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The water-splitting capability of Photosystem II (PSII) of plants and green algae requires the system to balance efficient light harvesting along with effective photoprotection against excitation in excess of the photosynthetic capacity, particularly under the naturally fluctuating sunlight intensity. The comparatively flat energy landscape of the multicomponent structure, inferred from the spectra of the individual pigment-protein complexes and the rather narrow and featureless absorption spectrum, is well known. However, how the combination of the required functions emerges from the interactions among the multiple components of the PSII supercomplex (PSII-SC) cannot be inferred from the individual pigment-protein complexes. In this work, we investigate the energy transfer dynamics of the C2S2-type PSII-SC with a combined spectroscopic and modeling approach. Specifically, two-dimensional electronic-vibrational (2DEV) spectroscopy provides enhanced spectral resolution and the ability to map energy evolution in real space, while the quantum dynamical simulation allows complete kinetic modeling of the 210 chromophores. We demonstrate that additional pathways emerge within the supercomplex. In particular, we show that excitation energy can leave the vicinity of the charge separation components, the reaction center (RC), faster than it can transfer to it. This enables activatable quenching centers in the periphery of the PSII-SC to be effective in removing excessive energy in cases of overexcitation. Overall, we provide a quantitative description of how the seemingly contradictory functions of PSII-SC arise from the combination of its individual components. This provides a fundamental understanding that will allow further improvement of artificial solar energy devices and bioengineering processes for increasing crop yield.

Histidine can be protonated on either or both of the two N atoms of the imidazole moiety. Each of the three possible forms occurs as a result of the stereochemical environment of the histidine side chain. In an atomic model, comparing the possible protonation states in situ, looking at possible hydrogen bonding and metal coordination, it is possible to predict which is most likely to be correct. A more direct method is described that uses quantum-mechanical methods to calculate, also in situ, the minimum geometry and energy for comparison, and therefore to more accurately identify the most likely protonation state.

Studying noncommuting conserved quantities, or 'charges,' has revealed a conceptual puzzle: noncommuting charges hinder thermalization in some ways yet promote it in others. While many quantum systems thermalize according to the Eigenstate Thermalization Hypothesis (ETH), systems with 'dynamical symmetries' violate the ETH and exhibit non-stationary dynamics, preventing them from equilibrating, much less thermalizing. We demonstrate that each pair of dynamical symmetries corresponds to a specific charge. We find that introducing new charges that do not commute with existing ones disrupts these symmetries, thereby eliminating non-stationary dynamics and facilitating thermalization. We illustrate this behavior across various models, including the Hubbard model and Heisenberg spin chains. Our findings demonstrate that noncommuting charges can enhance thermalization by reducing the number of local observables that thermalize according to the ETH. Noncommuting charges pose a puzzle: they hinder thermalization in some ways yet promote it in others. Here, the authors demonstrate how noncommuting charges enhance thermalization by reducing the number of local observables that thermalize. [ABSTRACT FROM AUTHOR]

The first experimental observation of entangled visible light was achieved by optically exciting free atoms of calcium and detecting pairs of photons emitted in a two-stage cascade. The polarizations of the entangled photons were observed to be correlated, in agreement with quantum theory. This review describes the rationale, methodology, challenges, and results, including experimental details not previously published. [ABSTRACT FROM AUTHOR]

Computing the Casimir force and energy between objects is a classical problem of quantum theory going back to the 1940s. Several different approaches have been developed in the literature often based on different physical principles. Most notably a representation of the Casimir energy in terms of determinants of boundary layer operators makes it accessible to a numerical approach. In this paper, we first give an overview of the various methods and discuss the connection to the Krein-spectral shift function and computational aspects. We propose variants of Krylov subspace methods for the computation of the Casimir energy for large-scale problems and demonstrate Casimir computations for several complex configurations. This allows for Casimir energy calculation for large-scale practical problems and significantly speeds up the computations in that case. [ABSTRACT FROM AUTHOR]

The dynamics of quantum systems coupled to baths are typically studied using the Nakajima-Zwanzig memory kernel (K ) or the influence functions (I), particularly when memory effects are present. Despite their significance, formal connections between the two have not been explicitly known. We establish their connections by examining the system propagator for a N-level system linearly coupled to Gaussian baths with various types of system-bath coupling. For a certain class of problems, we devised a non-perturbative, diagrammatic approach to construct K from I for (driven) systems interacting with Gaussian baths, bypassing conventional projection-free dynamics inputs. Our work provides a way to interpret approximate path integral methods in terms of approximate memory kernels. Moreover, it offers a Hamiltonian learning procedure to extract the bath spectral density from reduced system trajectories, opening new avenues in quantum sensing and engineering. The insights we provide advance our understanding of non-Markovian dynamics and will serve as a stepping stone for future theoretical and experimental developments in this area. The Feynman-Vernon Path Integral and the Generalized Quantum Master Equation are the two main and oldest approaches to open quantum system dynamics modelling. Here, the authors discover a formal link between them, and use it to find a Hamiltonian learning method that can extract environmental spectral densities from the dynamics of the reduced system. [ABSTRACT FROM AUTHOR]

