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Self-healing fabrics have garnered a lot of attention due to their recovering functionality upon damage. This work describes a facile technique for developing a novel self-healing coating with the goal of producing autonomous intrinsic self-healing fabrics that can recover from damage at room temperature without the use of external stimuli. The coating was developed using natural rubber latex (NRL) and consisted of a dynamic reversible metal thiolate ionic network. The formation of the reversible ionic network was assessed by Differential Scanning Calorimetry (DSC), Ultraviolet-visible spectroscopy (UV-vis), Fourier Transform Infrared (FTIR) and zeta potential analysis. Scanning electron microscope (SEM) images revealed that the coating impregnated the fibres of the fabric and improved their structural integrity. The morphology of the punctured area revealed that intermolecular diffusion had occurred during the recovery and the sample had completely healed. The results also showed that the tensile strength, tear strength and puncture strength of the fabric achieved 100% healing efficiency when the damaged fabrics were brought into contact with each other and allowed to be healed at room temperature. This technology is expected to open up a new avenue in the textile industry.

Natural rubber latex foam (NRLF) based on kenaf core and bast were prepared by using the Dunlop method. Mechanical properties, foam density, compression, hardness, thermal aging, and microstructural characteristics of kenaf-filled NRLF with different loadings of kenaf core and bast were analysed. The tensile strength, elongation at break, and compressive strength of kenaf bast filled NRLF samples decreased as the content of kenaf was increased. However, the modulus at 100%, hardness, and density of NRLF increased with increasing kenaf contents. The addition of kenaf core into NRLF increased the swelling percentage and aging of the foam compared to the bast. Scanning electron microscopy (SEM) results indicated that the fibrous kenaf bast had a stronger adhesion compared to the particulate kenaf core, resulting in higher tensile strength, elongation at break, and compression strength.

Generally, the compression ignition (CI) engine that runs with emulsified biofuel (EB) or higher viscosity fuel experiences inferior performance and a higher emission compared to petro diesel engines. The modification is necessary to standard engine level in order to realize its application. This paper proposes a guide vane design (GVD), which needs to be installed in the intake manifold, is incorporated with shallow depth re-entrance combustion chamber (SCC) pistons. This will organize and develop proper in-cylinder airflow to promote better diffusion, evaporation and combustion processes. The model of GVD and SCC piston was designed using SolidWorks 2017, while ANSYS Fluent version 15 was utilized to run a 3D analysis of the cold flow IC engine. In this research, seven designs of GVD with the number of vanes varied from two to eight vanes (V2&ndash, V8) are used. The four-vane model (V4) has shown an excellent turbulent flow as well as swirl, tumble and cross tumble ratios in the fuel-injected region compared to other designs. This is indispensable to break up heavier fuel molecules of EB to mix with the air that will eventually improve engine performance.

In this work, the feasibility of converting dead leaf biomass into green activated carbon for use as a reinforcement filler in natural rubber composites was assessed. The dead leaf activated carbon (DLAC) was prepared by pyrolysis at 550, 700, 900, and 1000 degrees C at a heating rate of 10 degrees C min(-1) under nitrogen gas flow of 100 cm(3) min(-1) and was activated by CO2 gas at the same flow rate when the pyrolysis temperature was reached. The properties of DLACs were characterized by particle size analysis, density, scanning electron microscopy, elemental energydispersive X-ray spectroscopy and Raman spectroscopy. The results revealed that the DLAC obtained by pyrolysis at 1000 degrees C had a small particle size of 28.86 tint; a highly porous structure; high carbon purity, at 82.58%; and a low density, at 1.588 g cm(-3). The effect of different DLAC contents (5, 10, and 15 phr) on the curing properties and the physical and mechanical performance of the rubber composites was investigated and compared with rubber composites containing carbon black (CB). The results showed that the addition of DLAC increased the maximum torque and reduced the scorch and cure times. The tensile strength for rubber composites containing 15 phr of DLAC increased by 8%, the M100 and M300 improved 40%, and the elongation at break and crosslink density decreased by approximately 5% and 24%, respectively. The studied DLAC is a promising, cost-effective alternative to commercial carbon black for improving the performance of rubber composites. Funding Agencies|Universiti Sains Malaysia under Research University Incentive (RUI) [1001/PBAHAN/8014138]

This research aims to investigate the influence of bed temperatures on various acrylonitrile butadiene styrene copolymer (ABS) parts produced from Fused Deposition Modeling (FDM). The Printing process was conducted at a fixed nozzle temperature of 240°C while bed temperatures were varied from 90°C, 100°C and 110°C. Part shapes were varied accordingly to examine warpage, shrinkage and density due to variation of part thicknesses separately. Changes in the glass transition temperature of ABS printed parts with different bed temperatures were examined using Differential Scanning Calorimetry (DSC). It was found that the warpage and shrinkage reduced with increasing bed temperature due to the reduction of thermal stress with a higher glass transition temperature of printed samples compared with its filament. The thin sample indicated pronounced shrinkage compared with thick sample due to lower thermal contraction in the thicker sample but the former was less affected by the variation of bed temperature. Samples of different heights with fixed infill density indicated variations of the trend of density with different bed temperatures.

