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The reactivation of shear zones under brittle conditions during exhumation due to extensional collapse of the thickened continental crust is a common feature of post-collisional settings. New illite K-Ar analyses and (U-Th)/He data help establish the timing of exhumation and residual deformation during the final stages of orogenic activity in the Kaoko Belt, NW Namibia. Dating of clay-sized white mica from fractionated samples can be used to estimate late-stage deformation in shear zones and constrain the transition from the ductile to the brittle regime. XRD characterization of the dated material indicates crystallization under epizonal conditions (>300°C), which, together with the lack of correlations with age in fractionated samples are suggestive of protracted mineral growth. This supports the interpretation that K-Ar ages at 510-480 Ma in the analyzed samples set a maximum age for the end of ductile activity in the Kaoko Belt, after which brittle faulting is interpreted to have been the predominant style of deformation. This is in accordance with zircon thermochronological data, which predominantly record fast cooling towards temperatures below 200°C shortly thereafter. When compared with equivalent data in South America, the new results reveal that, while the peak orogenic stage of the Dom Feliciano Belt (650-570) took place many tens of Myr earlier than in the Kaoko Belt (580-550 Ma), the transition from ductile to brittle deformation (535-465 Ma and 510-480 Ma, respectively) and rapid exhumation into upper crust conditions (550-400 Ma and 500-350 Ma, respectively) has much more significant overlaps. This observation suggests that, with the progression of the main deformation front from present- day South America to Africa at the time of the collisional process in the Kaoko Belt, the late-stage deformation and eventual post-orogenic exhumation of the Dom Feliciano Belt may have been controlled by the far-field tectonic influence of the continuing orogenic activity to the West. The late stages of the Kaoko Belt, on its turn, are also influenced by a continuation of the progressive migration of the orogenic front towards the Damara Belt, thus highlighting the interconnected character of deformation and exhumation within the entire orogenic system., 4° Encontro dos Pesquisadores de Pós-Doutorado do IGc/USP, Instituto de Geociências da Universidade de São Paulo, São Paulo, SP, Brasil, 29 e 30 de novembro de 2022.

International audience; This database is a geological and geochronological compilation made to study a small Archean/Paleoproterozoic block located in the centre of the Precambrian rock exposition of Uruguay. Petrographic and field outcrops data supporting the samples from which the zircons for textural analysis and U-Pb dating (LA-ICP-MS) come are presented at first with their descriptions. The first table (1) contains the new U-Pb isotopic data. The second table (2) presents a correlation of textures from different zircon samples. The last table (3) contains an inventory of different U-Pb ages found in antecedents. All these data are associated with the paper entitled: "The Archean Pavas Block in Uruguay: extension and tectonic evolution based on LA-ICP-MS U-Pb ages and airborne geophysics".

Single-walled carbon nanotube (SWCNT)/epoxy composites were cured under external electric fields and the influence of the processing parameters (electric field magnitude and frequency, SWCNT concentration and curing temperature) on the electrical response of the system was evaluated. A mold for the electric field application was designed and manufactured, allowing in situ measurements of the electrical resistivity of the composite, during and after the curing process. The resulting electrical properties revealed a strong dependence on the processing parameters. By rising the curing temperature, the solid bulk resistivity was decreased by one order of magnitude. Further reduction was observed with electric fields, up to an additional order of magnitude. Such improvements can be related with the decrease in viscosity and improvement of interconnected-nanotube paths within the polymer matrix. The effect of the electric field on the rotation and interconnection of the SWCNTs was investigated using a classical mechanics model based on the dielectrophoretic theory for the liquid state. The influence of inter-nanotube distances on the bulk electrical properties was calculated at different particle concentrations, using finite element models of the microstructure. This processing technique presents promising results for enhancing the electrical conductivity of polymer composites with carbon-based nanoparticles.

Industrial applications of conductive polymer composites with carbon nanotubes require precise tailoring of their electrical properties. While existing theoretical methods to predict the bulk conductivity require fitting to experiments and often employ power-laws valid only in the vicinity of the percolation threshold, the accuracy of numerical methods is accompanied with substantial computational efforts. In this paper we use recently developed physically-based finite element analyses to successfully train an artificial neural network to make predictions of the bulk conductivity of carbon nanotube-polymer composites at negligible computational cost.