Lasing in the bad-cavity regime has promising applications in quantum precision measurement and frequency metrology due to the reduced sensitivity of the laser frequency to cavity-length fluctuations. Thus far, relevant studies have been mainly focused on conventional cavities whose finesse is high enough that the resonance linewidth is sufficiently narrow compared to the cavity's free spectral range, though still in the bad-cavity regime. However, lasing output from the cavity whose finesse is close to the limit of 2 has never been experimentally accessed. Here, we demonstrate an extremely bad-cavity laser, analyze the physical mechanisms limiting cavity finesse, and report on the worst-ever laser cavity with finesse reaching 2.01. The optical cavity has a reflectance close to zero and only provides weak optical feedback. The laser power can be as high as tens of μW and the spectral linewidth reaches a few kHz, over one thousand times narrower than the gain bandwidth. In addition, the measurement of cavity pulling reveals a pulling coefficient of 0.0148, the lowest value ever achieved for a continuous-wave laser. Our findings open up an unprecedentedly innovative perspective for future new ultra-stable lasers, which could possibly trigger future discoveries in optical clocks, cavity QED, continuous-wave superradiant laser, and explorations of quantum many-body physics. [ABSTRACT FROM AUTHOR]

Periodically driven quantum systems exhibit a diverse set of phenomena but are more challenging to simulate than their equilibrium counterparts. Here, we introduce the Quantum High-Frequency Floquet Simulation (QHiFFS) algorithm as a method to simulate fast-driven quantum systems on quantum hardware. Central to QHiFFS is the concept of a kick operator which transforms the system into a basis where the dynamics is governed by a time-independent effective Hamiltonian. This allows prior methods for time-independent simulation to be lifted to simulate Floquet systems. We use the periodically driven biaxial next-nearest neighbor Ising (BNNNI) model, a natural test bed for quantum frustrated magnetism and criticality, as a case study to illustrate our algorithm. We implemented a 20-qubit simulation of the driven two-dimensional BNNNI model on Quantinuum's trapped ion quantum computer. Our error analysis shows that QHiFFS exhibits not only a cubic advantage in driving frequency ω but also a linear advantage in simulation time t compared to Trotterization. [ABSTRACT FROM AUTHOR]

Excitation energy transfer (EET) is a key photoinduced process in biological chromophoric assemblies. Here we investigate the factors which can drive EET into efficient ultrafast sub-ps regimes. We demonstrate how a coherent transport of electronic population could facilitate this in water solvated NADH coenzyme and uncover the role of an intermediate dark charge-transfer state. High temporal resolution ultrafast optical spectroscopy gives a 54±11 fs time constant for the EET process. Nonadiabatic quantum dynamical simulations computed through the time-evolution of multidimensional wavepackets suggest that the population transfer is mediated by photoexcited molecular vibrations due to strong coupling between the electronic states. The polar aqueous solvent environment leads to the active participation of a dark charge transfer state, accelerating the vibronically coherent EET process in favorably stacked conformers and solvent cavities. Our work demonstrates how the interplay of structural and environmental factors leads to diverse pathways for the EET process in flexible heterodimers and provides general insights relevant for coherent EET processes in stacked multichromophoric aggregates like DNA strands. Excitation energy transfer is important for many photoinduced biological processes in systems with multiple chromophores. Here, the authors elucidate this process for the coenzyme NADH using ultrafast spectroscopy and quantum dynamics. [ABSTRACT FROM AUTHOR]

We introduce an algorithm to compute expectation values of time-evolved observables on digital quantum computers that requires only bounded average circuit depth to reach arbitrary precision, i.e. produces an unbiased estimator with finite average depth. This finite depth comes with an attenuation of the measured expectation value by a known amplitude, requiring more shots per circuit. The average gate count per circuit for simulation time t is O ( t 2 μ 2 ) with μ the sum of the Hamiltonian coefficients, without dependence on precision, providing a significant improvement over previous algorithms. With shot noise, the average runtime is O ( t 2 μ 2 ϵ − 2 ) to reach precision ϵ. The only dependence in the sum of the coefficients makes it particularly adapted to non-sparse Hamiltonians. The algorithm generalizes to time-dependent Hamiltonians, appearing for example in adiabatic state preparation. These properties make it particularly suitable for present-day relatively noisy hardware that supports only circuits with moderate depth. [ABSTRACT FROM AUTHOR]

Among azobenzene derivatives, azothiophenes represent a relatively recent family of compounds that exhibit similar characteristics as dyes and photoreactive systems. Their technological applications are extensive thanks to the additional design flexibility conferred by the heteroaromatic ring. In this study, we present a comprehensive investigation of the structural and electronic properties of novel dyes derived from 3-thiophenamine, utilizing a multilevel approach. We thoroughly examined the potential energy surfaces of the E and Z isomers for three molecules, each bearing different substituents on the phenyl ring at the para position relative to the diazo group. This exploration was conducted through quantum chemistry calculations at various levels of theory, employing a continuum solvent model. Subsequently, we incorporated an explicit solvent (a dimethyl sulfoxide–water mixture) to simulate the most stable isomers using classical molecular dynamics, delivering a clear picture of the local solvation structure and intermolecular interactions. Finally, a hybrid quantum mechanics/molecular mechanics (QM/MM) approach was employed to accurately describe the evolution of the solutes' properties within their environment, accounting for finite temperature effects. [ABSTRACT FROM AUTHOR]

