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Within the framework of Landau-de Gennes theory for nematic liquid crystals, we study the temperature-induced isotropic-nematic phase transition on a spherical shell. Below a critical temperature, a thin layer of nematic coating a microscopic spherical particle exhibits non-uniform textures due to the geometrical frustration. We find the exact value of critical threshold for the temperature and determine exactly the nematic textures at the transition by means of a weakly nonlinear analysis. The critical temperature is affected by the extrinsic curvature of the sphere, and the nematic alignment is consistent with the Poincar\'e-Hopf index theorem and experimental observations. The stability analysis of the bifurcate textures at the isotropic-nematic transition highlight that only the tetrahedral configuration is stable.

Within the framework of continuum theory, we draw a parallel between ferromagnetic materials and nematic liquid crystals confined on curved surfaces, which are both characterized by local interaction and anchoring potentials. We show that the extrinsic curvature of the shell combined with the out-of-plane component of the director field gives rise to chirality effects. This interplay produces an effective energy term reminiscent of the chiral term in cholesteric liquid crystals, with the curvature tensor acting as a sort of anisotropic helicity. We discuss also how the different nature of the order parameter, a vector in ferromagnets and a tensor in nematics, yields different textures on surfaces with the same topology as the sphere. In particular, we show that the extrinsic curvature governs the ground state configuration on a nematic spherical shell, favouring two antipodal disclinations of charge +1 on small particles and four $+1/2$ disclinations of charge located at the vertices of a square inscribed in a great circle on larger particles.

We consider the elastic deformation of a circular cylindrical sector composed of an incompressible isotropic soft solid when it is straightened into a rectangular block. In this process, the circumferential line elements on the original inner face of the sector are stretched while those on the original outer face are contracted. We investigate the geometrical and physical conditions under which the latter line elements can be contracted to the point where a localized incremental instability develops. We provide a robust algorithm to solve the corresponding two-point boundary value problem, which is stiff numerically. We illustrate the results with full incremental displacement fields in the case of Mooney-Rivlin materials and also perform an asymptotic analysis for thin sectors

One of the least studied universal deformations of incompressible nonlinear elasticity, namely the straightening of a sector of a circular cylinder into a rectangular block, is revisited here and, in particular, issues of existence and stability are addressed. Particular attention is paid to the system of forces required to sustain the large static deformation, including by the application of end couples. The influence of geometric parameters and constitutive models on the appearance of wrinkles on the compressed face of the block is also studied. Different numerical methods for solving the incremental stability problem are compared and it is found that the impedance matrix method, based on the resolution of a matrix Riccati differential equation, is the more precise.

We give conditions on the strain-energy function of nonlinear anisotropic hyperelastic materials that ensure compatibility with the classical linear theories of anisotropic elasticity. We uncover the limitations associated with the volumetric deviatoric separation of the strain energy used, for example, in many Finite Element (FE) codes in that it does not fully represent the behavior of anisotropic materials in the linear regime. This limitation has important consequences. We show that, in the small deformation regime, a FE code based on the volumetric-deviatoric separation assumption predicts that a sphere made of a compressible anisotropic material deforms into another sphere under hydrostatic pressure loading, instead of the expected ellipsoid. For finite deformations, the commonly adopted assumption that fibres cannot support compression is incorrectly implemented in current FE codes and leads to the unphysical result that under hydrostatic tension a sphere of compressible anisotropic material deforms into a larger sphere.

We study what is clearly one of the most common modes of deformation found in nature, science and engineering, namely the large elastic bending of curved structures, as well as its inverse, unbending, which can be brought beyond complete straightening to turn into eversion. We find that the suggested mathematical solution to these problems always exists and is unique when the solid is modelled as a homogeneous, isotropic, incompressible hyperelastic material with a strain-energy satisfying the strong ellipticity condition. We also provide explicit asympto-tic solutions for thin sectors. When the deformations are severe enough, the compressed side of the elastic material may buckle and wrinkles could then develop. We analyse in detail the onset of this instability for the Mooney-Rivlin strain energy, which covers the cases of the neo-Hookean model in exact non-linear elasticity and of third-order elastic materials in weakly non-linear elasticity. In particular the associated theoretical and numerical treatment allows us to predict the number and wavelength of the wrinkles. Guided by experimental observations we finally look at the development of creases, which we simulate through advanced finite element computations. In some cases the linearised analysis allows us to predict correctly the number and the wavelength of the creases, which turn out to occur only a few percent of strain earlier than the wrinkles.

Nematic interfaces are thin fluid films, ideally two-dimensional, endowed with an in-plane degenerate nematic order. In this letter we examine a generalisation of the classical Plateau problem to an axisymmetric nematic interface bounded by two coaxial parallel rings. The equilibrium interface shape results from the competition between surface tension, which favours the minimization of the interface area, and the nematic elasticity which instead promotes the alignment of the molecules along a common direction. We find two classes of equilibrium solutions with intrinsically uniform alignments: one in which the molecules are aligned along the meridians, the other along parallels. Depending on two parameters, one geometric and the other constitutive, the Gaussian curvature of the equilibrium interface may be negative, vanishing or positive. The stability of these equilibrium configurations is investigated.

We derive the hydrodynamic equations for nematic liquid crystals lying on curved substrates. We invoke the Lagrange-Rayleigh variational principle to adapt the Ericksen-Leslie theory to two-dimensional nematics in which a degenerate anchoring of the molecules on the substrate is enforced. The only constitutive assumptions in this scheme concern the free-energy density, given by the two-dimensional Frank potential, and the density of dissipation which is required to satisfy appropriate invariance requirements. The resulting equations of motion couple the velocity field, the director alignment and the curvature of the shell. To illustrate our findings, we consider the effect of a simple shear flow on the alignment of a nematic lying on a cylindrical shell.

We propose a continuum model to describe the molecular alignment in thin nematic shells. By contrast with previous accounts, the two-dimensional free energy, aimed at describing the physics of thin films of nematics deposited on curved substrates, is not postulated but it is deduced from the conventional three-dimensional theories of nematic liquid crystals. Both the director and the order-tensor theories are taken into account. The so-obtained surface energies exhibit extra terms compared to earlier models. These terms reflect the coupling of the geometry of the shell with the nematic order parameters. As expected, the shape of the shell plays a key role in the equilibrium configurations of nematics coating it.