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The biological removal of a mixture of soil contaminants, namely, hydrocarbons, is not equally efficient for each compound. Some pollutants can be metabolized by the microbial consortium but also generated again as by-products from the removal of others. At the end of the runs, notwithstanding the high integral removal, single compounds can still be present with a relevant concentration. This paper presents the results achieved in a study of the aerobic degradation of diesel oil in three mesocosms carried out for several months with the same operative conditions. They differed in biological management: Natural Attenuation (NA), Biostimulated without inoculation (BS), and Biostimulated with Inoculation (BS + IN). At the end of the runs, the pollution removal was calculated by measuring the residual diesel oil, both as an average in the total amount of soil and only at the bottom of each column. The overall removal was around 2%, 66%, and 72% for NA, BS and BS + IN, reduced to 0%, 48%, and 47%, respectively, if measured only at the bottom. For the biostimulated mesocosms, the speciation of the hydrocarbons was carried out to assess their concentration. The findings evidence the need to delve deeper into this issue and assess the speciation of contaminants. [ABSTRACT FROM AUTHOR]

Abstract This paper presents the effect of environmentally friendly additives on selected parameters and microbial degradation of Marine Diesel Oil (MDO). Microbiological contamination is a serious problem in MDO and other petroleum products. For this reason, it was decided to investigate the effects of environmentally friendly additives such as silver solution and colloidal nanosilver, as well as effective liquid microorganisms and ceramic tubes with different percentages of them in diesel oil (MDO) on its selected parameters and inhibition of bacterial and fungal growth. The tests were conducted on a mixture of fuel with four types of environmentally friendly additives at concentrations of 2% and 5%, and on fuel without any additives. The effect of the additives on selected diesel parameters, including flash point, water content and acid number, as well as density and kinematic viscosity, is presented. The diesel oil was also subjected to microbiological tests. It was found that the most beneficial additive that positively influenced diesel parameters and microbial degradation was a silver solution at a concentration of 2%. The lowest ignition temperature was obtained when ionic silver was used, i.e. 60 °C, which is closest to the value for pure diesel fuel. The addition of effective microorganisms in liquid form to the fuel in an amount of 2%, increases the ignition temperature to 62.2 °C and this is the highest value obtained in comparison with other additives. The lowest water content in the test samples was obtained for the effective microorganisms in ceramic form at − 0.0068%, while the highest value was obtained for the silver solution at 0.0123%. At 100 °C, the highest kinematic viscosity was obtained for EM in ceramic, at 1.11 mm2/s. While for pure oil it was 1.03 mm2/s. For pure diesel, a value of 1.1 × 106 cfu/1 dm3 for bacteria and 7.3 × 103 cfu/1 dm3 was obtained. For each type of mixture, a value of less than 1 × 102 cfu/1 dm3 for bacteria was obtained, while in terms of fungal counts in the mixtures, a decrease of 73 times is also observed for diesel mixed with effective microorganisms in liquid form and ceramics, 48 times less was recorded after the use of non-ionic silver. The use of these additives is an innovative solution that has a positive effect on slowing down microbial degradation, without any loss of diesel performance.

This paper presents the development of the transport industry and indicates its leading role in the economic development of the country and the world. The paper analyzes the structure of the transport market in Poland and Europe, indicating its dynamic development despite the existing challenges related to fuel prices. The main objective is to assess fuel price fluctuations in the context of the activities of transport companies, in particular those performing land transport within the European Union. The assessment is conducted from the perspective of the operational activities of transport companies. This research aimed to identify the impact of fuel prices on companies' operating costs, analyze the economic factors influencing fuel prices, and assess the general situation in the transport market. In addition, the research also examined the opinions of entrepreneurs on how they cope with the current fuel crisis. Achieving the research goal required the preparation and administration of surveys among representatives of transport companies. The study involved 71 companies registered in Poland. The paper contains selected statistical data along with their interpretation, providing an introduction to further research in the field of identification and assessment of the degree of impact of fuel price fluctuations on the operational activities of transport companies. The research methodology focused on statistical analysis using the Pearson correlation coefficient and one-way ANOVA. This paper fills a gap in the literature on the impact of fuel price fluctuations on the activities of sports enterprises. The innovative element of the paper is the inclusion of entrepreneurs' opinions on the fuel crisis and their assessment of the degree of impact of changes on the operating costs and strategic management of transport enterprises. Considering these opinions provides the unique value of the conducted scientific considerations. [ABSTRACT FROM AUTHOR]

Experience shows that dilution of lubricating oil with diesel oil is unfavorable to the engine, causing issues including deterioration of engine performance, shortening of oil life, and reduction in engine reliability and safety. This paper presents the verification of the hypothesis that the changes in lubricity, friction coefficient, and decreasing oil film thickness (using a relative approach, given as a percentage) are similar for lubricating oil and diesel mixtures prepared from fresh lubricating oil and used lubricating oil. To validate this hypothesis, an experiment is conducted using a high-frequency reciprocating rig (HFFR), in which the lubricity is determined by the corrected average wear scar WS1.4, the coefficient of friction μ, and the percentage relative decrease in oil film thickness r. A qualitative visual assessment of the wear scars on the test specimens is also performed after the HFFR tests. The testing covers mixtures of SAE 30 grade Marinol CB-30 RG1230 lubricating oil with Orlen Efecta Diesel Biodiesel. The used lubricating oil is extracted from the circulating lubrication system of a supercharged, trunk-piston, four-stroke ZUT Zgoda Sulzer 5 BAH 22 engine installed in the laboratory of ship power plants of the Maritime University of Szczecin. Mixtures for the experiment are prepared for fresh lubricating oil with diesel oil and used lubricating oil with diesel oil. Mixtures of these lubricating oils with diesel oil are examined for diesel oil concentrations in the mixture equal to 1, 2, 5, 10, 15, and 20% m/m. The results of the experiment confirm the hypothesis, proving that, for up to 20% m/m diesel oil concentration in lubricating oil, the changes in the lubricity of used lubricating oil diluted with diesel oil can be evaluated based on reference data prepared for mixtures of diesel oil with fresh lubricating oil. The linear approximation of μ and r trends is made with a certain margin of error we estimated. The experiment also confirms the results of previous studies which state that oil aging products in small quantities contribute to improved lubricity. [ABSTRACT FROM AUTHOR]

This article presents the verification of the hypothesis on using certain approximation curves in the evaluation of used lubricating oil. These curves are plotted for fresh lubricating oil to approximate the parameters of lubricating oil diluted with diesel oil. To confirm the hypothesis, an experiment is conducted to determine the flash point, initial boiling point, density at 15 °C, kinematic viscosity at 40 °C and 100 °C, and viscosity index. The analysis covers fresh oil and used SAE 30 grade Marinol CB-30 RG1230 oil taken from the circulating lubrication system of a supercharged, trunk-piston, 4-stroke ZUT Zgoda Sulzer 5 BAH 22 engine that is located in the Marine Power Plant Laboratory of the Maritime University of Szczecin. Undiluted lubricating oils (both fresh and used) and mixtures of lubricating oils with diesel oil are examined for diesel oil concentrations in the mixture equal to 1, 2, 5, 10, 15, and 20% m/m. Orlen Efecta Diesel Biodiesel is used to prepare the mixtures. The functions approximating the parameters for fresh oil are determined and adapted to describe the variation of the same parameters for the used lubricating oil. For each case, the coefficient of determination, the maximum relative error of the model fitting to the experimental results, and the root mean square error (RMSE) are determined. In the experiment, the variation in the parameters of the used lubricating oil remained the same as for fresh oil parameters. Thus, the research hypothesis is confirmed. [ABSTRACT FROM AUTHOR]

