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Organic–inorganic halide perovskite solar cells (PVSCs) are considered a promising emerging photovoltaic technology that offer exceptional optoelectronic properties and the potential for economic solar energy conversion. Additive engineering‐based fabrication processes can achieve highly efficient and stable PVSCs that feature well‐controlled perovskite layers with a dense, uniform, "black" α‐phase crystal structure, as well as large grains and few defects. In this study, several hydroxylamine derivatives are introduced as additives to FAPbI3 precursor solutions to investigate their effects on the performance of PVSCs. The addition of hydroxylamine derivatives suppresses the formation of the unwanted δ‐phase and lead iodide, while the α‐phase cubic structure is preferentially formed without changing the bandgap of FAPbI3. Additionally, the additive‐treated perovskite films show improved stability compared with those without additives. Moreover, using X‐ray diffraction and X‐ray photoelectron spectroscopy analyses, it is discovered that the hydroxylamine‐based additives are not incorporated in the crystal lattices but rather resided on the surface or grain boundaries. Notably, the inverted PVSCs added with N‐methylhydroxylamine exhibit an improved power conversion efficiency, higher stability, and minimal hysteresis. [ABSTRACT FROM AUTHOR]

Background: Since global warming is a crucial worldwide issue, carbon tax has been introduced in the global supply chain as an environmental regulation for the reduction of greenhouse gas (GHG) emissions. Costs, GHG emissions, and carbon tax prices differ in each country due to economic conditions, energy mixes, and government policies. Additionally, multiple countries have signed a Free Trade Agreement (FTA). While FTAs result in their economic benefit, they also increase the risk of carbon leakage, which increases GHG emissions in the global supply chain due to relocation production sites from a country with stricter emission constraints to others with laxer ones. Method: This study proposes a mathematical model for decision support to minimize total costs involving carbon taxes with FTAs. Results: Our model determines suppliers, factory locations, and the number of transported parts and products with costs, FTAs, carbon taxes, and material-based GHG emissions estimated using the Life Cycle Inventory (LCI) database. The FTA utilization on the global low-carbon supply chain is examined by comparing the constructed supply chains with and without FTAs, and by conducting sensitivity analysis of carbon tax prices. Conclusions: We found that FTAs would not cause carbon leakage directly and would be effective for reducing GHG emissions economically. [ABSTRACT FROM AUTHOR]