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Abstract: The Guangou bauxite deposit in western Henan, China, is located in the North China Block and to the north of the North Qinling orogenic belt. The orebody is hosted within the lower member of the Carboniferous Benxi Formation, which overlies unconformably upon the Ordovician Majiagou Formation. In the lower member of the Benxi Formation, the bauxite orebody (with a diaspore–illite–anatase mineral assemblage) is sandwiched between underlying ferric clay (illite–hematite–goethite) and overlying top clay (kaolinite–quartz–goethite). According to field observations and geochemical evidence including trace- and rare-earth-element (REE) compositions, especially Zr/Hf ratios, the ferric clays were weathered from the underlying argillaceous limestones in the Majiagou Formation. During this weathering process, trace elements S, Zn, Ni, Cr, V, Sc, F, Ba, and Be are depleted; Li, Rb, and B are enriched; and Zr, Hf, Bi, Ta, Ga, Nb, and Th are relatively immobile. REEs exhibit evident differentiation with enrichment of La, Ce, Pr, and Nd and depletion of Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. The bauxite formed in weak reducing, slightly basic water conditions according to the geneses of coexisting diaspore and anatase, and it was altered during the epigenetic and second exposure periods, forming kaolinite and goethite, respectively. Interelemental relationship analyses of the ores suggest that the elemental behaviors of trace elements and REEs in the bauxitization process are mainly controlled by the mineral compositions in bauxite ore and chemical properties of the elements. For instance, zircon, rutile, and anatase contain Zr, Hf, Nb, Ta, W, and U. Based on geochemical evidence, together with age data and chemical compositions of the detrital minerals, both distant igneous rocks in the plate margin and Paleozoic carbonates and Precambrian rocks inside North China Block provide the miscellaneous material for the bauxite ore and the top clay. [Copyright &y& Elsevier]

Late Carboniferous bauxite is widely developed on the North China Craton (NCC), and is referred to as the "G" layer bauxite. The bauxite ores of the southern NCC are closely related to the tectonic evolution of the NCC and its neighboring North Qinling Belt (NQB) to the south. In this study, based on the geological and mineralogical observations, we used the U–Pb and Hf isotopes of detrital zircons and chemical compositions of detrital rutiles from the Gunziying and Shibanhe bauxite deposits, along the southern margin of the NCC to study the metallogenic process of bauxite ores and their tectonic implications. One and two bauxite ore layers were observed in the Gunziying and Shibanhe bauixte deposits, respectively. The bauxite ore is dominated by diaspore, illite, anatase, kaolinite, pyrite, zircon, and rutile. Analyses of detrital zircons revealed that the largest group (∼432–515 Ma, at a peak age of ∼450 Ma) is spread throughout the Late Carboniferous bauxite deposits, with εHf(t) values of −5.7–21.4, similar to the zircons from the NQB. Similarly, the detrital zircons with peak ages of ∼950 Ma and age clusters at ∼1.1 Ga, ∼1.3 Ga, and ∼1.8 Ga as well as those ranging in age from 635 to 797 Ma, also exhibited εHf(t) values similar to the zircons from the NQB. In addition, the results suggested that 62 (73%) and 75 (88.2%) of detrital rutiles showed metapelitic protoliths and amphibolite/eclogite facies temperatures, respectively, while 23 (27%) and 10 (11.8%) exhibited metamafic protoliths and granulite facies temperatures, respectively. Based on the results above, we propose that the provenance of the bauxite ores on the southern margin of the NCC is primarily from the NQB. The dominant contributors were the Neoproterozoic Kuanping Group and the Meso–Neoproterozoic Qinling Group. The Archean-Proterozoic metamorphic rocks in the paleo-uplifts of the NCC were also likely involved in the bauxite formation. A probable outline of the bauxite-formation process on the southern NCC, former weathered residuals and subsequent deposition, is proposed; and a reasonable interpretation that the NQB was accreted to the NCC in the Late Carboniferous and formed a northward lying slope basin within the NCC, is supported. Image 1 • New constraints on the source of the NCC bauxite ores are proposed. • Mainly material transport from the North Qinling and Kuanping Group. • Bauxitic formation most likely weathered residuals and deposited. • Late Paleozoic Tectonics resulted in the "G" bauxites throughout the NCC. [ABSTRACT FROM AUTHOR]