This article shows the effect of the addition of effective microorganisms and silver on the exhaust gas composition and fuel consumption. Exhaust emission standards are becoming increasingly stringent, which makes it difficult for engine manufacturers to meet them. For this reason, intensive work is underway to use alternative propulsion systems on ships, and for diesel engines, alternative fuels. Among other things, this applies to mixtures of petroleum-based fuels with vegetable oils and their esters. Unfortunately, their use, due to their physicochemical properties, can negatively affect the performance of the engine and the wear of its components. Therefore, the aim of this study was to see how additives of effective microorganisms in the form of ceramic liquid and tubes, and a silver solution and colloidal silver would affect some engine parameters, including the exhaust gas composition and fuel consumption. The authors are not aware of the results of previous research on this issue. The tests were carried out on a diesel engine for four types of green additives at concentrations of 2% and 5%, at different ranges of its load. The additives added to the diesel fuel were characterised, and the test stand was presented, along with the parameters of the tested fuel. The effect of additives on selected engine parameters, including fuel consumption, was presented. The characteristics of hourly fuel consumption and selected components of the exhaust gas, including nitrogen oxides, carbon monoxide and carbon dioxide as a function of the concentration of ecological additives are shown and analysed. It was found that the most beneficial additive that had a positive effect on the exhaust gas composition and fuel consumption was a silver solution in a 2% concentration. There was a decrease of up to 4% in the NOx content of the exhaust gas, a decrease in carbon monoxide of more than 28%, a decrease in carbon dioxide of 4.6% and a decrease in fuel consumption of around 3% was achieved under the tested conditions. The use of these additives is an innovative solution that has a positive impact on reducing the emissions of harmful compounds into the atmosphere. In further research, it will be necessary to study the effect of this additive on the combustion process in the engine and the wear of its components, as well as to confirm the results obtained in real operating conditions. [ABSTRACT FROM AUTHOR]

The biological removal of a mixture of soil contaminants, namely, hydrocarbons, is not equally efficient for each compound. Some pollutants can be metabolized by the microbial consortium but also generated again as by-products from the removal of others. At the end of the runs, notwithstanding the high integral removal, single compounds can still be present with a relevant concentration. This paper presents the results achieved in a study of the aerobic degradation of diesel oil in three mesocosms carried out for several months with the same operative conditions. They differed in biological management: Natural Attenuation (NA), Biostimulated without inoculation (BS), and Biostimulated with Inoculation (BS + IN). At the end of the runs, the pollution removal was calculated by measuring the residual diesel oil, both as an average in the total amount of soil and only at the bottom of each column. The overall removal was around 2%, 66%, and 72% for NA, BS and BS + IN, reduced to 0%, 48%, and 47%, respectively, if measured only at the bottom. For the biostimulated mesocosms, the speciation of the hydrocarbons was carried out to assess their concentration. The findings evidence the need to delve deeper into this issue and assess the speciation of contaminants.

This article proposes using the Arrhenius model for estimating the viscosity of a mixture of two liquids in the quantitative assessment of the physicochemical properties of lubricating oils in the context of assessing the level of dilution of lubricating oil with diesel oil. Dynamic are made of mixtures of lubricating oil and diesel oil with known concentrations of 0, 1, 2, 5, 10, 20, 50, and 100% m/m of the diesel oil content in the mixture. Mixtures of the most popular oils (viscosity classes SAE 30 and SAE 40) with diesel oil that meet the requirements of the DMX of the marine distillate fuels category are prepared and tested. Viscosity measurements are performed at 40, 50, 60, 70, 80, 90, and 100 °C temperatures. The Arrhenius model is used to estimate the viscosity of the mixtures with an assumed diesel oil content and to estimate the diesel oil concentration in the mixtures with a known measured viscosity value. In both cases, the absolute estimation error is determined, and the accuracy of the estimation is assessed against the known concentration of diesel oil in the mixture with lubricating oil and the temperature at which the viscosity is measured. The estimated concentrations of diesel oil in mixtures with lubricating oil are useful to assess the condition of the lubricating oil (for concentrations of diesel oil lower than 5% m/m). The method is proposed to be used in practice to support standard laboratory oil analysis. [ABSTRACT FROM AUTHOR]

Oil pollution is one of the most dangerous pollutant due to the huge quantities that are spillage from crude oil that contains toxic compounds. To treat contaminated soil with oil, bioremediation is an important methods which involve use microorganisms and plants to degraded pollutants and clean up the soils. A biological pot factorial experiment was carried out in a (CRD) design to study the ability of Rhizobia species, a mixture of Bacillus and Grasspea leguminous plant for removal diesel oil from contaminated soil. The results showed that the different species of bacteria led to a significant increase in the amount of diesel oil absorbed by roots and shoots of plant for all treatments compared to the control treatment. And the Vigna radiata (R4) species gave a highest value (13.70 mLpot−1) absorbed by shoots compared to lowest value of control treatment (4.15 mLpot−1), with a significant increase about (230.12%). The diesel oil amounts remaining in soil were decreased significantly with the addition of different isolates of Rhizobium bacteria or Bacillus compared to the control treatment. Moreover, there were significant differences in the amount of diesel oil degraded in soil treated with different isolates of microbial treatments planted compared to control treatment. The adding Rhizobia isolated from Vicia faba (R2) recorded the highest amount decomposed (504.33) mLpot−1 compared to the control treatment (318.52) mLpot−1 with a significant increase (58.33%). Therefore, we concluded that the Grasspea plant with Rhizobia species or Bacillus can be used for phytoremediation contaminated soil with diesel oil. [ABSTRACT FROM AUTHOR]

This article discusses the potential applications of the Fuel Shot liquid catalyst in compression ignition (CI) engines for reducing toxic substances in exhaust gases. Incorporating catalysts into fuel can optimize the combustion process, consequently reducing the emission of toxic substances into the atmosphere. Toxic compounds, such as nitrogen oxides, particulate matter, and hydrocarbons, adversely affect flora and fauna. Various methods are known for reducing their concentration in engine exhaust gases, one of which is the Fuel Shot liquid catalyst. The authors conducted experiments on a Fiat 1.3 JTD engine with a Common Rail system. The results indicate that the application of the liquid catalyst reduces the content of nitrogen oxides and hydrocarbons in the exhaust gases and slightly decreases fuel consumption. Additionally, investigations were carried out on the engine's injection apparatus, which was fueled with modified fuel. The findings demonstrate that the fuel additive does not affect the wear of precision parts of fuel injectors and high-pressure pumps. [ABSTRACT FROM AUTHOR]

Experience shows that dilution of lubricating oil with diesel oil is unfavorable to the engine, causing issues including deterioration of engine performance, shortening of oil life, and reduction in engine reliability and safety. This paper presents the verification of the hypothesis that the changes in lubricity, friction coefficient, and decreasing oil film thickness (using a relative approach, given as a percentage) are similar for lubricating oil and diesel mixtures prepared from fresh lubricating oil and used lubricating oil. To validate this hypothesis, an experiment is conducted using a high-frequency reciprocating rig (HFFR), in which the lubricity is determined by the corrected average wear scar WS1.4, the coefficient of friction μ, and the percentage relative decrease in oil film thickness r. A qualitative visual assessment of the wear scars on the test specimens is also performed after the HFFR tests. The testing covers mixtures of SAE 30 grade Marinol CB-30 RG1230 lubricating oil with Orlen Efecta Diesel Biodiesel. The used lubricating oil is extracted from the circulating lubrication system of a supercharged, trunk-piston, four-stroke ZUT Zgoda Sulzer 5 BAH 22 engine installed in the laboratory of ship power plants of the Maritime University of Szczecin. Mixtures for the experiment are prepared for fresh lubricating oil with diesel oil and used lubricating oil with diesel oil. Mixtures of these lubricating oils with diesel oil are examined for diesel oil concentrations in the mixture equal to 1, 2, 5, 10, 15, and 20% m/m. The results of the experiment confirm the hypothesis, proving that, for up to 20% m/m diesel oil concentration in lubricating oil, the changes in the lubricity of used lubricating oil diluted with diesel oil can be evaluated based on reference data prepared for mixtures of diesel oil with fresh lubricating oil. The linear approximation of μ and r trends is made with a certain margin of error we estimated. The experiment also confirms the results of previous studies which state that oil aging products in small quantities contribute to improved lubricity.