Food and life are intimately entangled. To grasp the underlying complexity of this seemingly simple statement, this article first introduces the approach to food/eating as an assemblage enacted by various heterogeneous components, and further develops it by engaging with actor network theory and material semiotics. Thereafter the focus turns to 'entanglement', as inspired by quantum physics, to elicit the basic dynamics of the entanglement of food and more-than-human beings, conceived of as involving mutual and differential becomings within and among assemblages. The article illustrates these entangled becomings by drawing upon examples from Sri Lanka, which in an intercultural philosophical fashion serve to establish an articulation (in the sense of a connection) between the proposed abstract approach to food and some basic premises of Buddhism and Ayurveda, a South Asian health system. Overall, the article crafts a conceptual toolbox and performs ontological groundwork wherein food and human beings as entangled assemblages provide a productive, refined, and sensitive research apparatus for the intimate study of more-than-human life and organization while also spurring novel theorizations through food/eating. [ABSTRACT FROM AUTHOR]

This article outlines a novel interpretation of quantum theory: the Q-based interpretation. The core idea underlying this interpretation, recently suggested for quantum field theories by Drummond and Reid, is to interpret the phase space function Q —a transform of the better known Wigner function—as a proper probability distribution, roughly analogous to the probability distribution ρ in classical statistical mechanics. Here I motivate the Q-based interpretation, investigate whether it is empirically adequate, and outline some of its key conceptual features. I argue that the Q-based interpretation is attractive in that it promises having no measurement problem, is conceptually parsimonious, and has the potential to apply elegantly to relativistic and field-theoretic contexts. [ABSTRACT FROM AUTHOR]

I address the recent debate between Alexander Meehan and Lev Vaidman concerning the claim made by the former for a new problem to quantum mechanics. I argue that while Meehan's incompatibility claim does hold in the situation he presents, it does not genuinely involve considerations that can limit quantum state preparation, nor does it introduce new constrains over possible interpretations of quantum theory. [ABSTRACT FROM AUTHOR]

Quantum theory is a fundamental part of contemporary science. But some recent arguments have been taken to show that if this theory is universally applicable then the outcome of a quantum measurement is not an objective fact. They motivate the more general reappraisal of the notions of fact and objectivity that I offer here. I argue that if quantum theory is universally applicable the facts about the physical world include a fact about each quantum measurement outcome. The physical facts may lack an ideal kind of objectivity, but their more modest objectivity is all that science needs. [ABSTRACT FROM AUTHOR]

This document provides a historical overview of the development of the concept of intrinsic angular momentum, or "spin," of the photon. It discusses the contributions of Bose and Einstein in postulating the spin of the photon and the quantization of energy, momentum, and angular momentum in particles and atoms. The document also explores the understanding of field energy and momentum in physics, including the arguments made by Maxwell, Thomson, and Heaviside. It further discusses the electromagnetic momentum density and the transfer of field angular momentum to mechanical angular momentum. Additionally, the document mentions the Feynman disk paradox and the quantization of angular momentum. [Extracted from the article]

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Entanglement and interference are both hallmark effects of quantum physics. Particularly rich dynamics arise when multiple (at least partially) indistinguishable particles are subjected to either of these phenomena. By combining both entanglement and many-particle interference, we propose an interferometric setting through which N-particle interference can be observed, while any interference of lower orders is strictly suppressed. We experimentally demonstrate this effect in a four-photon interferometer, where the interference is nonlocal, in principle, as only pairs of photons interfere at two separate and independent beam splitters. A joint detection of all four photons identifies a high-visibility interference pattern varying as a function of their collective four-particle phase, a genuine four-body property. [ABSTRACT FROM AUTHOR]

Characterizing the nature of hydrodynamical transport properties in quantum dynamics provides valuable insights into the fundamental understanding of exotic non-equilibrium phases of matter. Experimentally simulating infinite-temperature transport on large-scale complex quantum systems is of considerable interest. Here, using a controllable and coherent superconducting quantum simulator, we experimentally realize the analog quantum circuit, which can efficiently prepare the Haar-random states, and probe spin transport at infinite temperature. We observe diffusive spin transport during the unitary evolution of the ladder-type quantum simulator with ergodic dynamics. Moreover, we explore the transport properties of the systems subjected to strong disorder or a tilted potential, revealing signatures of anomalous subdiffusion in accompany with the breakdown of thermalization. Our work demonstrates a scalable method of probing infinite-temperature spin transport on analog quantum simulators, which paves the way to study other intriguing out-of-equilibrium phenomena from the perspective of transport. Quantum devices offer the potential to simulate quantum phenomena, which are otherwise computationally intractable. Here, Shi, Sun, Wang and coauthors use a superconducting quantum simulator to study spin-transport at infinite temperature. [ABSTRACT FROM AUTHOR]

Advances in attosecond spectroscopy have enabled tracing and controlling the electron motion dynamics in matter, although they have yielded insufficient information about the electron dynamic in the space domain. Hence, ultrafast electron and x-ray imaging tools have been developed to image the ultrafast dynamics of matter in real time and space. The cutting-edge temporal resolution of these imaging tools is on the order of a few tens to a hundred femtoseconds, limiting imaging to the atomic dynamics and leaving electron motion imaging out of reach. Here, we obtained the attosecond temporal resolution in the transmission electron microscope, which we coined "attomicroscopy." We demonstrated this resolution by the attosecond diffraction measurements of the field-driven electron dynamics in graphene. This attosecond imaging tool would provide more insights into electron motion and directly connect it to the structural dynamics of matter in real-time and space domains, opening the door for long-anticipated real-life attosecond science applications in quantum physics, chemistry, and biology. [ABSTRACT FROM AUTHOR]

