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Fracture toughness is an important characteristic for coatings for high speed cutting of titanium. This study focuses on improving the fracture toughness of the coatings using a layered design method. TiAlN/CrN multilayer coatings with bilayer periods between 12 nm and 270 nm were prepared by reactive magnetron sputtering. XRD results show the multilayer coatings have face-centred cubic structures. When the bilayer period of multilayer coating decreases from 270 nm to 25 nm, the coating hardness decreases from 24.5 GPa to 18.1 GPa. Increased fracture toughness and adhesion strength of multilayer coatings are observed with decreasing bilayer periods. A maximum fracture toughness (K IC ) of 3.6 MPa m 1/2 and adhesion strength of 107 N were obtained with a 25 nm bilayer period. The inhibition of crack propagation is the main reason for the high fracture toughness values in multilayer coatings. However, when the bilayer period is decreased further (12 nm), the coating hardness begins to increase rapidly to 23.4 GPa, and the fracture toughness and adhesion strength begin to decrease. Titanium cutting results show that an improvement in cutting performance is obtained with a TiAlN/CrN_25 multilayer coating. [ABSTRACT FROM AUTHOR]

Ti 1 − x − y Al x Ta y N coatings with various Ta contents ( y = 0.00–0.37) have been prepared by magnetron sputtering. Scanning electronic microscopy results show that the increased Ta content makes Ti 1 − x − y Al x Ta y N coatings more compact and exhibit a finer columnar structure. X-ray diffraction results show that the preferred orientation of Ti 1 − x − y Al x Ta y N coatings changes from (111) to (200) with increasing Ta content. Nanoindention results indicate that the hardness of the coatings sharply increases from 11 GPa without Ta to 31.2 GPa at y = 0.21. Solution strengthening caused by doping Ta is the main reason for the rapid increase of hardness. After oxidation in ambient air, Ti 0·44 Al 0.56 N coating is fully oxidized to α-TiO 2 and γ-TiO 2 at 600 °C. A significant increase of oxidation resistance for Ti 0·37 Al 0.42 Ta 0.21 N coating has been observed at 800 °C. However, a higher Ta content ( y = 0.37) is not conducive to retard the formation of α-TiO 2 phase at low temperature, but will increase lattice distortion. This can make the coating easy to spall during further oxidation. [ABSTRACT FROM AUTHOR]

Research on the relationship of microstructure and properties of coated tools such as TiAlN and TiAlSiN plays a key role in obtaining the needed cutting performance in titanium machining. In this study, three kinds of coatings of TiAlN, TiAlSiN monolayer and TiAlN/TiAlSiN composite multilayer have been fabricated by magnetron sputtering method. It is found that the coating structure changes from columnar growth to nanocrystal growth by doping Si element. The TiAlN/TiAlSiN coating is composed by a coarse columnar TiAlN bottom layer and a fine nanocrystalline TiAlSiN top layer. Premature spalling problem (Lc2) is improved by forming the TiAlN/TiAlSiN multilayer structure. Titanium cutting experiment shows that the major wear mechanism of these coated tools is adhesive wear and chipping. The TiAlSiN coated tool has the longest cutting distance at various cutting speeds in these three kinds of coatings. This is because less built-up edge and chipping are generated at the cutting edge due to the dense nanocrystal structure, high hardness and good oxidation resistance of TiAlSiN coating. Therefore, the TiAlSiN coating with dense structure, high hardness and good oxidation resistance is recommended to use in high speed turning titanium. [ABSTRACT FROM AUTHOR]

Rotational speed has an important influence on the performance of coating materials. The a-C:Ta composite coatings were prepared by controlling the substrate rotational speed during deposition process using PVD technique. The results showed that the coating transformed from dense structure to columnar structure. Due to the changes of deposition time and the vapor incident angle of the sputtering ions, the sp2 hybrid structure increased and the C–Ta bonds contents decreased as a function of the rotational speed, which led to the improvement of adhesion force. The average friction coefficient of the composite coatings did not fluctuate significantly for the amorphous carbon matrix and the transfer films formed during friction, while the wear rates were gradually increased. The sample at 0.5 rpm possessed the lowest wear rate, which was mainly associated with the cooperative behavior of the dense structure and the formation of TaC nanoclusters in the composite coating. [ABSTRACT FROM AUTHOR]

The (CrAlTiNbV)N x coatings are fabricated by controlling the substrate bias via magnetron sputtering method. Under low substrate bias, the coating tends to form a loose columnar crystal structure with (200) preferred orientation. However, when the substrate bias increases, the coating transforms into a dense nanocrystalline structure, and the (111) orientation is enhanced. As the substrate bias increases, the residual stress and hardness of the coating gradually increase, while the adhesion strength decreases slightly. Friction tests show that the coating possesses the lowest average friction coefficient (about 0.06) and wear rate (8.7 × 10-9 mm3/N·m) in 4050# aviation lubricant, which is achieved under the substrate bias of -96 V and -126 V, respectively. [ABSTRACT FROM AUTHOR]