1. Sulfur isotopic compositions of sulfides along the Southwest Indian Ridge: implications for mineralization in ultramafic rocks.
- Author
-
Ding, Teng, Tao, Chunhui, Dias, Ágata Alveirinho, Liang, Jin, Chen, Jie, Wu, Bin, Ma, Dongsheng, Zhang, Rongqing, Wang, Jia, Liao, Shili, Wang, Yuan, Yang, Weifang, Liu, Jia, Li, Wei, Zhang, Guoyin, and Huang, Hui
- Subjects
ULTRABASIC rocks ,SULFIDE minerals ,SULFIDES ,PYRITES ,SULFUR ,PYRRHOTITE ,MINERALIZATION - Abstract
The recently explored Tianzuo hydrothermal field in serpentinized ultramafic rocks of the amagmatic segment of the ultraslow-spreading Southwest Indian Ridge displays high-temperature sulfide mineralization (isocubanite, sphalerite, and minor pyrrhotite) and low-temperature (pyrite and covellite) phases. Pyrite can be subdivided into pyrite-I and -II, with the former generally having a pseudomorphic texture after pyrrhotite and the latter typically growing around isocubanite, sphalerite, and pyrite-I or occurring as individual grains in quartz veinlets. The sulfide minerals have the greatest range of δ
34 S values (− 23.8 to 14.1‰), found so far among modern sediment-starved ridges, with distinct δ34 S values for low- and high-temperature mineral phases. The high δ34 S values of isocubanite (9.6 to 12.2‰) and sphalerite (9.1 to 14.1‰) suggest that sulfate, which precipitated from seawater during an early low-temperature phase of hydrothermal circulation, was the main sulfur source for these sulfides. Pyrite-II has the lowest and most variable δ34 S values (− 23.8 to − 3.6‰), suggesting microbial sulfate reduction. Pyrite-I has variable and generally positive δ34 S values (− 0.1 to 12.0‰), with sulfur being inherited from pyrrhotite from the original thermochemical reduction of sulfate, mixed with volcanogenic sulfur. Intermittent magmatism represented by gabbroic intrusions, and high permeability caused by well-developed fractures associated with detachment faults, contributed to the formation of sulfides in the Tianzuo hydrothermal field. These factors possibly control sulfide mineralization in amagmatic segments of ultraslow-spreading ridges. [ABSTRACT FROM AUTHOR]- Published
- 2021
- Full Text
- View/download PDF