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Anthropogenic activities on land will affect the carbon system in coastal waters. This condition will affect the role of coastal waters as a source or sink of carbon. This research will examine the distribution of carbonate systems and estimate CO2 fluxes. Water samples were taken at 30 stations as well as measuring in situ water parameters including pH, temperature, salinity, and pressure. Alkalinity was analysed based on the titration method, chl-a using the fluorometer method, and carbonate system parameters (pCO2(sea) and DIC) calculated using CO2SYS.xlsm. The pCO2(atm) value is calculated based on atmospheric data from satellite data, including the saturation vapour pressure of sea air in the atmosphere, fraction mol of CO2, and sea level pressure. Pearson correlation analysis was used to see the correlation between the measured parameters and CO2 flux. Carbon flux is determined based on the difference between atmospheric and oceanic pCO2. The DIC calculation result was in the range of 1,946.09 µmol/kg - 2,061.65 µmol/kg and the total alkalinity was 2,156.86 µmol/kg - 2,264.71 µmol/kg. Based on this value, Jepara coastal waters have pCO2(sea) of 573,800 micro-atmospheric (µatm) which is higher than pCO2(atm) (i.e., 386,772 µatm). The input of organic/inorganic carbon resulting from anthropogenic processes on land has influenced Jepara coastal waters which act as a source of CO2 into the atmosphere amounting to 103,799 mmol/m2/day. The results of this research can be used as a reference for managing coastal areas to achieve low carbon emissions. [ABSTRACT FROM AUTHOR]

The fluctuation of suspended particulate matter (SPM) is essential to the biogeochemical cycle and ecological health of coastal waters. Anthropogenic activities potentially trigger an increase in SPM, so it needs to be monitored continuously. Spatial and temporal monitoring of SPM can be carried out cost-effectively with broad coverage using a remote sensing application. This study aims to build the SPM algorithm and estimate its temporal variability. The algorithm model in this study is based on an empirical formula between field data and reflectance data with the same acquisition. Water samples were taken from 100 stations in July 2022. Half were used for model building and the other for model validation. Suspended Particulate Matter was determined gravimetrically and estimated their temporal variability was based on Landsat 9 image records from December 2021 - November 2022. The results of the analysis show that the best algorithm for SPM estimation can be built based on coastal aerosol canals (B1), blue canals (B2), and green canals (B3) with the accuracy test result of (R² = 0.68; RMSE = 5.551 mg.L-1; MAPE= 7.07%; Bias= 0.28). The SPM temporal fluctuations were generally higher in the west monsoon and lowered in the east monsoon, ranging from 30 to 70 mg.L-1. On the other hand, the spatial distribution shows a higher magnitude in the estuary than in the offshore waters, with a deviation of about 30 mg.L-1. Regional authorities can use the results obtained to improve the management of coastal water quality and monitoring systems. [ABSTRACT FROM AUTHOR]

The distribution of organic matter and nutrients in the estuary can be influenced by tidal current. The presence of organic matter and nutrients can determine the water quality. However, the exceed amount of organic matter and nutrient in the water could lead to eutrofication that caused the depletion of dissolved oxygen. The research was aimed to determine the distribution of organic matter and nutrients (i.e. phophate and nitrate) due to the tidal current in Demaan estuary, Jepara. The titration method with permanganate was used to measure the organic matter concentration in the samples. Meanwhile, the spectrophotometric method was used to measure nitrate and phosphate concentration in the samples. Tidal current was simulated by Surface water Modelling System (SMS) software, and the distribution of organic matter, nitrate and phosphate was plotted using ArGIS software. The result showed that the concentration of organic matter and nutrients is higher at ebb tide than flood tide. The distribution of organic matter and phosphate followed the tidal current, flowing to the north at ebb tide and back to south at flood tide. It is concluded that organic matter and phosphate sourced from the rivers. [ABSTRACT FROM AUTHOR]