Fil: González, Santiago. Universidad Nacional de Río Negro, Instituto de Investigación en Paleobiología y Geología. Río Negro, Argentina. Fil: Greco, Gerson. Universidad Nacional de Río Negro, Instituto de Investigación en Paleobiología y Geología. Río Negro, Argentina. Fil: Galetto, Antonella. CONICET-IDEAN, Universidad de Buenos Aires. Argentina. Fil: Bordes, Sofia. La.Te. Andes SA (GEOMAP-CONICET). Salta, Argentina. Fil: Basei, Miguel. Centro de Pesquisas em Geocronologia e Geoquímica Isotopica (CPGeo) - Universidad de San Pablo. Brasil. Fil: Parada, Martín. Universidad Nacional de Río Negro, Instituto de Investigación en Paleobiología y Geología. Río Negro, Argentina. Fil: Giacosa, Raúl. Universidad Nacional de Río Negro, Instituto de Investigación en Paleobiología y Geología. Río Negro, Argentina. In the eastern North Patagonian Massif, the Marifil Volcanic Complex corresponds to an Early Jurassic magmatic event. In this study, we evaluate new geochronological and thermochronological data obtained from an ignimbrite of the complex. U–Pb zircon ages from the pumice fraction reveal a Concordia age of 184.4 ± 1.1 Ma. Conversely, U–Pb zircon ages from the whole-rock sample evidence a Concordia age of 190.4 ± 0.6 Ma. Fission track techniques were applied on the same whole-rock sample. Zircon fission track performed on the same zircon-crystals dated by U–Pb yielded an age of 172.5 ± 8.1 Ma, while apatite fission track evidenced a cooling age of 179.1 ± 13.5 Ma. Apatite and zircon crystals describe uniform morphologies with unaltered euhedral to subhedral grains and well-developed crystalline forms. The results suggest that the age of eruption and deposition of the ignimbrite is better explained by the pumice zircon age rather than the whole-rock zircon age. Inherited grain-ages and petrographic evidence support provenance from older, probably cogenetic, magmatic products. Fission track ages reflect a post-depositional process probably related to diagenetic mineral changes.

We present finite element simulations to predict the conductivity, elastic response and strain-sensing capability of conductive composites comprising a polymeric matrix and carbon nanotubes. Realistic representative volume elements (RVE) of the microstructure are generated and both constituents are modelled as linear elastic solids, with resistivity independent of strain; the electrical contact between nanotubes is represented by a new element which accounts for quantum tunnelling effects and captures the sensitivity of conductivity to separation. Monte Carlo simulations are conducted and the sensitivity of the predictions to RVE size is explored. Predictions of modulus and conductivity are found in good agreement with published results. The strain-sensing capability of the material is explored for multiaxial strain states.

We present predictive multiscale models of the multiaxial strain-sensing response of conductive CNT-polymer composites. Detailed physically-based finite element (FE) models at the micron scale are used to produce training data for an artificial neural network; the latter is then used, at macroscopic scale, to predict the electro-mechanical response of components of arbitrary shape subject to a non-uniform, multiaxial strain field, allowing savings in computational time of six orders of magnitude. We apply this methodology to explore the application of CNT-polymer composites to the construction of different types of sensors and to damage detection.

S2: CL images of the studied zircons from sample TAB-24

Methods and analytical procedures.

Mineral chemistry information

S3: CL images of the studied zircons from sample TAB-40

S1: Petrography

Supplementary figures

Background HTLV-1 infection is a neglected disease, despite infecting 10-15 million people worldwide and severe illnesses develop in 10% of carriers lifelong. Acknowledging a greater risk for developing HTLV-1 associated illnesses due to immunosuppression, screening is being widely considered in the transplantation setting. Herein, we report the experience with universal HTLV testing of donors and recipients of solid organ transplants in a survey conducted in Spain. Methods All hospitals belonging to the Spanish HTLV network were invited to participate in the study. Briefly, HTLV antibody screening was performed retrospectively in all specimens collected from solid organ donors and recipients attended since the year 2008. Results A total of 5751 individuals were tested for HTLV antibodies at 8 sites. Donors represented 2312 (42.2%), of whom 17 (0.3%) were living kidney donors. The remaining 3439 (59.8%) were recipients. Spaniards represented nearly 80%. Overall, 9 individuals (0.16%) were initially reactive for HTLV antibodies. Six were donors and 3 were recipients. Using confirmatory tests, HTLV-1 could be confirmed in only two donors, one Spaniard and another from Colombia. Both kidneys of the Spaniard were inadvertently transplanted. Subacute myelopathy developed within 1 year in one recipient. The second recipient seroconverted for HTLV-1 but the kidney had to be removed soon due to rejection. Immunosuppression was stopped and 3 years later the patient remains in dialysis but otherwise asymptomatic. Conclusion The rate of HTLV-1 is low but not negligible in donors/recipients of solid organ transplants in Spain. Universal HTLV screening should be recommended in all donor and recipients of solid organ transplantation in Spain. Evidence is overwhelming for very high virus transmission and increased risk along with the rapid development of subacute myelopathy.