Molecular imprinting is a promising approach for developing polymeric materials as artificial receptors. However, only a few types of molecularly imprinted polymers (MIPs) are commercially available, and most research on MIPS is still in the experimental phase. The significant limitation has been a challenge for screening imprinting systems, particularly for weak functional target molecules. Herein, a combined method of quantum mechanics (QM) computations and molecular dynamics (MD) simulations was employed to screen an appropriate 2,4-dichlorophenoxyacetic acid (2,4-D) imprinting system. QM calculations were performed using the Gaussian 09 software. MD simulations were conducted using the Gromacs2018.8 software suite. The QM computation results were consistent with those of the MD simulations. In the MD simulations, a realistic model of the 'actual' pre-polymerisation mixture was obtained by introducing numerous components in the simulations to thoroughly investigate all non-covalent interactions during imprinting. This study systematically examined MIP systems using computer simulations and established a theoretical prediction model for the affinity and selectivity of MIPs. The combined method of QM computations and MD simulations provides a robust foundation for the rational design of MIPs. [ABSTRACT FROM AUTHOR]

For nearly one hundred years most quantum-mechanics texts have depicted a continuous, spin-direction superposition of the wavefunction of the silver atom traversing a Stern–Gerlach (S–G) magnet. But there are sound scientific arguments which deny that understanding. Schrodinger's equation for that continuous wavefunction development cannot describe the transfer of energy from the magnetic field to that atom. Modern micro-fabrication techniques now make it possible to implement a simple, accessible experiment testing whether a spin superposition does continue in the magnet. Because the S–G experiment is the prototype for quantum measurement, that observation is crucial to implementing a realistic quantum theory of measurement. [ABSTRACT FROM AUTHOR]

This paper introduces a novel and efficient technique for quantum state estimation, coined as low-rank matrix-completion quantum state tomography for characterizing pure quantum states, as it requires only non-entangling bases and 2 n + 1 local Pauli operators. This significantly reduces the complexity of the process and increases the accuracy of the state estimation, as it eliminates the need for the entangling bases, which are experimentally difficult to implement on quantum devices. The required minimal post-processing, improved accuracy and efficacy of this matrix-completion-based method make it an ideal benchmarking tool for investigating the properties of quantum systems, enabling researchers to verify the accuracy of quantum devices, characterize their performance, and explore the underlying physics of quantum phenomena. Our numerical results demonstrate that this method outperforms contemporary techniques in its ability to accurately reconstruct multi-qubit quantum states on real quantum devices, making it an invaluable contribution to the field of quantum state characterization and an essential step toward the reliable deployment of intermediate- and large-scale quantum devices. [ABSTRACT FROM AUTHOR]

The detection of gravitational waves in 2015 ushered in a new era of gravitational wave (GW) astronomy capable of probing the strong field dynamics of black holes and neutron stars. It has opened up an exciting new window for laboratory and space tests of Einstein's theory of classical general relativity (GR). In recent years, two interesting proposals have aimed to reveal the quantum nature of perturbative gravity: (1) theoretical predictions on how graviton noise from the early universe, after the vacuum of the gravitational field was strongly squeezed by inflationary expansion; (2) experimental proposals using the quantum entanglement between two masses, each in a superposition (gravitational cat, or gravcat) state. The first proposal focuses on the stochastic properties of quantum fields (QFs), and the second invokes a key concept of quantum information (QI). An equally basic and interesting idea is to ask whether (and how) gravity might be responsible for a quantum system becoming classical in appearance, known as gravitational decoherence. Decoherence due to gravity is of special interest because gravity is universal, meaning, gravitational interaction is present for all massive objects. This is an important issue in macroscopic quantum phenomena (MQP), underlining many proposals in alternative quantum theories (AQTs). To fully appreciate or conduct research in these exciting developments requires a working knowledge of classical GR, QF theory, and QI, plus some familiarity with stochastic processes (SPs), namely, noise in quantum fields and decohering environments. Traditionally a new researcher may be conversant in one or two of these four subjects: GR, QFT, QI, and SP, depending on his/her background. This tutorial attempts to provide the necessary connective tissues between them, helping an engaged reader from any one of these four subjects to leapfrog to the frontier of these interdisciplinary research topics. In the present version, we shall address the three topics listed in the title, excluding gravitational entanglement, because, despite the high attention some recent experimental proposals have received, its nature and implications in relation to quantum gravity still contain many controversial elements. [ABSTRACT FROM AUTHOR]

This paper is a study of a generalization of the quantum Riemannian Hamiltonian evolution, previously analyzed by us, in the geometrization of quantum mechanical evolution in a Finsler geometry. We find results with dynamical equations governing the evolution of the trajectories defined by the expectation values of the position. The analysis appears to provide an underlying geometry described by a geodesic equation, with a connection form with a second term which is an essentially quantum effect. These dynamical equations provide a new geometric approach to the quantum evolution where we suggest a definition for "local instability" in the quantum theory. [ABSTRACT FROM AUTHOR]

