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In this study, a series of conductive composite wires were successfully prepared by combining dispersions of multi-wall carbon nanotubes (MWCNTs) and TEMPO-oxidized cellulose nanofibers (TOCNFs) with different MWCNTs contents into a dispersion of partially deacetylated α-chitin nanofibers (α-DECHNs) followed with a drying process. The TOCNFs/MWCNTs/α-DECHNs composite wires were prepared by extruding the negatively charged TOCNFs/MWCNTs dispersion into the positively charged α-DECHNs dispersion. The contact of the positively charged α-DECHNs and the negatively charged TOCNFs/MWCNTs triggers the electrostatic interaction (heterocoagulation) resulting in wire-shaped conductive composites. The SEM analysis indicates this conductive composite material has a wire-like shape with a rough but tight surface. The properties of samples were characterized by a zeta potential analyzer (Zetasizer Nano), a four-probe, an electrochemical workstation, a Fourier transform infrared spectroscopy (FTIR), an X-ray diffractometer (XRD), and a thermogravimetric analyzer (TG). Besides, the conductivity and the AC impedance of TOCNFs/MWCNTs/α-DECHNs composite wires with different MWCNTs contents were also analyzed. The conductivity of the composite wire increases from 9.98 × 10 - 6  S∙cm - 1 to 1.56 × 10 - 3  S∙cm - 1 as the MWCNTs content raises from 3.0 wt% to 14.0 wt%. When the MWCNTs content reaches 14.0 wt%, the prepared composite wire can light up LED at a voltage of 5 V, indicating the great potential of this biomass-based conductive composite in conductive material application., (Copyright © 2019 Elsevier B.V. All rights reserved.)

In this work, lignin fractionation is proposed as an effective approach to reduce the heterogeneity of lignin and improve the adsorption and recycle performances of lignin as a cationic dye adsorbent. By stepwise dissolution of enzymatic hydrolysis lignin in 95% and 80% ethanol solutions, three lignin subdivisions (95% ethanol-soluble subdivision, 80% ethanol-soluble subdivision, and 80% ethanol-insoluble subdivision) were obtained. The three lignin subdivisions were characterized by gel permeation chromatography (GPC), FTIR, 2D-NMR and scanning electron microscopy (SEM), and their adsorption capacities for methylene blue were compared. The results showed that the 80% ethanol-insoluble subdivision exhibited the highest adsorption capacity and its value (396.85 mg/g) was over 0.4 times higher than that of the unfractionated lignin (281.54 mg/g). The increased adsorption capacity was caused by the enhancement of both specific surface area and negative Zeta potential. The maximum monolayer adsorption capacity of 80% ethanol-insoluble subdivision by adsorption kinetics and isotherm studies was found to be 431.1 mg/g, which was much higher than most of reported lignin-based adsorbents. Moreover, the 80% ethanol-insoluble subdivision had much higher regeneration yield (over 90% after 5 recycles) compared with the other two subdivisions. Consequently, the proposed fractionation method is proved to be a novel and efficient non-chemical modification approach that significantly improves adsorption capacity and recyclability of lignin.

The presence of dyes in wastewater effluents made from the textile industry is a major environmental problem due to their complex structure and poor biodegradability. In this study, a cationic lignin polymer was synthesized via the free radical polymerization of lignin with [2-(methacryloyloxy) ethyl] trimethyl ammonium chloride (METAC) and used to remove anionic azo-dyes (reactive black 5, RB5, and reactive orange 16, RO16) from simulated wastewater. The effects of pH, salt, and concentration of dyes, as well as the charge density and molecular weight of lignin-METAC polymer on dye removal were examined. Results demonstrated that lignin-METAC was an effective flocculant for the removal of dye via charge neutralization and bridging mechanisms. The dye removal efficiency of lignin-METAC polymer was independent of pH. The dosage of the lignin polymer required for reaching the maximum removal had a linear relationship with the dye concentration. The presence of inorganic salts including NaCl, NaNO₃, and Na₂SO₄ had a marginal effect on the dye removal. Under the optimized conditions, greater than 98% of RB5 and 94% of RO16 were removed at lignin-METAC concentrations of 120 mg/L and 105 mg/L in the dye solutions, respectively.

A novel multivalent cations-triggered shape memory hydrogels were synthesized in a one-pot method, and interpenetrating double network was formed by chemically cross-linked polyacrylamide (PAM) network and physically cross-linked sodium carboxymethyl cellulose network. The temporary shape was fixed by complexation between a native biopolymer, sodium carboxymethyl cellulose (CMC), and transition metal ions, specifically Fe 3+ , Ag + , Al 3+ , Cu 2+ , Ni 2+ , and Mg 2+ . In particular, CMC-Fe 3+ hydrogel exhibits excellent shape fixity ratio (95%). Therefore, we chose PAM/CMC 1.0 -Fe 3+ hydrogel as the model material and further investigated its shape recovery process. It was found that a wide range of molecules and anions could be applied to break off the temporary cross-links between CMC and Fe 3+ . The PAM/CMC composite hydrogels also exhibited excellent tunable mechanical properties. The mechanical properties of the composite hydrogel can be adjusted by changing the cross-linking densities. The presented strategy could enrich the construction as well as application of biopolymers based shape memory hydrogels., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

Added Al2SO4 greatly accelerates the hydrolysis at 150.0 degrees C of 1,5-anhydrocellobiitol, a model for the beta(1 --> 4) linkages in cellulose, in succinate buffers of room temperature pH 3.05 and 3.35; E(a) values for 20 mM Al(III)- and H+-catalysed hydrolyses are 109 +/- 3 and 140 +/- 1 kJ mol(-1), respectively.