We present a multiscale modelling approach to explore the effects of a non-uniform concentration of carbon nanotubes (CNTs) on the electrical conductivity of CNT-polymer composites. Realistic three-dimensional representative volume elements (RVEs) are generated from a two-dimensional CNT concentration map, obtained via microscopy techniques. The RVEs capture the measured probability density function of the CNT concentration and include a length-scale to represent the details of the spatial distribution of the concentration. The homogenized conductivity of the RVEs is computed via multiscale FE analyses for different values of such length-scale, and it is compared to measurements. The modelling strategy is then used to explore the effects of the microstructural features of these materials on their electrical conductivity.

An Early Cambrian pluton, known as the Guasayan pluton, has been identified in the central area of Sierra de Guasayan, northwestern Argentina. A U-Pb zircon Concordia age of 533±4 Ma was obtained by LA-MC-ICP-MS and represents the first report of robustly dated Early Cambrian magmatism for the northwestern Sierras Pampeanas. The pluton was emplaced in low-grade metasedimentary rocks and its magmatic assemblage consists of K-feldspar (phenocrysts)+plagioclase+quartz+biotite, with zircon, apatite, ilmenite, magnetite and monazite as accessory minerals. Geochemically, the granitic rock is a metaluminous subalkaline felsic granodiorite with SiO2=69.24%, Na2O+K2O=7.08%, CaO=2.45%, Na2O/ K2O=0.71 and FeO/MgO=3.58%. Rare earth element patterns show moderate slope (LaN/YbN=8.05) with a slightly negative Eu anomalies (Eu/Eu*=0.76). We report the first in situ Hf isotopes data (εHft=-0.12 to -4.76) from crystallized zircons in the Early Cambrian granites of the Sierras Pampeanas, helping to constrain the magma source and enabling comparison with other Pampean granites. The Guasayan pluton might provide a link between Early Cambrian magmatism of the central Sierras Pampeanas and that of the Eastern Cordillera, contributing to define the western boundary of the Pampean paleo-arc. Un plutón de edad Cámbrica temprana, conocido como plutón Guasayán, ha sido identificado en el área central de la sierra de Guasayán, noroeste de Argentina. Una edad U-Pb en concordia de 533±4 Ma fue obtenida en circones mediante LA-MC-ICP-MS. Esta edad representa el primer reporte de magmatismo Cámbrico temprano para el noroeste de las Sierras Pampeanas. El mismo está emplazado en rocas metasedimentarias de bajo grado y se caracteriza por una asociación magmática de K-feldespato (fenocristales)+plagioclasa+cuarzo+biotita, con circón, apatita, ilmenita, magnetita y monacita como minerales accesorios. Geoquímicamente, la roca granítica se clasifica como una granodiorita félsica metaluminosa subalcalina con contenidos de SiO2=69,24%, Na2O+K2O=7,08%, CaO=2,45% y relaciones de Na2O/ K2O=0,71 y FeO/MgO=3,58%. Los patrones de elementos de tierras rara muestran una pendiente moderada (LaN/YbN=8,05) con una ligera anomalía negativa de Eu (Eu/Eu*=0,76). Nosotros reportamos los primeros datos in situ de isótopos de Hf (εHft=-0,12 a -4,76) para circones cristalizados en granitos del Cámbrico temprano de Sierras Pampeanas, lo que aporta información crítica sobre la fuente de los magmas, permitiendo la comparación con otros granitos pampeanos. El plutón Guasayán podría proveer el enlace entre el magmatismo del Cámbrico temprano del sector central de las Sierras Pampeanas y aquel de la cordillera Oriental, contribuyendio a definir el límite occidental del paleoarco Pampeano.

Foi estudada a biologia reprodutiva de Melocactus glaucescens e M. paucispinus (Cactaceae) no Município de Morro do Chapéu, Chapada Diamantina, Bahia, sendo abordados aspectos da fenologia, biologia floral, polinização e sistema reprodutivo. Foram registrados os períodos de floração e frutificação, visitantes florais, freqüência e tipo de visitas, além de estratégia e comportamento dos visitantes às flores. Foram realizadas polinizações experimentais para verificar o sistema reprodutivo das espécies. As duas espécies de Melocactus estudadas apresentaram sobreposição de floração ao longo do período de estudo. Os atributos florais de ambas as espécies são típicos da síndrome da ornitofilia: cores atrativas, estrutura tubulosa e produção de néctar com baixa concentração de solutos, entre 20% e 30%. O beija-flor Chlorostilbon aureoventris Boucier & Mulsant (1948) foi o visitante mais freqüente, com 82% e 89% do total de visitas para M. paucispinus e M. glaucescens, respectivamente. Outras espécies de beija-flores e borboletas também visitaram as flores das espécies. A sobreposição no período de floração e a similaridade na composição da guilda de polinizadores destas e demais espécies simpátricas de Melocactus favorece a hibridação no gênero, como foi observado na região. Melocactus glaucescens apresentou auto-incompatibilidade e alogamia, enquanto M. paucispinus é auto-compatível e autogâmica, porém com menor frutificação em autopolinização do que em polinização cruzada, possivelmente devido à ocorrência de depressão endogâmica. Polinizações interespecíficas indicam a ocorrência de inter-compatibilidade entre M. paucispinus e M. concinnus Buining & Brederoo, sustentando hipóteses correntes de hibridação entre estas espécies.