Investigations into the effective, fast, and economically viable remediation of soils polluted with petroleum-derived products are still relevant. The vegetative pot experiment was conducted at the Didactic-Experimental Garden greenhouse (NE, Poland, 53.759° N, 20.452° E) on loamy sand (LS) and sandy loam (SL) soils. Its main research objective was to assess the effectiveness of biochar (B), halloysite (H) and alginite (A) in the biological regeneration of contaminated soil diesel oil (DO) and petrol (P). The assessment was conducted by determining the magnitude of the adverse impact of these xenobiotics on the growth and development of Zea mays, as well as the activity of seven soil enzymes. The impact of the tested contaminants and sorbents was assessed based on the impact factors (IF) of DO and P, as well as B, H, and A on Zea mays biomass and enzymatic activity of the soil. Soil contamination with petroleum-derived products disrupted the growth and development of Zea mays. DO had a stronger inhibitory effect on plant growth compared to P. Zea mays cultivated in LS, which was less resistant to the effects of these contaminants compared to that cultivated in SL. The impact of DO and P on enzyme activity depended on the soil texture. DO stimulated enzyme activity in LS and SL, while P only did so in LS. All remediation substances, and biochar in particular, led to an increase in plant biomass in the DO-contaminated soils. Both biochar, halloysite and alginite also improved the biochemical quality index (BA) of SL and LS. Despite the unquestionable remediation potential of the analyzed sorbents, their highest efficacy can only be achieved by their application on soils with physicochemical properties corresponding to their characteristics, which is a valuable guideline for further research. [ABSTRACT FROM AUTHOR]

The use of diesel oil has been proven to increase exhaust emissions which will have an impact on the environment. Mixing diesel oil with other fuels can reduce exhaust emissions and increase combustion efficiency. This article discusses the review of mixing kerosene with diesel oil and biodiesel. The method was the fuel are running in the diesel engine and calculated the performance and emissions in the engine. The fuel properties of mixing kerosene with diesel oil and biodiesel can reduce the level of viscosity and specific gravity of the fuel and increase the calorific value which will have an impact on improving the atomization in combustion. In addition, mixing diesel oil and kerosene can reduce emissions such as CO2, CO, HC, particulate, and opacity. However, mixing kerosene with biodiesel can increase NOx emissions. In addition, the addition of kerosene in diesel oil can lead to low fuel consumption in diesel oil. The addition of kerosene with biodiesel will increase thermal efficiency. Therefore, it can be concluded that the addition of kerosene into diesel oil and biodiesel can improve engine performance in the engine and reduce some exhaust emissions.

Sustainable biodesulfurization (BDS) processes require the use of microbial biocatalysts that display high activity against the recalcitrant heterocyclic sulfur compounds and can simultaneously withstand the harsh conditions of contact with petroleum products, inherent to any industrial biphasic BDS system. In this framework, the functional microbial BDS-related diversity in a naturally oil-exposed ecosystem, was examined through a 4,6-dimethyl-dibenzothiophene based enrichment process. Two new Rhodococcus sp. strains were isolated, which during a medium optimization process revealed a significantly enhanced BDS activity profile when compared to the model strain R. qingshengii IGTS8. In biocatalyst stability studies conducted in biphasic mode using partially hydrodesulfurized diesel under various process conditions, the new strains also presented an enhanced stability phenotype. In these studies, it was also demonstrated for all strains, that the BDS activity losses were decoupled from the overall cells' viability, in addition to the fact that the use of whole-broth biocatalyst positively affected BDS performance.

The soil pollution caused by diesel oil and heavy metals has become an increasingly serious environmental issue, with negative global-scale impacts. The remediation of contaminated soil requires special attention, in which phytoremediation has emerged as an ecofriendly solution. However, the response of plants to the combined stress of diesel oil and heavy metals remains largely unknown. In this study, the aim was to investigate the potential of Populus alba and P. russkii for phytoremediation by examining their response to combined diesel oil and heavy metal stress. In a greenhouse experiment using soil contaminated with 15 mg kg−1 of diesel oil and varying concentrations of Sr (0, 10, or 100 mg kg−1), we studied the physiological and biochemical changes, as well as the Sr absorption, of P. alba and P. russkii. The results showed that at high concentrations of Sr and diesel oil, the growth of both species was substantially inhibited, but P. alba exhibited higher resistance due to its higher antioxidant enzyme activities and increased accumulation of soluble sugar and proline. Additionally, P. alba concentrated Sr in the stem, whereas P. russkii accumulated Sr in the leaf, exacerbating its negative effects. Diesel oil treatments were beneficial for Sr extraction due to cross-tolerance. Our findings indicate that P. alba is more suitable for the phytoremediation of Sr contamination due to its superior tolerance to combined stress, and we identified potential biomarkers for monitoring pollution. Therefore, this study provides a theoretical basis and implementation strategy for the remediation of soil contaminated by both heavy metals and diesel oil. [ABSTRACT FROM AUTHOR]

The pyrolysis of plastic waste to fuel will lead to greener waste management, ensure sustainability and serve as an alternative energy source. This study seeks to convert plastic waste into diesel engine-grade oil as an alternative energy source for various applications. A mixture of plastic waste of 58% PET, 20% HDPE, 12% LDPE, 7% PP, and 3% PS were used for the study. Catalytic and thermal pyrolysis was conducted in a batch reactor at a temperature of 450 °C for 2 h using Nitrogen gas. The plastic fuel produced was then analyzed using the Fourier Transform Infrared (FT-IR) spectroscopy and Gas Chromatography-Mass Spectrometry (GC–MS). The various characteristics of the oil, such as the kinematic viscosity, calorific value, density, and pour point, were determined. The results indicated that thermal pyrolysis produced 13% liquid, 59% gas and 27% solid residue, and on the other hand, catalytic pyrolysis yielded 15.16% liquid, 69.16% of gas, and 14.8% of solid residue. The FT-IR also showed the presence of aliphatic and aromatic compounds with a predominance of the aliphatic group. From the GC–MS analysis, the plastic fuel contains 30 compounds in the C8- C40 range. The calorific value of plastic fuel after analysis was 43.175 MJ/kg in catalytic pyrolysis and 34.132 MJ/kg in thermal pyrolysis. Also, the kinematic viscosity was 4.344 cSt in catalytic pyrolysis and 2.750 cSt in thermal pyrolysis, while the density and pour point were 0.856 g/cm3 and −17 °C respectively. These results show that catalytic pyrolysis yielded more gas and liquid with high calorific value than the thermal pyrolysis. This is an indication of the use of catalysts to improve the conversion of plastic into energy. The conversion of plastic waste into diesel oil will not only address environmental challenges but help achieve the SDGs 7 & 13 as well as Goal 7 of Agenda 2063.

