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A gas–liquid vortex reactor (GLVR) is considered one of the promising Process-Intensified Equipment for applications that require high mixing and mass transfer efficiency. To gain understanding of the fundamentals of GLVR operation, the gas–liquid hydrodynamics in the GLVR has been investigated by high-speed imaging, digital images analysis and cross correlation. Gas bubbles and liquid ligaments are observed in the GLVR over a wide operating window. The dynamic liquid layer thickness in the GLVR chamber varies in the range of 26–36 mm. The instantaneous and time-average velocity fields of the liquid phase are obtained with a guaranteed high signal-to-noise ratio (cross correlation peak ratio higher than 10), allowing the analysis of liquid turbulent properties including the turbulent kinetic energy and its dissipation rate. Results show that the high turbulent kinetic energy dissipation rate ranging from 23 to 114 m2/s3 contributes to a high mixing and mass transfer efficiency in the GLVR.

Biomass fast pyrolysis has been considered one of the best alternatives for the thermal conversion of biomass into bio-oil. This work introduces a new reactor technology for biomass fast pyrolysis, the Gas-Solid Vortex Reactor (GSVR), to obtain high bio-oil yields. The GSVR was designed to decrease the residence time of the pyrolysis vapors; thus, the secondary cracking reactions are reduced, to enhance the segregation of the char and the unreacted biomass and to improve the heat transfer rate. Biomass fast pyrolysis experiments have been carried out for the first time in a Gas-Solid Vortex Reactor (GSVR) at 773 K, using softwood (pine) and hardwood (poplar) as feedstock. Char yields as low as 10 wt. % in the GSVR were comparable to those reported for the same feedstocks processed in conventional fluidized bed reactors. The yields of non-condensable gases in the range of 15–17 wt. % were significantly lower than those reported for other commonly used biomass fast pyrolysis reactors. Two-dimensional gas chromatography (GC × GC) revealed noticeable differences at the molecular level between the bio-oils from the GSVR and bio-oils from other reactors. The aromatics in the pine bio-oil consist almost entirely (85 wt. %) of guaiacols. For poplar bio-oils no predominant group of aromatics was found, but phenolics, syringols, and catechols were the most pronounced. The experimental results highlight the advantages of the GSVR for biomass pyrolysis, reaching stable operation in around 60 s, removing the formed char selectively during operation, and enabling fast entrainment of pyrolysis vapors. Results indicate a great potential for increasing yield and selectivity towards guaiacols in softwood (e.g., pine) bio-oil. Likewise, decreasing pyrolysis temperature could increase the yield of guaiacols and syringols in hardwood (e.g., poplar) bio-oil.

To develop cost-effective CO2 capture technology process intensification will play a vital role. In this work, the capabilities of a gas-liquid vortex reactor (GLVR) as novel process intensification equipment are evaluated by studying its interphase mass transfer parameters to build up the fundamentals for its future application to for example, CO2 capture. The NaOH-CO2 chemisorption system and Danckwerts' model are applied to obtain the effective interfacial area and liquid-side mass transfer coefficient. Results show that the gas-liquid contact in the GLVR is capable of both generating a large interfacial area in a small reactor volume and creating a region with high-energy dissipation to improve mass transfer. A comparison of the volumetric mass transfer coefficients with data reported in literature for conventional and intensified reactor types confirms a superior mass transfer efficiency and, most importantly, a favorable energetic efficiency of the GLVR.