Spin 1/2 quantum spin chains represent the prototypical model for coupled two-level systems. Consequently, they offer a fertile playground for both fundamental and technological applications ranging from the theory of thermalization to quantum computation. Recently, it has been shown that interesting phenomena are associated to the boundary conditions imposed on the quantum spin chains via the so-called topological frustration. In this work, we analyze the effects of such frustration on a few-spin system, with a particular focus on the strong even–odd effects induced in the ground-state energy. We then implement a topologically frustrated quantum spin chain on a quantum computer to show that our predictions are visible on current quantum hardware platforms. [ABSTRACT FROM AUTHOR]

The meaning of the quantum minimum effective length that should distinguish the quantum nature of a gravitational field is investigated in the context of manifestly covariant quantum gravity theory (CQG-theory). In such a framework, the possible occurrence of a non-vanishing minimum length requires one to identify it necessarily with a 4-scalar proper length s.It is shown that the latter must be treated in a statistical way and associated with a lower bound in the error measurement of distance, namely to be identified with a standard deviation. In this reference, the existence of a minimum length is proven based on a canonical form of Heisenberg inequality that is peculiar to CQG-theory in predicting massive quantum gravitons with finite path-length trajectories. As a notable outcome, it is found that, apart from a numerical factor of O 1 , the invariant minimum length is realized by the Planck length, which, therefore, arises as a constitutive element of quantum gravity phenomenology. This theoretical result permits one to establish the intrinsic minimum-length character of CQG-theory, which emerges consistently with manifest covariance as one of its foundational properties and is rooted both on the mathematical structure of canonical Hamiltonian quantization, as well as on the logic underlying the Heisenberg uncertainty principle. [ABSTRACT FROM AUTHOR]

A new formalism is introduced that makes it possible to elucidate the physical and geometric content of quantum space–time. It is based on the Minimum Group Representation Principle (MGRP). Within this framework, new results for entanglement and geometrical/topological phases are found and implemented in cosmological and black hole space–times. Our main results here are as follows: (i) We find the Berry phases for inflation and for the cosmological perturbations and express them in terms of the observables, such as the spectral scalar and tensor indices, n S and n T , and the tensor-to-scalar ratio r. The Berry phase for de Sitter inflation is imaginary with the sign describing the exponential acceleration. (ii) The pure entangled states in the minimum group (metaplectic) M p (n) representation for quantum de Sitter space–time and black holes are found. (iii) For entanglement, the relation between the Schmidt type representation and the physical states of the M p (n) group is found: This is a new non-diagonal coherent state representation complementary to the known Sudarshan diagonal one. (iv) Mean value generators of M p (2) are related to the adiabatic invariant and topological charge of the space–time, (matrix element of the transition − ∞ < t < ∞ ). (v) The basic even and odd n-sectors of the Hilbert space are intrinsic to the quantum space–time and its discrete levels (in particular, continuum for n → ∞ ), they do not require any extrinsic generation process such as the standard Schrodinger cat states, and are entangled. (vi) The gravity or cosmological domains on one side and another of the Planck scale are entangled. Examples: The quantum primordial trans-Planckian de Sitter vacuum and the classical late de Sitter vacuum today; the central quantum gravity region and the external classical gravity region of black holes. The classical and quantum dual gravity regions of the space–time are entangled. (vii) The general classical-quantum gravity duality is associated with the Metaplectic M p (n) group symmetry which provides the complete full covering of the phase space and of the quantum space–time mapped from it. [ABSTRACT FROM AUTHOR]

Organic–inorganic hybrid perovskite quantum dots (QDs) have garnered significant research interest owing to their unique structure and optoelectronic properties. However, their poor optical performance in ambient air remains a significant limitation, hindering their advancement and practical applications. Herein, three amino acids (valine, threonine and cysteine) were chosen as surface ligands to successfully prepare highly luminescent CH3NH3PbBr3 (MAPbBr3) QDs. The morphology and XRD results suggest that the inclusion of the amino acid ligands enhances the octahedral structure of the QD solutions. Moreover, the observed blue-shifted phenomenon in the photoluminescence (PL) aligns closely with the blue-shifted phenomenon observed in the ultraviolet–visible (UV-Vis) absorption spectra, attributed to the quantum confinement effect. The time-resolved spectra indicated that the introduction of the amino acid ligands successfully suppressed non-radiative recombination, consequently extending the fluorescence lifetime of the MAPbBr3 QDs. The photoluminescence quantum yields (PLQYs) of the amino acid-treated MAPbBr3 QDs are increased by 94.8%. The color rendering index (CRI) of the produced white light-emitting diode (WLED) is 85.3, with a correlated color temperature (CCT) of 5453 K. Our study presents a novel approach to enhancing the performance of perovskite QDs by employing specially designed surface ligands for surface passivation. [ABSTRACT FROM AUTHOR]