This article shows the effect of the addition of effective microorganisms and silver on the exhaust gas composition and fuel consumption. Exhaust emission standards are becoming increasingly stringent, which makes it difficult for engine manufacturers to meet them. For this reason, intensive work is underway to use alternative propulsion systems on ships, and for diesel engines, alternative fuels. Among other things, this applies to mixtures of petroleum-based fuels with vegetable oils and their esters. Unfortunately, their use, due to their physicochemical properties, can negatively affect the performance of the engine and the wear of its components. Therefore, the aim of this study was to see how additives of effective microorganisms in the form of ceramic liquid and tubes, and a silver solution and colloidal silver would affect some engine parameters, including the exhaust gas composition and fuel consumption. The authors are not aware of the results of previous research on this issue. The tests were carried out on a diesel engine for four types of green additives at concentrations of 2% and 5%, at different ranges of its load. The additives added to the diesel fuel were characterised, and the test stand was presented, along with the parameters of the tested fuel. The effect of additives on selected engine parameters, including fuel consumption, was presented. The characteristics of hourly fuel consumption and selected components of the exhaust gas, including nitrogen oxides, carbon monoxide and carbon dioxide as a function of the concentration of ecological additives are shown and analysed. It was found that the most beneficial additive that had a positive effect on the exhaust gas composition and fuel consumption was a silver solution in a 2% concentration. There was a decrease of up to 4% in the NOx content of the exhaust gas, a decrease in carbon monoxide of more than 28%, a decrease in carbon dioxide of 4.6% and a decrease in fuel consumption of around 3% was achieved under the tested conditions. The use of these additives is an innovative solution that has a positive impact on reducing the emissions of harmful compounds into the atmosphere. In further research, it will be necessary to study the effect of this additive on the combustion process in the engine and the wear of its components, as well as to confirm the results obtained in real operating conditions.

Desulfurization technology is vital in the removal of sulfur compounds in diesel to attain clean fuels. In this research, the mixing assisted oxidative desulfurization (MAOD) in conjunction with a high shear mixer was used with the catalyst of the activated carbon supported phosphotungstic acid. This study discusses the desulfurization of a simulated diesel, containing 2.3 wt% S of dibenzothiophene and benzothiophene in real fuel oil. The influences of mixing speed (8,000 rpm to 16,800 rpm), mixing time (30 min to 90 min), and mixing temperature (25°C to 65°C) were examined for the sulfur oxidation. A 2k full factorial design and a face-centered cube design were utilized for the screening and optimization studies, respectively, in the experimental runs. The analysis of variance was able to determine and generate a simplified quadratic model to predict the response in the MAOD process. The optimum variables for sulfur conversion were achieved at 88.5 min (mixing time), 16,800 rpm (mixing speed), and 63.28°C (mixing temperature). The confirmatory run resulted in percent oxidation of 62.37 % and validated the generated model. Moreover, the fundamental properties of diesel oil were analyzed for comparison prior to and after the MAOD method. The results revealed the retention of essential properties of the simulated diesel oil even after the MAOD treatment step. Thus, the MAOD process has successfully preserved the properties of diesel oil even after its treatment process. This indicates a promising result of the MAOD process favorable for its future applications.

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The manuscript intends to demonstrate the impact of aircraft operating fluids on the parameters of airfield hardened concrete. In the studies conducted over the longer term than provided for in the applicable standards, the impact of these operating fluids on the durability of C 30/37 concrete composed with the use of basalt and granite aggregate was determined. The tests showed that the discussed operating fluids have a destructive effect on airfield runway concrete to a varying degree. The currently applied agents that protect runway pavement against its deterioration fulfil their function only in a limited scope. [ABSTRACT FROM AUTHOR]

The widespread use of diesel fuel for transportation, industry, and electricity generation causes several environmental issues via an increase in the amount of sulfur compound emissions. Commercial diesel fuel must be free of sulfur-containing compounds since they can cause several environmental problems. Considering the currently available processes to eliminate sulfur compounds, oxidative desulfurization (ODS) is one of the effective means for this purpose. This work presented a simple, low cost, and efficient ODS system of high-sulfur diesel fuels using peroxide oxidation with the aid of citric, pimelic, and α-ketoglutaric acids. The aim of the study was to investigate the potential of these acids as hydrogen peroxide (H2O2) activators for ODS and to optimize the reaction conditions for maximum sulfur removal. The results showed that citric, pimelic, and α-ketoglutaric acids were effective catalysts for the desulfurization of high-sulfur diesel with an initial sulfur content of 2568 mg L−1, achieving a sulfur removal efficiency of up to 95%. The optimized reaction conditions were found to be 0.6 g of carboxylic acid dosage and 10 mL of H2O2 at 95 °C. The desulfurization efficiency of the real diesel sample (2568 mg L−1) was shown to be 27, 34, and 84.57%, using citric acid, α-ketoglutaric acid, and pimelic acid after 1h, respectively. The effectiveness of the oxidation process was characterized by gas chromatographic pulsed flame photometric detector (GC-PFPD) and Fourier-transform infrared spectroscopy (FTIR) techniques. The experimental results demonstrated that the developed system exhibited high efficiency for desulfurization of real high-sulfur diesel fuels that could be a good alternative for commercial application with a promising desulfurization efficiency. [ABSTRACT FROM AUTHOR]

Biofuels are interested in using alternative fuel in diesel engines because those are friendly to the environment and can be recycled. However, characteristics of chemical and physical differences compared to diesel fuel. While using the fuel injection system of an engine must be adjusted. Computational Fluid Dynamics KIVA-3V software allows simulation of the working cycle of the engine with injection pressure effect. This paper presents the results of a simulation study of B15 biofuel used on the 4CHE Yanmar diesel engine, and the fuel injection pressure was adjusted at 210, 220, 230, and 240 bar within the limits of high-pressure pump adjustment. The results showed that the soot emissions of the engine were lowest at 230 bars.

Coconut is a popular plant and is often concentrated mainly in coastal and river areas in the southern provinces of Vietnam. That is a tree with economic value and preventing erosion in river areas. Coconut tree grows very well on sandy soil with high salt tolerance, specific it is suitable for places with lots of sunshine and average rainfall as the climate in Vietnam Therefore, in Vietnam, coconuts are an abundant raw material used to produce biomass and bioenergy. This paper mainly presents the research process of applying coconut oil as a fuel to reduce environmental pollution from internal combustion engines, replacing a part of traditional fuel. Research results by experimental methods have shown that coconut oil does not need to be synthesized into biodiesel but mixed directly into diesel oil with different ratios that can be used as fuel to reduce emissions pollution, mainly soot. However, the combustion pressure of the engine tends to decrease when the proportion of coconut oil in the diesel-coconut oil mixture exceeds 20% coconut oil (20% coconut oil - 80% diesel oil).

For environmental and economic purposes, it is necessary to search for methods that reduce gas emission by flare from the oil refineries. It causes environmental pollution and warmup. All laboratory tests have been completed at Koya University, with the contribution of the Institute of Technology in Koya, to check some readings and verify their accuracy. Increasing the absorptivity of the gases by heavy oil will have expected to improve oil burning characteristics. This research aims to determine the best operating conditions that leads for higher absorption. In this research the diesel oil is considered as a heavy cut and LPG as a light gas. A lab scale unit was installed for that purpose. The amount of changes in oil weight before and after atomizing was determines as well as, the properties of the diesel oil like flash point, cetane number, and diesel index. The effect of a wide range of atomizing time (10, 20, 30, 40, 50, 60, and 90) minutes at different temperatures (0, 10, 20, 30, 40, and 50) °C was considered. The data is discussed and graphically analyzed. The optimum operating conditions is achieved by, 9 liters/minute gas Atomizing flowrate of LPG for one liter of diesel oil, atomizing Temperature is 30 ᵒC, atomizing Time is 30 minutes’ minimum till 60 minutes’ maximum. The produced Diesel Flash Point is 55 ᵒC, and the amount of gas absorption is 24 gm per 850 gm of diesel oil which represent 2.8 % of diesel weight and 5% of LPG gas flowrate.

