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Biochar prepared from crop straw is an economical method for adsorbing bromocresol green (BCG) from textile industrial wastewater. However, there is limited research on the adsorption mechanism of biochar for the removal of BCG. This study utilized cucumber straw as raw material to prepare biochar with good adsorption potential and characterized its physicochemical properties. Through adsorption experiments, the effects of solution pH, biochar dosage, and initial dye concentration on adsorption performance were examined. The adsorption mechanism of cucumber straw biochar (CBC) for BCG was elucidated at the molecular level using adsorption kinetics, adsorption isotherm models, and density functional theory (DFT) calculations. Results show that the specific surface area of the CBC is 101.58 m2/g, and it has a high degree of carbonization, similar to the structure of graphite crystals. The presence of aromatic rings, –OH groups, and –COOH groups in CBC provides abundant adsorption sites for BCG. The adsorption process of CBC for BCG is influenced by both physical and chemical adsorption, and can be described by the Langmuir isotherm model, indicating a monolayer adsorption process. The theoretical maximum monolayer adsorption capacity (qm) of BCG at 298 K was calculated to be 99.18 mg/g. DFT calculations reveal interactions between BCG and CBC involving electrostatic interactions, van der Waals forces, halogen–π interactions, π–π interactions, and hydrogen bonds. Additionally, the interaction of hydrogen bonds between BCG and the –COOH group of biochar is stronger than that between BCG and the –OH group. These findings provide valuable insights into the preparation and application of efficient organic dye adsorbents. [ABSTRACT FROM AUTHOR]

Aqueous zinc−ion batteries (ZIBs) are widely recognized as highly promising energy storage devices because of their inherent characteristics, including superior safety, affordability, eco−friendliness, and various other benefits. However, the significant corrosion of the zinc metal anode, side reactions occurring between the anode and electrolyte, and the formation of zinc dendrites significantly hinder the practical utilization of ZIBs. Herein, we utilized an electrodeposition method to apply a unique hydrous molybdenum oxide (HMoOx) layer onto the surface of the zinc metal anode, aiming to mitigate its corrosion and side reactions during the process of zinc deposition and stripping. In addition, the HMoOx layer not only improved the hydrophilicity of the zinc anode, but also adjusted the migration of Zn2+, thus facilitating the uniform deposition of Zn2+ to reduce dendrite formation. A symmetrical cell with the HMoOx−Zn anode displayed reduced−voltage hysteresis (80 mV at 2.5 mA/cm2) and outstanding cycle stability after 3000 cycles, surpassing the performance of the uncoated Zn anode. Moreover, the HMoOx−Zn anode coupled with a γ−MnO2 cathode created a considerably more stable rechargeable full battery compared to the bare Zn anode. The HMoOx−Zn||γ−MnO2 full cell also displayed excellent cycling stability with a charge/discharge−specific capacity of 129/133 mAh g−1 after 300 cycles. In summary, this research offers a straightforward and advantageous approach that can significantly contribute to the future advancements in rechargeable ZIBs. [ABSTRACT FROM AUTHOR]

In this study, an efficient visible light responsive MIL-125(Ti)/ZnIn2S4 hybrid structure (MIL-1.2/ZIS) was synthesized through two-step method with improved photocatalytic H2-evolution performance. The MIL-1.2/ZIS nanocomposites could retained the characteristic features including the highly surface area of metal organic frameworks and the hierarchical sheet-like structure of ZnIn2S4. The optimal sample could exhibit the H2 generation rate of 873.4 μmol g−1·h−1, and the improved photocatalytic activity could be ascribed to the well-matched band structure and the formation of hybrid interfaces, which could lead to the effective charge transfer and separation of photo-excited electron–hole pairs. We hope this paper could broad the potential utilization of MOF-based nanocomposites in photocatalytic energy conversion fields. [ABSTRACT FROM AUTHOR]

A study of self-association of alcohols in carbon tetrachloride is investigated. Multivariate curve resolution in the near-infrared region is used for this purpose.

Aqueous zinc-ion batteries (ZIBs) are widely recognized as highly promising energy storage devices because of their inherent characteristics, including superior safety, affordability, eco-friendliness, and various other benefits. However, the significant corrosion of the zinc metal anode, side reactions occurring between the anode and electrolyte, and the formation of zinc dendrites significantly hinder the practical utilization of ZIBs. Herein, we utilized an electrodeposition method to apply a unique hydrous molybdenum oxide (HMoO x ) layer onto the surface of the zinc metal anode, aiming to mitigate its corrosion and side reactions during the process of zinc deposition and stripping. In addition, the HMoO x layer not only improved the hydrophilicity of the zinc anode, but also adjusted the migration of Zn 2+ , thus facilitating the uniform deposition of Zn 2+ to reduce dendrite formation. A symmetrical cell with the HMoO x -Zn anode displayed reduced-voltage hysteresis (80 mV at 2.5 mA/cm 2 ) and outstanding cycle stability after 3000 cycles, surpassing the performance of the uncoated Zn anode. Moreover, the HMoO x -Zn anode coupled with a γ-MnO 2 cathode created a considerably more stable rechargeable full battery compared to the bare Zn anode. The HMoO x -Zn||γ-MnO 2 full cell also displayed excellent cycling stability with a charge/discharge-specific capacity of 129/133 mAh g -1 after 300 cycles. In summary, this research offers a straightforward and advantageous approach that can significantly contribute to the future advancements in rechargeable ZIBs.