Following Einstein's prediction that "Physics constitutes a logical system of thought" and "Nature is the realization of the simplest conceivable mathematical ideas", this topical review outlines a formal extension of local realism limited by the speed of light to global realism with bipolar strings (GRBS) that unifies the principle of locality with quantum nonlocality. The related literature is critically reviewed to justify GRBS which is shown as a necessary and inevitable consequence of the Bell test and an equilibrium-based axiomatization of physics and quantum information science for brain–universe similarity and human-level intelligence. With definable causality in regularity and mind–light–matter unity for quantum superposition/entanglement, bipolar universal modus ponens (BUMP) in GRBS makes quantum emergence and submergence of spacetime logically ubiquitous in both the physical and mental worlds—an unexpected but long-sought simplification of quantum gravity with complete background independence. It is shown that GRBS forms a basis for quantum intelligence (QI)—a spacetime transcendent, quantum–digital compatible, analytical quantum computing paradigm where bipolar strings lead to bipolar entropy as a nonlinear bipolar dynamic and set–theoretic unification of order and disorder as well as linearity and nonlinearity for energy/information conservation, regeneration, and degeneration toward quantum cognition and quantum biology (QCQB) as well as information-conservational blackhole keypad compression and big bang data recovery. Subsequently, GRBS is justified as a real-world quantum gravity (RWQG) theory—a bipolar relativistic causal–logical reconceptualization and unification of string theory, loop quantum gravity, and M-theory—the three roads to quantum gravity. Based on GRBS, the following is posited: (1) life is a living bipolar superstring regulated by bipolar entropy; (2) thinking with consciousness and memory growth as a prerequisite for human-level intelligence is fundamentally mind–light–matter unitary QI logically equivalent to quantum emergence (entanglement) and submergence (collapse) of spacetime. These two posits lead to a positive answer to the question "If AI machine cannot think, can QI machine think?". Causal–logical brain modeling (CLBM) for entangled machine thinking and imagination (EMTI) is proposed and graphically illustrated. The testability and falsifiability of GRBS are discussed. [ABSTRACT FROM AUTHOR]

The problem of the two-dimensional motion of a charged particle with constant mass in the presence of a uniform constant perpendicular magnetic field features in several undergraduate and graduate quantum physics textbooks. This problem is very important to studies of two-dimensional materials that manifest quantum Hall behavior, as evidenced by several major discoveries over the last few years. Many real experimental samples are more complicated due to the anisotropic mass of the electrons. In this work, we provide the exact solution to this problem by means of a clever scaling of coordinates. Calculations are done for a symmetric gauge of the magnetic field. This study allows a broad audience of students and teachers to understand the mathematical techniques that lead to the solution of this quantum problem. Editor's note: The behavior of an electron confined to move in two dimensions in the presence of a perpendicular magnetic field underlies the quantum Hall effect. This is also an analytically solvable problem, so it is valuable to quantum mechanics pedagogy. This paper reviews the solution and then shows a neat trick for solving the problem when the electron's effective mass is anisotropic, a situation that is fairly common in solid-state systems. [ABSTRACT FROM AUTHOR]

From 1948 until around 1965, Louis de Broglie, awarded the Nobel Prize for Physics in 1929 for his fundamental contributions to quantum theory, pursued a systematic study of the formal analogies between wave mechanics and the thermomechanics of Boltzmann and Helmholtz. As part of this line of research, he produced several interesting observations, which were, however, published only in French, and, therefore, had a very limited diffusion. Here, we reconsider, in particular, a result of his relating to the analogy between the internal clock (de Broglie phase) of a free particle and a cyclic isothermal process in a thermomechanical system. We show that the fundamental equivalence obtained by him can be derived under more convenient hypotheses than the original ones, essentially tied to the quantization of the action exchanged by the particle with a suitable thermostat. In this emended formulation, the relations proposed by de Broglie describe the emergence of the particle proper time from a thermal background. They also suggest a specific physical meaning of the Wick rotation, often used in quantum mechanical calculations, and the thermal time that appears in it. [ABSTRACT FROM AUTHOR]

We argue that the dynamics of particle imbalance in quadratic fermionic models is, for the majority of initial many-body product states in the site occupation basis, virtually indistinguishable from the dynamics of survival probabilities of single-particle states. We then generalize our statement to a similar relationship between the non-equal time and space density correlation functions in many-body states, and the transition probabilities of single-particle states at nonzero distances. Finally, we study the equal-time connected density–density correlation functions in many-body states, which exhibit certain qualitative analogies with the survival and transition probabilities of single-particle states. Our results are numerically tested for two paradigmatic models of single-particle localization: the 3D Anderson model and the 1D Aubry–André model. This work gives an affirmative answer to the question of whether it is possible to measure features of single-particle survival and transition probabilities by the dynamics of observables in many-body states. [ABSTRACT FROM AUTHOR]

Recently, there has been substantial interest in studying the dynamics of quantum theory beyond that of states, in particular, the dynamics of channels, measurements, and higher-order transformations. Castro-Ruiz et al. pursues this using the process-matrix formalism, together with a definition of the possible dynamics of such process matrices, and focusing especially on the question of evolution of causal structures. One of its major conclusions is a strong theorem saying that within the formalism, under continuous and reversible transformations, the causal order between operations must be preserved. Our result here challenges that of Castro-Ruiz et al.: if one is to take into account a full picture of the physical evolution of operations within the standard quantum–mechanical formalism, then the conclusion of Castro-Ruiz et al. does not hold. That is, we show that under certain continuous and reversible dynamics, the causal order between operations is not necessarily preserved. We moreover identify and analyse the root of this apparent contradiction, specifically, that the commonly accepted and widely applied framework of higher-order processes, whilst mathematically sound, is not always appropriate for drawing conclusions on physical dynamics. Finally, we show how to reconcile the elements of the whole picture following the intuition based on entanglement processing by local operations and classical communication. [ABSTRACT FROM AUTHOR]