This article provides a brief introduction to the indicators of the volatility and flammability of lubricating oils and fuels. It is proposed that the initial boiling point be used as an indicator of the contamination of lubricating oil with distillate fuel (i.e., diesel biofuel oil) in the context of the rapid detection of explosion risks in the crankcase. Detailed tests were carried out on lubricating oil samples (SAE 30 and SAE 40 grades, which are most commonly used in the lubrication systems of marine trunk engines) diluted with diesel oil at selected mass concentrations (0, 1, 2, 5, 10, 20, 50, and 100%). The oils were tested to determine their relevant properties: the flash point temperature and the initial boiling temperature. The flash point was determined in a closed crucible using the Pensky–Martens method, which is in accordance with PN-EN ISO 2719. The differences between the initial boiling point and the flash point of the tested lubricating oils were determined for different dilution levels of lubricating oil in diesel fuel. An approximate method for the calculation of the flash point of the oil based on the initial boiling point is proposed. The results of oil flash point measurements are compared with values calculated as a function of the boiling point for both lubricating oils tested. An evaluation of how well models fit the experimental results is reported. Conclusions are presented on the applicability of the proposed method during operational practice. [ABSTRACT FROM AUTHOR]

Pollution caused by petroleum oil in several manners is becoming a threat to aquatic ecosystem. Hence, we carried out an experiment to investigate how diesel oil affects biota behavior, physiological attributes and how they recover by using Nile tilapia (Oreochromis niloticus) as a model organism. Nile tilapia of two different treatment groups were exposed to 0.1 mL/L and 0.5 mL/L diesel oil for 7 days. Then both groups were kept in completely diesel oil-free water for 14 days. A control group was maintained throughout the experimental period. We examined the behavioral attributes, hemato-biochemical parameters: hemoglobin (Hb), red blood cell (RBC), white blood cell (WBC) and glucose (Glu), and morphological changes of erythrocytes after diesel exposure and at the end of recovery phase. Our results revealed that there were abnormalities in behavior and significant changes in Hb, RBC, WBC and Glu level in both of the treatment group after 7 days of exposure. Frequencies of erythrocytic cellular abnormalities (ECAs), for example, twin, spindle, elongated, tear drop and erythrocytic nuclear abnormalities (ENAs) like notch nuclei, karyopyknosis, nuclear bud and nuclear bridge were prominent in both groups. However, the amount of anomalies was higher in most if not all the cases in 0.5 mL/L treatment group. Nile tilapia of both groups were quick to recover but the 0.1 mL/L group showed profound recovery than the 0.5 mL/L group. However, in the cases of ECAs and ENAs, recovery of the 0.5 mL/L group was insignificant. Hence, our experimental study concluded that the higher the exposure to diesel oil, higher incidences of major health problems are recorded, seriously piercing the healing system of Nile tilapia.

Investigations into the effective, fast, and economically viable remediation of soils polluted with petroleum-derived products are still relevant. The vegetative pot experiment was conducted at the Didactic-Experimental Garden greenhouse (NE, Poland, 53.759° N, 20.452° E) on loamy sand (LS) and sandy loam (SL) soils. Its main research objective was to assess the effectiveness of biochar (B), halloysite (H) and alginite (A) in the biological regeneration of contaminated soil diesel oil (DO) and petrol (P). The assessment was conducted by determining the magnitude of the adverse impact of these xenobiotics on the growth and development of Zea mays, as well as the activity of seven soil enzymes. The impact of the tested contaminants and sorbents was assessed based on the impact factors (IF) of DO and P, as well as B, H, and A on Zea mays biomass and enzymatic activity of the soil. Soil contamination with petroleum-derived products disrupted the growth and development of Zea mays. DO had a stronger inhibitory effect on plant growth compared to P. Zea mays cultivated in LS, which was less resistant to the effects of these contaminants compared to that cultivated in SL. The impact of DO and P on enzyme activity depended on the soil texture. DO stimulated enzyme activity in LS and SL, while P only did so in LS. All remediation substances, and biochar in particular, led to an increase in plant biomass in the DO-contaminated soils. Both biochar, halloysite and alginite also improved the biochemical quality index (BA) of SL and LS. Despite the unquestionable remediation potential of the analyzed sorbents, their highest efficacy can only be achieved by their application on soils with physicochemical properties corresponding to their characteristics, which is a valuable guideline for further research.

This article discusses current testing methods for motor vehicle engines. Traction engines have so far been tested, for example, according to WLTP (Worldwide Harmonized Light Vehicle Test Procedure) driving tests, but due to the "VW—gate" incident, these are now to be supplemented by RDE (Real Driving Emissions) tests, conducted under real road conditions. The analyses of the state of knowledge and the directions of research to date unequivocally indicate the need for the construction of a stand that allows: testing of a complete vehicle admitted to traffic; testing of a motor vehicle with the possibility of simulating real operating conditions; load setting with the possibility of its regulation; feeding the engine with various fuels; modification of the software of controllers having a direct impact on the control strategies of the engine; transmission and traction control system; reading, recording and analysis of the parameters of the operation of control systems in real time; detailed recording and analysis of the combustion process occurring directly in the combustion chamber; and the measurement of emitted toxic substances. On a bench with the above features, tests were carried out on a diesel motor vehicle, which were based on recording changes in the parameters of the combustion and injection process. The tests were conducted under static and dynamic conditions. Tests under static conditions were conducted on a chassis dynamometer. They consisted of indicating the engine for different fuel dose control maps. The vehicle equipped with the test engine was driven at a constant speed on the chassis dynamometer and loaded with a drag force of 130 Nm. Tests under dynamic conditions were conducted under real traffic conditions. They were limited to the presentation of results under static conditions. The main results of the tests are given in the conclusion and include a general summary. In particular, the presented results of the diesel tests demonstrate an attempt to adapt the engine to co-power with hydrogen. [ABSTRACT FROM AUTHOR]

This study was conducted to assess the survival rates, growth, and chlorophyll fluorescence (Fv/Fm) of four hybrid aspen (14, 191, 27, 291) and two European aspen (R3 and R4) clones cultivated in creosote- and diesel oil-contaminated soil treatments under three different plant densities: one plant per pot (low density), two plants per pot (medium density), and six plants per pot (high density) over a period of two years and three months. Evaluating the survival, growth, and Fv/Fm values of different plants is a prerequisite for phytoremediation to remediate polluted soils for ecological restoration and soil health. The results revealed that contaminated soils affected all plants' survival rates and growth. However, plants grown in the creosote-contaminated soil displayed a 99% survival rate, whereas plants cultivated in the diesel-contaminated soil showed a 22–59% survival rate. Low plant density resulted in a higher survival rate and growth than in the other two density treatments. In contrast, the medium- and high-density treatments did not affect the plant survival rate and growth to a greater extent, particularly in contaminated soil treatments. The effects of clonal variation on the survival rate, growth, and Fv/Fm values were evident in all treatments. The results suggested that hybrid aspen clones 14 and 291, and European aspen clone R3 were suitable candidates for the phytoremediation experiment, as they demonstrated reasonable survival rates, growth, and Fv/Fm values across all treatments. A superior survival rate for clone 291, height and diameter growth, and stem dry biomass production for clone 14 were observed in all soil treatments. Overall, a reasonable survival rate (~75%) and Fv/Fm value (>0.75) for all plants in all treatments, indicating European aspen and hybrid aspen have considerable potential for phytoremediation experiments. As the experiment was set up for a limited period, this study deserves further research to verify the growth potential of different hybrid aspen and European aspen clones in different soil and density treatment for the effective phytoremediation process to remediate the contaminated soil. [ABSTRACT FROM AUTHOR]

