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This study delves into the investigation of Maxwell fluid flow across a sheet with a particular effort on the melting heat and zero mass flux at the boundary. A Maxwell fluid, characterized by both viscous and elastic responses, plays a pivotal role in various industrial and biological applications. The mathematical model describing Maxwell fluid flow is represented using non-linear momentum and energy equations, incorporating MHD. Similarity transformation is used to change from partial differential equation to ordinary differential equation. The introduction of a phase change term in the energy equation accounts for the melting heat effect at the boundary. The BVP4C solver using MATLAB is hired to numerically answer the system of equations, enabling the determination of the steady-state solution. The solution of this investigation offers valuable insights into the interplay between viscoelasticity and melting heat effects on various flow characteristics, including velocity and temperature profiles. The practical significance of this research is evident in polymer processing, food processing, and materials engineering, where the understanding of Maxwell fluids and their interaction with melting boundaries is essential for process optimization and product quality. So far in the literature survey no one have considered Melting heat effect along with Maxwell fluid. The conclusion for this study is that Melting heat effect increases velocity profile and decreases the temperature profile. This is the main conclusion of this research.

Luminescent lanthanum oxyfluoride nano inorganic materials were considered to be prospective building blocks for multifunctional applications. This offers new potentials in surface-based science comprising of visualization of latent fingerprint (LFPs) and lips print on non-porous surfaces. Traditional visualization techniques possess high backward hindrance, low sensitivity, complicated setup and poor visibility. To overcome with these problems, LaOF:Sm3+ (5 mol%) nanopowder (NPs) prepared via sonochemical route were explored. Photoluminescence (PL) emission spectra exhibit strong emission peaks at ∼566 nm, 607 nm, 653 nm and 708 nm attributed to 4G5/2 → 6H5/2, 4G5/2 → 4H7/2, 4G5/2 → 6H9/2 and 4G5/2 → 6H11/2 intra-4f orbital transitions of Sm3+ ions respectively. Estimated photometric properties confirm that the material emits warm orange red color. Therefore, the synthesized phosphor materials may quite be useful for LFPs recovery, cheiloscopy and optoelectronics applications. Keywords: Ultrasonication, Photoluminescence, Forensic, Cheiloscopy, Solid state lighting

Since fungal infections are on the rise and with limited treatment options, there is a need to modify existing drugs either by making structural changes or making use of better drug delivery systems. Aureofungin, an antibiotic of a polyene class, is primarily used to prevent fungal infection in agriculture. However, it has limited application in clinical therapy due to high toxicity. Therefore, a water-soluble sodium salt derivative of aureofungin was synthesized as a promising antifungal agent, which required a bioanalytical method to be established for the quantitation in the biological matrix and thereby understanding its pharmacokinetics. As a result, in the present work, a simple and rapid reversed-phase high-performance liquid chromatography method was developed for the determination of aureofungin bulk and its water-soluble derivative in rat plasma. The analytes were separated in an isocratic mode using a C18 amide column (250 x 4.6 mm, 5 [micro]m) and a mobile phase of 10 mM ammonium acetate (pH 4.0) and acetonitrile (55 : 45, v/v) with a flow rate of 1.0 mL/min at ambient temperature and detection at 378 nm. The analyte was efficiently extracted using a simple protein precipitation technique. The methodology was found to be linear (r.sup.2 [greater than or equal to] 0.995), selective, repeatable (CV [less than or equal to] 15.0%), accurate (100 ± 15%), and free of any carryover effects. Under the investigated storage conditions, the bioanalytical samples demonstrated acceptable stability. An oral pharmacokinetic study in rats was then performed to verify the applicability of the method., Author(s): Sandeep Sankaran [sup.1] , Raj Soni [sup.2] , Sahebrao More [sup.3] , Arulmozhi Sathiyanarayanan [sup.2] , Mahesh Ghaisas [sup.2] , Suhas Mohite [sup.4] , Sathiyanarayanan Lohidasan [sup.5] Author Affiliations: [...]

The titled compound TA structure was optimized in B3LYP/cc-pVDZ basis set using Gaussian software. In natural bond orbital analysis the highest stabilization energy is 82.3 kcal/mol, which is confirmed by LP(1)-C19 to antibonding π*(C13-C14). Electron localization and delocalization areas are confirmed by wavefunction studies. The Gaussian-16w software establishes thermodynamic properties for a titled compound which is confirmed by various solvents. The HOMO and LUMO analysis ethanol have the highest energy gap value, which is 5.88 eV. In molecular electrostatic potential study nitrogen is the nucleophilic attack (blue color) and oxygen is the electrophilic attack (red color). In non-linear optical (NLO) study water solvent shows the highest dipole moment activity. The docking study showed the greatest binding affinity score of −4.08 kcal/mol.

The absorption studies on serotonin (STO) and platinum metal clusters were investigated. The STO-Pt3 (gas phase) cluster has the maximum adsorption energy, whereas the water medium has the lowest. The gas phase STO-Pt3 absorption energy is -19.18 kcal/mol, while the water solvent is -11.03. The electrophilicity index of all metal-drug systems is greater, indicating that metal clusters make the serotonin more electrophilic. The cluster's conductivity representation as energy gaps pointed, suggesting it could be a sensor. A more stable gas phase medium has more negative solvation energies than other media types. The metal clusters and molecules interacted substantially in non-covalent interaction studies. Electron localized function (ELF) and localized orbital locator (LOL) experiments proved electron delocalization energies and reduced density gradient (RDG) confirmed non-covalent interactions. Molecular electrostatic potential shows the electrophilic and nucleophilic attractions of STO with Pt3 metal clusters. Frontier molecular orbital (FMO) studies show very low energy gap values.