We consider a low-energy effective theory of p -branequaes in a D -dimensional spacetime, and impose two conditions: (1) the theory is scale-invariant, and (2) the electric–magnetic dual |$(D-p-4)$| -branes exist and they obey the same type of interactions to the p -branes. (We also assume other natural conditions such as Lorentz invariance but not string theory, supersymmetry, supergravity, and so on.) We then ask what values of p and D are consistent with these conditions. Using simple dimensional analysis, we find that only two solutions are possible: |$(p,D)=(2,11)$| and |$(p,D)=(2n-1,4n+2)$|⁠ , (⁠|$n=1,2,3,\cdots$|⁠). The first solution corresponds to M-theory, and the second solutions at |$n=1$| and |$n=2$| correspond to self-dual strings in little string theory and D3-branes in type IIB superstring theory, respectively, while the second solutions for |$n \ge 3$| are unknown but would be higher spin theories. Thus, quantum gravity (massless spin two theory) satisfying our two conditions would only be superstring theories, and the conditions would be strong enough to characterize superstring theories in quantum gravity. [ABSTRACT FROM AUTHOR]

This paper reviews the nature of two quasiparticles, the Majorana fermion and vison, emergent in the Kitaev model, mainly from the theoretical point of view. We demonstrate how the fractionalization of a quantum spin into these two quasiparticles occurs and clarify their properties in the presence and absence of magnetic fields. In addition to discussions on the itinerant nature inherent to Majorana fermions, the quantum dynamics of visons induced by an applied magnetic field is revealed. Fractional quasiparticles manifest themselves in temperature evolutions of thermodynamic quantities, excitation spectra, and transport properties. The formulations for them and calculation results are shown in detail. Based on the results, we present how the signatures of fractional quasiparticles appear in physical quantities. The paper also mentions the recent developments of the experimental and theoretical works of Kitaev-related systems and presents outlooks of studies on these systems. [ABSTRACT FROM AUTHOR]

A series of novel salts based on aromatic polyamines and 2,3-pyrazinedicarboxylic acid, such as C10H12N6O5 (1), C10H9ClN6O4 (2), C11H10N8O4 (3), and C14H17N16O5.5 (4) or 3,4-thiophenedicarboxylic acid, such as C10H10N4O4S (5), C10H9ClN4O4S (6), and C10H10N4O4S2 (7), were synthesized and characterized by single-crystal X-ray diffraction. All compounds crystallize in a monoclinic space group. The structure was subjected to complex Hirshfeld surface analysis, molecular electrostatic potential, enrichment ratio, and energy framework calculations. The influence of different cations on the packing of 3-carboxypyrazine-2-carboxylate and 4-carboxythiophene-3-carboxylate anions in the crystal lattice was studied. O...H/H...O interactions are the main contributor in all crystals. In addition, in a series of pyrazine-containing structures, N(C)...H/H...N(C) interactions have relevance, while in a series of thiophene-based compounds, C...H/H...C and S...H(O)/H(O)...S. In addition, Cl-based interactions are observed in compound 2. According to the enrichment ratio calculations, O...H/H...O and C...C are the most preferable interactions in all structures. The energy frameworks are dominated by the dispersive contribution, only in compound 3 is the electrostatic term dominant. The analyzed structures reveal intra- and intermolecular recurrent supramolecular synthons. In both series of crystals, the robust H-bonded centrosymmetric dimer R22(8) as homo- or as heterosynthon (in compounds 2, 3, 6, and 7) and the intramolecular synthon S(7) generated by O-H...O interactions (in compounds 2, 6, and 7) are present. The supramolecular patterns formed by π...π (C...C) and C-O(Cl,S)...C are also noticeable. Notably, a dual synthon linking the supramolecular chain via π...π interactions and the homosynthon R22(8) via N-H...N interactions is visible in both series of new salts. A library of H-bonding motifs at diverse levels of supramolecular architecture is provided. We extended the analysis of intramolecular H-bonding motifs to similar structures deposited in the Cambridge Structural Database. Another important feature is the existence of an intramolecular O...H...O bridge between two neighboring carboxylic groups as substituents in anions in compounds 3 and 5. In this context, we performed quantum theory of atoms-in-molecule calculations to reveal more details. [ABSTRACT FROM AUTHOR]

In this work, we demonstrate the use of two-photon polymerization direct laser writing in the production of continuously tuneable optical vortex beam (OV) generators in a liquid crystal (LC) layer sandwiched between glass substrates. Results are presented that show how an OV generator can be inscribed into a 20 μm-thick LC layer and how the order of the OV beam can be tuned with the application of a voltage. Importantly, only a single pair of electrodes is needed to tune the order of the vortex as the required phase profile is generated through the 3D structuring of the polymer network using the laser writing process. Following the design and fabrication of the LC-OV generator, a Mach–Zehnder interferometer is subsequently employed, in conjunction with polarizing optical microscopy, to characterize the devices to confirm the generation of OVs of different orders and to determine the corresponding chirality. The paper concludes by considering whether these LC-OV generators can function at a range of different operation wavelengths. Such devices would be of potential importance in applications ranging from optical communications to quantum physics. [ABSTRACT FROM AUTHOR]