Background: Today, soil pollution with heavy metals and petroleum compounds is one of the main environmental problems. This research was done to investigate the effect of drought stress, soil salinity, Piriformospora indica (P. indica), and MWCNs on biodegradation of diesel oil in the soil that contaminated with Pb and Cd under cultivation of triticale plant.Methods: Treatments consisted of applying MWCNs (2% [W/W]) in the Pb- and Cd-polluted soil that was simultaneously polluted with diesel oil (0, 5, and 10% [W/W]), and the plants used in this study were inoculated with P. indica. After 70 days, plants were harvested, and plant and soil Cd were measured using AAS (atomic absorption spectrometry). In addition, the degradation percentage of diesel oil in soil was determined.Results: Soil application of MWCNs at the rate of 2% (W/W) significantly increased the biodegradation of diesel oil in the soil in the drought and salinity (6 dS/m) stress by 11.3% and 15.6%, respectively. In addition, plant inoculation with P. indica significantly increased the biodegradation of diesel oil in the soil by 12.3%. For salinity (6 dS/m) and drought stress, it was increased by 8.3% and 9.4%, respectively. In addition, the Pb and Cd concentrations decreased by 14.3% and 12.8%, respectively, when the MWCNs were added to the soil (2% [W/W]).Conclusion: Soil application of MWCNs and plant inoculation with P. indica not only increased the biodegradation of diesel oil but also decreased the plant Pb and Cd concentrations.

The group composition of diesel oil (DO) predetermines the basic physical, chemical and calorific properties of fuel, which have a significant impact on the processes of evaporation, ignition and combustion of fuel in the diesel engine and, consequently, on its performance and fuel economy indicators. The group composition of diesel oil of various grades is characterized by a certain content in it of various hydrocarbon components and chemical compounds. One of the effective methods of researching the group composition of diesel oil is chromatography-mass spectrometry. Chromatographic separation of summer and winter diesel fuel into hydrocarbon components and chemical compounds, as well as their mass-spectrometric analysis were carried out on a chromato-mass-spectrometer of the Chromatec company. The obtained mass-spectra of hydrocarbon components and chemical compounds made it possible to determine the group composition of diesel fuel brands DT-L-K5 and DT-Z-K5. The results of test-bench runs of an automobile diesel engine D-245.12C show that the engine produces the maximum effective power when running on summer diesel and less power when running on winter diesel. Fuel efficiency indicators (hourly and specific effective fuel consumption) of the diesel engine at its operation on winter diesel oil is better in comparison to the operation on summer diesel oil. The highest values of effective efficiency are observed when the diesel is operated on winter diesel oil.

The soil pollution caused by diesel oil and heavy metals has become an increasingly serious environmental issue, with negative global-scale impacts. The remediation of contaminated soil requires special attention, in which phytoremediation has emerged as an ecofriendly solution. However, the response of plants to the combined stress of diesel oil and heavy metals remains largely unknown. In this study, the aim was to investigate the potential of Populus alba and P. russkii for phytoremediation by examining their response to combined diesel oil and heavy metal stress. In a greenhouse experiment using soil contaminated with 15 mg kg−1 of diesel oil and varying concentrations of Sr (0, 10, or 100 mg kg−1), we studied the physiological and biochemical changes, as well as the Sr absorption, of P. alba and P. russkii. The results showed that at high concentrations of Sr and diesel oil, the growth of both species was substantially inhibited, but P. alba exhibited higher resistance due to its higher antioxidant enzyme activities and increased accumulation of soluble sugar and proline. Additionally, P. alba concentrated Sr in the stem, whereas P. russkii accumulated Sr in the leaf, exacerbating its negative effects. Diesel oil treatments were beneficial for Sr extraction due to cross-tolerance. Our findings indicate that P. alba is more suitable for the phytoremediation of Sr contamination due to its superior tolerance to combined stress, and we identified potential biomarkers for monitoring pollution. Therefore, this study provides a theoretical basis and implementation strategy for the remediation of soil contaminated by both heavy metals and diesel oil.

This paper investigated the micron-scale activated carbon (MAC) immobilized diesel-oil-degrading bacteria (bio-MAC) used as remediation materials for the removal of diesel-oil-contaminated water. The high-efficiency indigenous diesel-oil-degrading bacteria were firstly screened and enriched, then the MAC was used as a diesel oil sorbent and biocarrier for the immobilization of degrading bacteria to prepare the bio-MAC material. The removal performance of the bio-MAC was evaluated via a comparison with the freely degrading bacteria and MAC. The SEM results demonstrated that the diesel-oil-degrading bacteria were effectively immobilized and grew well on the surfaces of MAC particles. The concentration of MAC significantly influenced the growth and activity (DHA and LPS) of immobilized bacteria, and the MAC addition of 3.0 g/L was proven to be an optimum amount for the preparation of bio-MAC. The high-throughput sequencing analysis further indicated that the bacteria immobilized on MAC showed higher abundance levels and diversities index values compared to freely suspended bacteria, such as Pseudomonas, Rhodococcus, Bacillus and Microbacterium. The FTIR spectroscopy results showed that the bio-MAC could effectively degrade the aliphatic hydrocarbons, alkenes and aromatic compounds of diesel oil to carboxylic acids, esters, alcohols and other metabolites. When the concentration of diesel oil was 1 g/L, the removal efficiency for the diesel oil of bio-MAC reached 86.35% after 15 days, while only 23.82% and 70.97% of the diesel oil was removed using the same amount of free bacteria and MAC, respectively. The prepared bio-MAC showed a synergic effect of adsorption and biodegradation and efficiently removed diesel oil from wastewater. [ABSTRACT FROM AUTHOR]

The electromagnetic properties (electrical permittivity and electrical conductivity) of three different soil mesocosms polluted with diesel oil were monitored using a time-domain reflectometry probe for 8 months. The main target of the research was to establish a relationship between the development of biological activity within the mesocosms and the temporal behaviour of electromagnetic properties. The trend of the electromagnetic properties exhibited different responses that could be related to the composition of the mesocosms and their variation with time during the runs. We considered three different mesocosms with similar soil conditions and the same diesel oil concentration: porosity of 45%, volumetric diesel oil content of 9%, and volumetric water content of 15%. The first one was subjected to a natural attenuation (NA), the second one was biostimulated without inoculation (BS), and the third one was biostimulated with inoculation (BS + IN). The biostimulated mesocosms showed a marked decrease in electrical permittivity and electrical conductivity, whereas the naturally attenuated mesocosm did not show these variations. Between the biostimulated mesocosms, the inoculated one showed the fastest variations in the electromagnetic properties. The microbial activity and the pollutant degradation were evidenced by the analyses performed at the end of the experiment. As demonstrated by the results for the fluorescein diacetate analysis, the microbial activity was a bit higher for the inoculated microcosm, which also showed faster variations of the electromagnetic properties. In the biostimulated mesocosms, the removal of diesel oil was 66% and 72%, respectively. With natural attenuation, there was a limited removal efficiency, in the order of 2%. Even if the electromagnetic properties evidenced different kinetics of bioremediation in BS and BS + IN, both were able to successfully degrade similar percentages of the contaminant after 8 months. The long monitoring revealed that a substantial decrease in the electromagnetic properties happened only in the first month after contamination. Additionally, an increasing trend of the permittivity was detected in the following months, before reaching a steady-state condition. This study revealed that biodegradation processes with acceptable overall removal efficiency can be monitored successfully by observing the variations in the electromagnetic properties. [ABSTRACT FROM AUTHOR]