An intrinsic self-healing natural rubber featuring reversible metal-thiolate ion networks was fabricated and the corresponding healing mechanism and mechanical properties were presented. The developed materials were able to repair themselves at room temperature upon damage without any external stimuli. Reversible metal-thiolate ion networks were proven to form within the rubber material. These networks dominated the cross-linking system and were identified by Differential Scanning Calorimetry (DSC) and Fourier-transform Infrared Spectroscopy (FTIR). Meanwhile, the quantitative amount of metal-thiolate ion networks and covalent crosslinks was determined by swelling testing. Scanning Electron Microscopy (SEM) results revealed that intermolecular diffusion had occurred at the fracture area of the self-healing samples. The results revealed that the mechanical properties could be 100% regenerated after the broken samples were brought into contact with each other. It was also found that self-healing increased by 60% of the material lifespan. This new material is expected to open up promising avenues for the manufacturing of sustainable rubber products.

The heat evolved during setting of class C fly ash geopolymers with different molarity of sodium hydroxide are discussed. The reaction kinetics and microstructure properties of geopolymers are studied towards the early strength development. Differential Scanning Calorimeter was applied to determine the heat evolved and Johnson-Mehl-Avrami-Kolmogrov Model was used to analyse the reaction kinetics during setting of the geopolymers. Morphology and strength development were monitored. The results revealed that the heat evolved increased proportionally with increasing molarity of sodium hydroxide. This indicated rapid reaction of geopolymerization due to the increasing of hydroxide ion content thus mainly affect dissolution process. It was also found that the geopolymerization during setting was governed by one-dimensional growth with instantaneous heterogeneous nucleation and this was supported by the morphology of the geopolymers observed. Among the activator molarities, the molarity of 12 (12M) was observed to be most influential based on its highest compressive strength (up to 46MPa at 7-days) and supported by the morphology properties results.

The objective of this study was to compare the physical and mechanical performance of poly(lactic acid) (PLA), acrylonitrile butadiene styrene (ABS), and nylon 6 fabricated using fused deposition modeling (FDM) and conventional injection molding. It is found that different processing methods did not affect the viscosity of the samples, and the percentage difference for the density measurement is less than 4%. Water absorption of FDM samples is approximately 108% higher compared to those fabricated using the injection molding. The results also revealed that the FDM method did not strongly affect the degree of crystallinity of ABS, but it increased the degree of crystallinity of PLA and nylon 6. The tensile strength, Young's modulus, elongation at break, and impact strength of FDM samples were approximately 48%, 50%, 48%, and 78%, lower compared with the injection molded samples. The results presented can provide a guide to manufacturing the final products using FDM with the desired performance.

Geopolymerization consists of several chemical reactions that has been reported widely as an exothermic reaction. Previous studies on heat released during geopolymerization used metakaolin and fly ash of F class as a precursor for geopolymer. Meanwhile, in this study, fly ash of C class is used and a preliminary study has been conducted on determining the exothermic reaction of the geopolymerization with various ratios of solid-to-liquid ranging from 1.5 to 2.5. The amount of heat released was determined by using Differential Scanning Calorimeter. It was proven that different solid-to-liquid ratio affected the amount of heat released during geopolymerization as the highest amount of the heat released were recorded at the optimum solid-to-liquid ratio of 2.0.

In this study, magnetorheological elastomers (MREs) based on iron sand and natural rubber were prepared. The Taguchi method was employed to investigate the effect of a number of factors, namely, the iron sand content, iron sand particle size, and applied magnetic field during curing on the loss tangent (tan δ) and energy dissipated during cyclic loading. Tan δ was measured through dynamic mechanical analysis over a range of frequency (0.01–130 Hz), strain amplitude (0.1–4.5%), and temperature (−100 to 50°C). The energy dissipated was measured with a universal tester under cyclic tensile loading. The data were then statistically analyzed to predict the optimal combination of factors, and finally, experiments were conducted for verification. It was found that the iron sand content had the greatest influence on tan δ when measured over a range of frequency, and the energy dissipated during hysteresis tests. However, none of the factors showed a significant influence on tan δ when measured over a range of strain amplitude. Furthermore, the iron sand content and magnetic field were also found to influence the width of the peak in tan δ as a function of the temperature. The morphological characteristics of the MREs were also examined with scanning electron microscopy. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41506.