The negatively charged silicon vacancy center ( V Si − ) in silicon carbide (SiC) is an emerging color center for quantum technology covering quantum sensing, communication, and computing. Yet, limited information currently available on the internal spin-optical dynamics of these color centers prevents us from achieving the optimal operation conditions and reaching the maximum performance especially when integrated within quantum photonics. Here, we establish all the relevant intrinsic spin dynamics of the V Si − center at cubic lattice site (V2) in 4H-SiC by an in-depth electronic fine structure modeling including the intersystem-crossing and deshelving mechanisms. With carefully designed spin-dependent measurements, we obtain all the previously unknown spin-selective radiative and non-radiative decay rates. To showcase the relevance of our work for integrated quantum photonics, we use the obtained rates to propose a realistic implementation of time-bin entangled multi-photon GHZ and cluster state generation. We find that up to three-photon GHZ or cluster states are readily within reach using the existing nanophotonic cavity technology. [ABSTRACT FROM AUTHOR]

With this work, we celebrate the 45th anniversary of the Theoretical Physics Group (GFT) of ICIMAF in two aspects: historical and scientific. The article is based in the talk given at the conference FT-45. Anecdotes of the group's influence on the author's development are presented, and the impact the group has had on the Cuban community is described. A research direction, inheriting the group's work, is presented by reviewing recent advances in the study of the landscape of effective theories derived from string theory. The exploration of string theory vacua in extra toroidal dimensions and with fluxes, using Machine Learning is described [1]. This method consists of a neural network coupled with a genetic algorithm. Additionally, the constraints on quantum gravity theories in this model are explored. In particular, the well-studied conjecture that stable de Sitter (dS) vacua do not appear in effective theories consistent with gravity is addressed. We conclude by mentioning an avenue for exploring the landscape, related to the GFT's tradition. [ABSTRACT FROM AUTHOR]

Chemical reactions between Be+ ions and H2 molecules have significance in the fields of ultracold chemistry and astrophysics, but the corresponding dynamics studies on the ground-state reaction have not been reported because of the lack of a global potential energy surface (PES). Herein, a globally accurate ground-state BeH2+ PES is constructed using the neural network model based on 18,657 ab initio points calculated by the multi-reference configuration interaction method with the aug-cc-PVQZ basis set. On the newly constructed PES, the state-to-state quantum dynamics calculations of the Be+(2S) + H2(v0 = 0; j0 = 0) and Be+(2S) + D2(v0 = 0; j0 = 0) reactions are performed using the time-dependent wave packet method. The calculated results suggest that the two reactions are dominated by the complex-forming mechanism and the direct abstraction process at relatively low and high collision energies, respectively, and the isotope substitution has little effect on the reaction dynamics characteristics. The new PES can be used to further study the reaction dynamics of the BeH2+ system, such as the effects of rovibrational excitations and alignment of reactant molecules, and the present dynamics data could provide an important reference for further experimental studies at a finer level. [ABSTRACT FROM AUTHOR]

The mechanism of selectivity in ion channels is still an open question in biology. Recent studies suggest that the selectivity filter may exhibit quantum coherence, which could help explain how ions are selected and conducted. However, environmental noise causes decoherence and loss of quantum effects. It is hoped that the effect of classical noise on ion channels can be modeled using the framework provided by quantum decoherence theory. In this paper, the behavior of the ion channel system was simulated using two models: the Spin–Boson model and the stochastic Hamiltonian model under classical noise. Additionally, using a different approach, the system's evolution was modeled as a two-level Spin–Boson model with tunneling, interacting with a bath of harmonic oscillators, based on decoherence theory. We investigated under what conditions the decoherence model approaches and deviates from the noise model. Specifically, we examined Gaussian noise and Ornstein-Uhlenbeck noise in our model. Gaussian noise shows a very good agreement with the decoherence model. By examining the results, it was found that the Spin–Boson model at a high hopping rate of potassium ions can simulate the behavior of the system in the classical noise approach for Gaussian noise. [ABSTRACT FROM AUTHOR]

The manipulation and metrology of light beams are pivotal for optical science and applications. In particular, achieving ultrahigh precision in the measurement of light beam rotations has been a long-standing challenge. Instead of using quantum probes like entangled photons, we address this challenge by incorporating a quantum strategy called "indefinite time direction" into the parameterizing process of quantum parameter estimation. Leveraging this quantum property of the parameterizing dynamics allows us to maximize the utilization of orbital angular momentum resources for measuring ultrasmall angular rotations of beam profile. Notably, a nanoradian-scale precision of light rotation measurement is lastly achieved in the experiment, which is the highest precision by far to our best knowledge. Furthermore, this scheme holds promise in various optical applications due to the diverse range of manipulable resources offered by photons. [ABSTRACT FROM AUTHOR]

Two-dimensional (2D) Dirac materials, e.g., graphene and transition metal dichalcogenides (TMDs), are one-atom-thick monolayers whose electronic behaviors are described by the Dirac equation. These materials serve not only as test beds for novel quantum physics but also as promising constituents for nanophotonic devices. This review provides a brief overview of the recent effort to control Dirac electron behaviors using nanophotonics. We introduce a principle of light-2D Dirac matter interaction to offer a design guide for 2D Dirac material–based nanophotonic devices. We also discuss opportunities for coupling nanophotonics with externally perturbed 2D materials. [ABSTRACT FROM AUTHOR]