Oxygen is a crucial molecule for cellular function. When oxygen demand exceeds supply, the oxygen sensing pathway centred on the hypoxia inducible factor (HIF) is switched on and promotes adaptation to hypoxia by up-regulating genes involved in angiogenesis, erythropoiesis and glycolysis. The regulation of HIF is tightly modulated through intricate regulatory mechanisms. Notably, its protein stability is controlled by the oxygen sensing prolyl hydroxylase domain (PHD) enzymes and its transcriptional activity is controlled by the asparaginyl hydroxylase FIH (factor inhibiting HIF-1).To probe the complexity of hypoxia-induced HIF signalling, efforts in mathematical modelling of the pathway have been underway for around a decade. In this paper, we review the existing mathematical models developed to describe and explain specific behaviours of the HIF pathway and how they have contributed new insights into our understanding of the network. Topics for modelling included the switch-like response to decreased oxygen gradient, the role of micro environmental factors, the regulation by FIH and the temporal dynamics of the HIF response. We will also discuss the technical aspects, extent and limitations of these models. Recently, HIF pathway has been implicated in other disease contexts such as hypoxic inflammation and cancer through crosstalking with pathways like NF?B and mTOR. We will examine how future mathematical modelling and simulation of interlinked networks can aid in understanding HIF behaviour in complex pathophysiological situations. Ultimately this would allow the identification of new pharmacological targets in different disease settings.

Isotopic data are presented for rocks of the Andean crystalline basement at 40°S, in Neuquén and Río Negro provinces. The methods used were U-Pb in zircon (crystallization ages of plutonic rocks), K-Ar in micas and U-Pb in titanite (metamorphism and cooling ages) and Sm-Nd in whole rock (crustal evolution). No Proterozoic ages were obtained as suggested by previous Rb-Sr and K-Ar data, and two different igneous-metamorphic events were identified. The older one is Devonian and exposed in San Martín de los Andes region, according to 420-380 Ma zircon ages and 375-310 Ma ages in micas of deformed tonalitic and granitic rocks. The younger one, in rocks cropping out to the south of Limay River region, is revealed by Early Permian zircon ages (about 280 Ma) and Late Permian cooling ages (260-250 Ma) of metaigneous rocks. The rocks of both sets were assigned to a magmatic arc environment and correlated respectively with the Chanic orogeny (Devonian; Upper Famatinian Cycle) and Gondwanic Cycle (Upper Paleozoic-Triassic). The Sm-Nd TDM model ages, ca.1907-1165 Ma, eNd for the crystallization age of the rocks ca. -3,0 and -8,4 and eNd(0) ca. -6,9-11,9 suggest reworking of continental proterozoic crust with minor addition of juvenile magmas from the mantle during the Paleozoic.

Se da a conocer los resultados de la datación U-Pb convencional en circones del Granito Paimán, uno de los componentes del flanco oriental del Sistema de Famatina. Fueron analizadas cinco fracciones de cristales de circón de un granito porfiroide, característico de la unidad. Los resultados son coherentes entre sí y proveen una edad de 477,6 ± 4,1 Ma, que ubican la edad de cristalización y emplazamiento en el Ordovícico Temprano. La datación corrobora su asignación a la fase magmática oclóyica y específicamente al cinturón famatiniano. El análisis del presente y otros datos U-Pb previos de otras rocas graníticas del cinturón famatiniano entre los 28º y 33º S, permiten delimitar un estrecho lapso (alrededor de 20 Ma) de actividad ígnea, sin poderse determinar ninguna polaridad en la producción del magmatismo., Conventional U-Pb zircon ages for the Paimán Granite are presented. The magmatic unit crops out in the eastern border of the Famatina range. Five zircon fractions were analysed from a coarse porphyritic granitoid, the major component in the Paimán-Chilecito area. Results are concordant for the five fractions and the mean 206Pb/238U age of 477.6 ± 4.1 Ma is Early Ordovician. This age confirms that the Paimán Granite is part of the Ocloyic magmatic phase and Famatinian belt. The present age together with the previous U-Pb ages from granitoids of the Famatinian belt between 28º and 33º S suggest that the magmatic activity occurred over a short time span of about 20 Ma, following no noticeable internal polarity within the belt., Centro de Investigaciones Geológicas