1. Photocatalytic Abstraction of Hydrogen Atoms from Water Using Hydroxylated Graphitic Carbon Nitride for Hydrogenative Coupling Reactions
- Author
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Dongsheng Zhang, Pengju Ren, Wuwen Liu, Yaru Li, Sofia Salli, Feiyu Han, Wei Qiao, Yu Liu, Yingzhu Fan, Yi Cui, Yanbin Shen, Emma Richards, Xiaodong Wen, Mark H. Rummeli, Yongwang Li, Flemming Besenbacher, Hans Niemantsverdriet, Tingbin Lim, and Ren Su
- Subjects
Coupling Reaction ,Water ,Heterogeneous Photocatalysis ,General Medicine ,General Chemistry ,Hydrogen Atom Transfer ,Surface Hydroxylation ,Catalysis - Abstract
Employing pure water, the ultimate green source of hydrogen donor to initiate chemical reactions that involve a hydrogen atom transfer (HAT) step is fascinating but challenging due to its large H−O bond dissociation energy (BDEH-O=5.1 eV). Many approaches have been explored to stimulate water for hydrogenative reactions, but the efficiency and productivity still require significant enhancement. Here, we show that the surface hydroxylated graphitic carbon nitride (gCN−OH) only requires 2.25 eV to activate H−O bonds in water, enabling abstraction of hydrogen atoms via dehydrogenation of pure water into hydrogen peroxide under visible light irradiation. The gCN−OH presents a stable catalytic performance for hydrogenative N−N coupling, pinacol-type coupling and dehalogenative C−C coupling, all with high yield and efficiency, even under solar radiation, featuring extensive impacts in using renewable energy for a cleaner process in dye, electronic, and pharmaceutical industries.
- Published
- 2022