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Analysis of volatile organic compounds (VOCs) for medical and industrial applications typically requires complex and expensive mass spectrometric systems to achieve the desired sensitivity and specificity. Raman spectroscopy enables specific compound identification based on distinct spectral fingerprints but traditionally has low sensitivity. We have developed a novel Raman system that provides VOC detection in the low ppm range. VOCs from the gas phase are absorbed and enriched in a thin polymer film coated on the surface of an optical sensor element. The VOC enriched polymer film is probed with evanescent wave excitation and optimized Raman signal collection. The herein described Raman sensor is low-cost, robust, readily manufacturable, and capable of providing high sensitivity without the nanostructured sensors required for surface enhanced Raman spectroscopy. To suppress background noise and interfering spectral features while improving our ability to resolve VOC mixture spectra, we applied two-dimensional (2D) correlation analysis to time series spectra acquired during VOC absorption into the polymer film. We established proof of principle through analysis of known VOC biomarkers for selected bacterial pathogens. The system enabled VOC detection with significantly higher sensitivity than commercial Raman probes. We observed good agreement between spectra of VOCs in the thin film obtained after 2D correlation analysis, and of pure VOCs using a commercial probe. Mixture spectra were further de-convoluted based on the off-diagonal peaks observable in the 2D Raman spectrum in conjunction with segmented data analysis. We anticipate that this system can be applied to a variety of medical, industrial, and biodefense applications.

Recent observations show that the probability of encountering an extremely large rogue wave in the open ocean is much larger than expected from ordinary wave-amplitude statistics. Although considerable effort has been directed towards understanding the physics behind these mysterious and potentially destructive events, the complete picture remains uncertain. Furthermore, rogue waves have not yet been observed in other physical systems. Here, we introduce the concept of optical rogue waves, a counterpart of the infamous rare water waves. Using a new real-time detection technique, we study a system that exposes extremely steep, large waves as rare outcomes from an almost identically prepared initial population of waves. Specifically, we report the observation of rogue waves in an optical system, based on a microstructured optical fibre, near the threshold of soliton-fission supercontinuum generation--a noise-sensitive nonlinear process in which extremely broadband radiation is generated from a narrowband input. We model the generation of these rogue waves using the generalized nonlinear Schrödinger equation and demonstrate that they arise infrequently from initially smooth pulses owing to power transfer seeded by a small noise perturbation.

Spectral broadening in silicon is studied numerically as well as experimentally. Temporal dynamics of the free carriers generated during the propagation of optical pulses, through the process of two-photon absorption (TPA), affect the amplitude and phase of the optical pulses, thereby determining the nature and extent of the generated spectral continuum. Experimental results are obtained by propagating pico-second optical pulses in a silicon waveguide for intensities that span two orders of magnitude (1-150 GW/cm2). These results validate the conclusions drawn from numerical simulations that the continuum generation has a self-limiting nature in silicon., Comment: 16 pages, 6 figures

This paper presents recent breakthroughs and applications of Raman based silicon photonics such as silicon Raman amplifiers and lasers. These lasers would extend the wavelength range of III-V laser to mid-IR where important applications such as laser medicine, biochemical sensing, and free space optical communication await the emergence of a practical and low cost laser.

We describe the first observation of spontaneous Raman emission, stimulated amplification, and lasing in a SiGe waveguide. A pulsed optical gain of 16dB and a lasing threshold of 25 W peak pulse power (20 mW average) is observed for a Si1-xGex waveguide with x=7.5%. At the same time, a 40 GHz frequency downshift is observed in the Raman spectrum compared to that of a silicon waveguide. The spectral shift can be attributed to the combination of composition- and strain-induced shift in the optical phonon frequency. The prospect of Germanium-Silicon-on-Oxide as a flexible Raman medium is discussed.

First demonstration of cross phase modulation based interferometric switch is presented in silicon on insulator waveguides. By using Mach-Zehnder interferometric configuration we experimentally demonstrate switching of CW signal ~25 nm away from the pump laser. We present the effect of free carrier accumulation on switching. Additionally, we theoretically analyze the transient effects and degradations due to free carrier absorption, free carrier refraction and two photon absorption effects. Results suggest that at low peak power levels the system is governed by Kerr nonlinearities. As the input power levels increase the free carrier effects becomes dominant. Effect of free carrier generation on continuum generation and power transfer also theoretically analyzed and spectral broadening factor for high input power levels is estimated.