the CIG 638 is naturally a less perturbed galaxy where a lower fraction of dense molecular gas, as well as a more even distribution could explain the measured ratios. In this scenario the dense gas tracers would be naturally dimmer, while the UV enhanced CCH, would be overproduced in a less shielded medium. [ABSTRACT FROM AUTHOR]

Aims. We study the molecular composition of the interstellar medium (ISM) surrounding an active galactic nucleus (AGN), by making an inventory of molecular species and their abundances, to establish a chemical differentiation between starburst galaxies and AGN. Methods. We used the IRAM-30m telescope to observe the central 1.5-2 kpc region of NGC 1068, covering the frequencies between 86.2 GHz and 115.6 GHz. Using Boltzmann diagrams, we calculated the column densities of the detected molecules. We used a chemical model to reproduce the abundances found in the AGN, to determine the origin of each detected species, and to test the influence of UV fields, cosmic rays, and shocks on the ISM. Results. We identified 24 different molecular species and isotopologues, among which HC3N, SO, N2H+, CH3CN, NS, 13CN, and HN13C are detected for the first time in NGC1068. A comparison of the abundances in the nuclear regions of NGC1068, M82, and NGC253 allowed us to establish a chemical differentiation between starburst galaxies and AGN. Two abundant species in starburst galaxies, H2CO and CH3CCH, are not detected in NGC1068, probably because they are destroyed by UV fields or shocks. On the other hand, species such as CN, SiO, HCO+, and HCN, are enhanced by cosmic ray radiation fields. We obtained the upper limits to the isotopic ratios 12C/13C = 49, 16O/18O = 177, and 32S/34S = 5. These ratios are much lower in this AGN than in starburst galaxies. Our chemical models suggest that the chemistry in the nucleus of NGC1068 is strongly influenced by cosmic rays, although high values of both cosmic rays and far ultraviolet (FUV) radiation fields also explain the observations well. C-shocks can explain the abundances of C2H and H2CO, but do not strongly affect the abundances of the other detected species. Conclusions. The gas in the nucleus of NGC 1068 has a different chemical composition than starburst galaxies. The distinct physical processes dominating galaxy nuclei (e.g. C-shocks, UV fields, X-rays, cosmic rays) leave clear imprints in the chemistry of the gas, which allow the nucleus activity to be characterised by its molecular abundances. [ABSTRACT FROM AUTHOR]

We present a summary of the physical and chemical properties we have obtained for the molecular gas found in galaxies, an essential triggering ingredient to any star formation (SF) process. In particular, we focus our studies on the molecular gas phases as traced by CO, HCO+ and CS line emissions, in a sample of galaxies including starbursts -SBs-, irregulars galaxies, low-metallicity sources, normal spirals, mergers, Early Type Galaxies (ETGs), galaxies with an Active Galactic Nucleus (AGN), with Cosmic Ray Dominated Regions (CRDRs) and with Photo-Dominated Regions (PDRs). Our studies mix theoretical developments (i.e. computational models) with the acquisition of large observational datatsets (at both low and high spatial resolution) that we then compare in order to better determine the conditions under which some SF activity is starting and/or is maintained. [ABSTRACT FROM PUBLISHER]

Using the IRAM 30 m telescope, we perform a molecular line survey of the 3 and 2 mm wavelength ranges towards 5 selected positions in the Galactic center region, sampling shocked regions, ultraviolet (UV) and X-ray pervaded regions, and positions with rich organic chemistry. These surveys have the potential to be used as chemical templates for different types of activity, such as photodissociated regions (PDRs), shocks and X-ray dominated regions (XDRs). Complementary, molecular surveys done towards extragalactic nuclei, that are also dominated by these physical activities, were carried by our group. [ABSTRACT FROM PUBLISHER]

Spectral surveys provide the only way to determine the full molecular inventory of a source and hence to build a comprehensive view of the state of the molecular gas and its role in the star formation process. Systematic studies have opened the possibility of using chemistry as a diagnostic tool for star burst and AGN activities in the highly obscured galactic nuclear regions. [ABSTRACT FROM AUTHOR]

We have derived radial sky-subtracted surface brightness profiles of a sample of 42 face-on nearby early-type spiral galaxies, classified as unbarred, from SDSS data as well as our own observations (INT/WFC) at La Palma. A key objective was to derive the fraction of truncated profiles. We find that only a small minority 7% of the galaxies are obviously truncated within the limits of the measured surface brightness range, while some 20% show exponential disc profiles but with a shallower inner portion near the centre: classical “Freeman Type II” profiles (Freeman, 197). Half of the discs show a single unbroken exponential (“type I”) brightness profile with no evidence of truncation out to the edge of detectability, while the remainder show “antitruncations”: external profiles less steep than those of the internal disc (Type III). A general profile classification scheme based on these and other recent related measurements is presented, and will be of use in probing disc formation scenarios. [ABSTRACT FROM PUBLISHER]