Besides technological processes; logistics; and the use of petrol and light solvents, which are widely known as pollutants, the sources of BTEX hydrocarbon contributing to air pollution may also include other petroleum products and fuels that feature higher boiling points and that have not yet been associated with this issue. In this study, the contents of benzene; toluene; ethylbenzene; and o-, m-, and p-xylene were evaluated in 25 commercial samples of diesel oils; the gaseous phase in thermodynamic equilibrium with liquid diesel oil at 40 °C was then evaluated. Based on the experimental results, it was found that benzene concentration in the gaseous phase is five to more than fifteen times higher than the limits set by regulations for benzene concentration in the air at a work place (1.6 mg/m3) and cannot be compared with the limits set by regulations for annual average basal levels of benzene concentration in the air (5 µg/m3). The research revealed that diesel oil is a potential source of environmental contamination from BTEX hydrocarbons, in particular benzene. [ABSTRACT FROM AUTHOR]

In this research work, selenium dioxide (SeO2) nanorods have been prepared by a solvothermal method in which a strong reducing agent (NaBH4) was used to reduce precursor salt into SeO2 nanorods. X-ray diffraction (XRD) technique was applied to observe the crystal structure which confirmed its tetragonal geometry. Moreover, morphology and particle size were studied by scanning electron microscopy (SEM). SEM fully described the 1-dimensional morphology of SeO2 nanorods which then arranged themselves to create a 3-dimensional flower-like structure with an average particle size of 50 nm. Also, the catalytic activity of SeO2 nanorods as diesel-additive was studied by defining different parameters such as fire and flash points, calorific value, cloud and pour points, specific gravity, and kinematic viscosity. Subsequently, SeO2 nanorods proved to be an excellent diesel additive due to higher total heat content and lower value of kinematic viscosity which enhances the better performance of the diesel engine.

Aims: This study was done to evaluate the effectiveness of foliar applications of synthesized zinc-amino acid chelates and ZnSO4 on the nutritional status of wheat plant in a soil contaminated with Cd and diesel oil. Materials and Methods: Treatments were consist of foliar application of Zn amino acid chelate (Zn(Arg)2 and (Zn(His)2) and ZnSO4 at the rate of 0, 0.1, and 0.2% (W/V) in the soil co-contaminated with Cd (0, 10, and 20 mg Cd/kg soil) and diesel oil (0 and 8% [W/W]). Results: Application of Zn amino acid chelates had a significant effect on increasing plant nutrient status, however, soil pollution with Cd and diesel oil had an adverse effect. Based on the results of this study, application of 0.2% (W/V) (Zn(Arg)2 and (Zn(His)2) significantly increased the grain Zn concentration of the plants grown in the soil polluted with Cd (10 mg Cd/kg soil) and diesel oil (8% [W/W]) by 11.3% and 10.1%, respectively. For co-contaminated soil with Cd and diesel oil, it was increased by 9.8%. Soil microbial respiration has affected by Zn amino acid chelate and soil pollution. According to our results, application of 0.2% (W/V) Zn(Arg)2 chelate significantly increased the soil microbial respiration in the soil polluted with Cd (10 mg Cd/kg soil) and diesel oil (8% [W/W]) by 12.5% and 13.1%, respectively. Conclusion: Zn amino acid chelate had a significant effect in increasing plant nutrient status such as Zn and Fe that is a positive point environmental study.

Goal: This study analyzes the impacts of the transportation sector on air pollution within the scope of one major Brazilian metropolitan region. Design / Methodology / Approach: A literature review was conducted on the subject's constructs, with subsequent reasoning grounded on the fleet's characteristics and data obtained from in-depth interviews from a government transportation agency. Results: The results show Brazil's contextual evidence that risk management for the haulage sector should consider air pollution's negative impacts. With air quality standards as an essential reference, it is possible to observe that the city of Uberlândia does not effectively manage air quality. Limitations of investigation: One limitation of this research is related to the representativeness of the sample. The research also recommends future studies to use government policies for the improvement of the framework. Practical implications: The local and contextual addressing of air pollution and transport correlation in one focal point for cargo transportation at a national level pontentially contributes to environmental public policies. Originality / Value: Originality value resides in considering emissions from cargo vehicles as a significant factor in this process of air pollution in a specific context of a metropolitan area of an emerging economy that has its transportation modal grounded on trucking freight. [ABSTRACT FROM AUTHOR]

Carbon aerogel (CA) was prepared using the cellulose extracted from luffa sponge (LS). Trichlorosilane was employed to modify CA to enhance the adsorption capacity for diesel oil. The physical and chemical properties of aerogel, CA and modified CA were analyzed using XRD (X-ray diffraction), XPS (X-ray photoelectron spectroscopy), FTIR (Fourier Transform infrared spectroscopy), SEM (scanning electron microscope) and TGA/DTG (Thermogravimetric analysis/Derivative Thermogravimetry). Modified carbon aerogel (MCA) had better adsorption capacity for diesel oil (49.62 g/g) than aerogel (5.2 g/g) and CA (32.34 g/g). In addition, the adsorption capacity of MCA for other organics was also investigated, which indicated the abroad application scope for MCA. The reuse method (burning, suction filtration and pyrolysis) for diesel oil adsorption using MCA was investigated and pyrolysis shown the optimal effect for MCA regeneration. The cycle times of MCA for diesel oil adsorption was studied using pyrolysis to regenerate MCA and MCA still had good adsorption capacity for diesel oil (45.14 g/g) in the sixth use. This paper provides a novel strategy for resource utilization of LS and a fast and green method for diesel oil treatment. [ABSTRACT FROM AUTHOR]

In this research, the soil samples were contaminated with 0.05% and 0.1% of cadmium and lead. Seventy pots containing 200 g of soil were polluted with 5% diesel (w/w) (10 g). The physicochemical parameters of the soil were determined. There was a decrease in the pH, and electrical conductivity but the nitrogen, phosphorous, organic carbon and organic matter increased during the 84 days of biodegradation. The bacteria isolated from diesel oil contaminated soil were species of Bacillus and Pseudomonas. The GC-MS analysis revealed a significant decrease in the alkane and an increase in the ester constituents of the biodegraded oil samples after 84 days. Diesel oil co-contaminated soil supplemented with 0.1% of cadmium and lead had a percentage degradation of 89.5% and 80.54% respectively while compared to the un-supplemented samples (28.36%) after 84 days. This indicates that lead and cadmium as co-contaminant in diesel contaminated soil improved the rate of biodegradation of diesel.

Bioremediation is one of kind method which use of bacteria to degrade of hydrocarbon to be another compound. This study aims to get isolation of indigenous bacteria and potential test with Gordonia terrae on diesel oil bioremediation. The water sample was taken from Tanjung Perak Port of Surabaya, Indonesia where contaminated with diesel oil. Analysis of in-situ water quality parameters were consist of Dissolved oxygen, temperature, pH, salinity. Strain isolate bacteria were isolated by Bushnell-Hass medium. The bacterial density result shows in IN6 shows that bacterial density increased up to 9 × 108 cells/ml at day 2 incubation and decrease up to 1.79 × 108 cells/ml at final incubation, IN8 increased up to 8.6 × 108 cells/ml, then decrease up to 3.57 × 108 cells/ml. While, EX8 increased up to 9.1 × 108 cells/ml, and then decrease up to 3.06 × 108 cells/ml. While, results of degradation diesel oil hydrocarbon show treatment IN6, TPH values showed a decrease in the initial hydrocarbon concentration of 30 ppm to 16 ppm. IN8 TPH value shows a decrease in the initial hydrocarbon concentration of 30 ppm to 16 ppm. EX8 TPH value shows a decrease in the initial hydrocarbon concentration of 30 ppm to 24 ppm. In this experiment was found that Bacillus cereus was effectively degrading of diesel oil and can be agent bacterial for bioremediation.

This article discusses current testing methods for motor vehicle engines. Traction engines have so far been tested, for example, according to WLTP (Worldwide Harmonized Light Vehicle Test Procedure) driving tests, but due to the “VW—gate” incident, these are now to be supplemented by RDE (Real Driving Emissions) tests, conducted under real road conditions. The analyses of the state of knowledge and the directions of research to date unequivocally indicate the need for the construction of a stand that allows: testing of a complete vehicle admitted to traffic; testing of a motor vehicle with the possibility of simulating real operating conditions; load setting with the possibility of its regulation; feeding the engine with various fuels; modification of the software of controllers having a direct impact on the control strategies of the engine; transmission and traction control system; reading, recording and analysis of the parameters of the operation of control systems in real time; detailed recording and analysis of the combustion process occurring directly in the combustion chamber; and the measurement of emitted toxic substances. On a bench with the above features, tests were carried out on a diesel motor vehicle, which were based on recording changes in the parameters of the combustion and injection process. The tests were conducted under static and dynamic conditions. Tests under static conditions were conducted on a chassis dynamometer. They consisted of indicating the engine for different fuel dose control maps. The vehicle equipped with the test engine was driven at a constant speed on the chassis dynamometer and loaded with a drag force of 130 Nm. Tests under dynamic conditions were conducted under real traffic conditions. They were limited to the presentation of results under static conditions. The main results of the tests are given in the conclusion and include a general summary. In particular, the presented results of the diesel tests demonstrate an attempt to adapt the engine to co-power with hydrogen.

The photocatalysis of graphtic carbon nitride (g-C3N4) material has been widely used for the photocatalytic degradation of organic pollutants. However, g-C3N4 still has some drawbacks, such as the high recombination of photo-induced electron–hole pairs and weak absorption of light irradiation. To further improve the photodegradation performance of g-C3N4, a novel composite photocatalyst (CoO/ PT-C3N4) has been prepared by using a one-pot calcination method, in which cobalt oxide (CoO) as a cocatalyst are introduced on the rectangular hollow substrate of g-C3N4 (PT-C3N4), The CoO/PT-C3N4 composite photocatalyst delivers an excellent photodegradation performance for diesel oil under a simulated sunlight. It exhibits a high degradation efficiency of 95.92% after light irradiation for 2 h, which is much higher than that of pristine PT-C3N4. Free radical capture experiments manifest that the free radical of ·O2− plays a major role for the photodegradation and main active radicals abide by the sequence: ·O2− > ·OH > h+. Moreover, the CoO/PT-C3N4 composite photocatalyst delivers an excellent cyclic stability, which only degrades 8.71% photodegradation efficiency after 10 cycles. The improvement of CoO/PT-C3N4 composite photocatalyst is ascribed to the formation of a heterojunction between CoO and PT-C3N4, which promotes the separation of photo-induced carriers. This work paves a new way for the exploration of photocatalyst for the organic pollutant degradation. [ABSTRACT FROM AUTHOR]

This study was conducted to assess the survival rates, growth, and chlorophyll fluorescence (Fv/Fm) of four hybrid aspen (14, 191, 27, 291) and two European aspen (R3 and R4) clones cultivated in creosote- and diesel oil-contaminated soil treatments under three different plant densities: one plant per pot (low density), two plants per pot (medium density), and six plants per pot (high density) over a period of two years and three months. Evaluating the survival, growth, and Fv/Fm values of different plants is a prerequisite for phytoremediation to remediate polluted soils for ecological restoration and soil health. The results revealed that contaminated soils affected all plants’ survival rates and growth. However, plants grown in the creosote-contaminated soil displayed a 99% survival rate, whereas plants cultivated in the diesel-contaminated soil showed a 22–59% survival rate. Low plant density resulted in a higher survival rate and growth than in the other two density treatments. In contrast, the medium- and high-density treatments did not affect the plant survival rate and growth to a greater extent, particularly in contaminated soil treatments. The effects of clonal variation on the survival rate, growth, and Fv/Fm values were evident in all treatments. The results suggested that hybrid aspen clones 14 and 291, and European aspen clone R3 were suitable candidates for the phytoremediation experiment, as they demonstrated reasonable survival rates, growth, and Fv/Fm values across all treatments. A superior survival rate for clone 291, height and diameter growth, and stem dry biomass production for clone 14 were observed in all soil treatments. Overall, a reasonable survival rate (~75%) and Fv/Fm value (>0.75) for all plants in all treatments, indicating European aspen and hybrid aspen have considerable potential for phytoremediation experiments. As the experiment was set up for a limited period, this study deserves further research to verify the growth potential of different hybrid aspen and European aspen clones in different soil and density treatment for the effective phytoremediation process to remediate the contaminated soil.

In soil bioremediation, the main target is the removal of pollutants to the maximum extent. Careful monitoring of pollution concentration provides information about the process efficacy and removal efficiency. Moreover, a detailed analysis of residual pollution composition provides a detailed picture of single compound removal or presence, especially of interest when pollution is constituted by a mixture of chemical species. This paper shows the first results of a study on the speciation of diesel oil compound removal from soils by aerobic remediation. The experimental study was carried out in a microcosm using indigenous microorganisms and adopting the biostimulation strategy with a mineral salt medium for bacteria. The microcosm contained 200 g of dry soil and 14 g of diesel oil with a carbon to nitrogen ratio (C/N) equal to 180 and water content (u%) equal to 12% by mass. The residual pollution concentration in soil was monitored for 138 days to evaluate both the overall removal efficiency and that for the main groups of hydrocarbons. The results showed that the pollution composition changed during the test because of the different rate of metabolization for the single compounds: the overall removal efficiency was about 65%, and that of different hydrocarbon clusters was between 53% and 88%. The monitoring data also allowed the kinetic study of the degradation process, which was better modeled by a second-order kinetic model than by a first-order one. These findings were confirmed by analyzing other microcosms with different operative conditions (C/N = 120, 180 and u% = 8%, 12%, 15% by mass). The proposed methodology may be useful for the evaluation of compliance to concentration limits imposed by law. [ABSTRACT FROM AUTHOR]

Meiobenthos has been considered as an excellent tool for biomonitoring assessment. Elevated temperature and oil pollution are considered as the most pervasive aspects of global environmental changes and matter of concern for contemporary society. Presently, very limited information is available about the synergistic effect of these stressors on meiobenthic community structure and tolerance potential from tropical intertidal environment. Here, we assessed their impacts on meiobenthic community by conducting a 60 days long benthocosm experiment selecting three sets of temperature (25°, 30° and 35 °C) and two sets of diesel oil (low and high) combinations. Gradual changes in their community composition were revealed discernibly with exposures to both the disturbances after 30 and 60 days of experimental period. Diversity profiles for the nematodes were less affected, but copepods showed a graded response of decreasing density with increasing dose of both the stressors. Other meiobenthic taxa such as halacarid mite, turbellaria and polycheate juveniles were adversely affected and eliminated from the treatments, howbeit abundance of ostracods, foraminiferans and bivalve settlers varied significantly. A 3-factor PERMANOVA indicated a significant effect of temperature, diesel, between their interaction and interaction among stressors and time on meiofaunal abundances. In case of free-living nematodes, temperature rise and diesel contamination synchronously led to an elimination of k-selected species like Halalaimus gracilis, H. longicaudatus, Oxystomina aesetosa and Pomponema sp. with a significant decrease in abundance of H. capitulatus and Oncholaimus sp. The r-selected species Daptonema invagiferoum, Sabatieria praedatrix, Theristus acer, Monhystera sp. and Thalassomonhystera sp. had endured even at high doses of diesel treatment in three different temperatures set up. The effects were evident in term of changes in life strategies with an increment of opportunistic species and increased trophic diversity of deposit feeders in treated sediments. Overall, elevated temperature together with diesel oil contamination were found to alter species dynamics within shallow intertidal meiobenthic communities, which might have significant Armageddon on benthic ecosystem functioning.