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We present a significantly updated CO2 altitude profile for Venus (64.2–0.9 km) and provide support for a potential deep lower atmospheric haze of particles (≤17 km). We extracted this information by developing a new analytical model for mass spectra obtained by the Pioneer Venus Large Probe (PVLP) Neutral Mass Spectrometer (LNMS). Our model accounts for changes in LNMS configuration and output during descent and enables the disentanglement of isobaric species via a data fitting routine that adjusts for mass-dependent changes in peak shape. The model yields CO2 in units of density (kg m−3), isotope ratios for 13C/12C and 18O/16O, and 14 measures of CO2 density across 55.4–0.9 km, which represents the most complete altitude profile for CO2 at ≤60 km to date. The CO2 density profile is also consistent with the pressure, temperature, and volumetric gas measurements from the PVLP and VeNeRa spacecraft. Nominal and low-noise operations for the LNMS mass analyzer are supported by the behaviors (e.g., ionization yields, fragmentation yields, and peak shapes) of several internal standards (e.g., CH3+, CH4+, 40Ar+, 136Xe2+, and 136Xe+), which were tracked across the descent. Lastly, our review of the CO2 profile and LNMS spectra reveals hitherto unreported partial and rapidly clearing clogs of the inlet in the lower atmosphere, along with several ensuing data spikes at multiple masses. Together, these observations suggest that atmospheric intake was impacted by particles at ≤17 km and that rapid particle degradation at the inlet yielded a temporary influx of mass signals into the LNMS.

We present a re-examination of mass spectral data obtained from the Pioneer Venus Large Probe Neutral Mass Spectrometer. Our interpretations of differing trace chemical species are suggestive of redox disequilibria in Venus' middle clouds. Assignments to the data (at 51.3 km) include phosphine, hydrogen sulfide, nitrous acid, nitric acid, carbon monoxide, hydrochloric acid, hydrogen cyanide, ethane, and potentially ammonia, chlorous acid, and several tentative PxOy species. All parent ions were predicated upon assignment of corresponding fragmentation products, isotopologues, and atomic species. The data reveal parent ions at varying oxidation states, implying the presence of reducing power in the clouds, and illuminating the potential for chemistries yet to be discovered. When considering the hypothetical habitability of Venus' clouds, the assignments reveal a potential signature of anaerobic phosphorus metabolism (phosphine), an electron donor for anoxygenic photosynthesis (nitrite), and major constituents of the nitrogen cycle (nitrate, nitrite, ammonia, and N2).

Venus has a thick atmosphere that rotates 60 times as fast as the surface, a phenomenon known as superrotation. We use data obtained from the orbiting Akatsuki spacecraft to investigate how the super-rotation is maintained in the cloud layer, where the rotation speed is highest. A thermally induced latitudinal-vertical circulation acts to homogenize the distribution of the angular momentum around the rotational axis. Maintaining the super-rotation requires this to be counteracted by atmospheric waves and turbulence. Among those effects, thermal tides transport the angular momentum, which maintains the rotation peak, near the cloud top at low latitudes. Other planetary-scale waves and large-scale turbulence act in the opposite direction. We suggest that hydrodynamic instabilities adjust the angular-momentum distribution at mid-latitudes.

From the discovery that Venus has an atmosphere during the 1761 transit by M. Lomonosov to the current exploration of the planet by the Akatsuki orbiter, we continue to learn about the planet's extreme climate and weather. This chapter attempts to provide a comprehensive but by no means exhaustive review of the results of the atmospheric thermal structure and radiative balance since the earlier works published in Venus and Venus II books from recent spacecraft and Earth based investigations and summarizes the gaps in our current knowledge. There have been no in-situ measurements of the deep Venus atmosphere since the flights of the two VeGa balloons and landers in 1985 (Sagdeev et al., Science 231:1411-1414, 1986). Thus, most of the new information about the atmospheric thermal structure has come from different remote sensing (Earth based and spacecraft) techniques using occultations (solar infrared, stellar ultraviolet and orbiter radio occultations), spectroscopy and microwave, short wave and thermal infrared emissions. The results are restricted to altitudes higher than about 40 km, except for one investigation of the near surface static stability inferred by Meadows and Crisp (J. Geophys. Res. 101:4595-4622, 1996) from 1 m observations from Earth. Little information about the lower atmospheric structure is possible below about 40 km altitude from radio occultations due to large bending angles. The gaps in our knowledge include spectral albedo variations over time, vertical variation of the bulk composition of the atmosphere (mean molecular weight), the identity, properties and abundances of absorbers of incident solar radiation in the clouds. The causes of opacity variations in the nightside cloud cover and vertical gradients in the deep atmosphere bulk composition and its impact on static stability are also in need of critical studies. The knowledge gaps and questions about Venus and its atmosphere provide the incentive for obtaining the necessary measurements

We describe and compare two methods of short-exposure, high-definition ground-based imaging of the planet Mercury. Two teams haverecorded images of Mercury on different dates, from different locations, and with different observational and data reduction

Although Earth-based observations provide hints of Neptune's dynamic activity, most of the observations of cloud patterns, winds, and horizontal variations in temperature are from Voyager. The wind speed varies from 400 m s^(-1) westward at the equator to 250m s^(-1) eastward at -70° latitude. As on all the giant planets, the winds decay with height in the stratosphere. The meridional contrasts in temperature are small in the upper troposphere and lower stratosphere, with mid-latitude minima that are reminiscent of those on Uranus. The oscillations and motions of Neptune's large spots are more regular than those of Jupiter and Saturn. During the Voyager observations, the Great Dark Spot moved steadily equatorward while it oscillated in shape with an 8-day period. The latitude and longitude of Dark Spot 2 oscillated with a 36-day period. The small elements within each major feature appeared and disappeared in less than a day. Such activity is remarkable for a planet whose emitted power per unit area is 1/20 that of Jupiter and 1/400 that of the Earth. Weak viscosity can account for the decay of winds in the stratosphere, and models without viscosity can account for the spot oscillations. But the wind velocities and temperatures vs latitude--especially the differences among the giant planets--have not been explained. Major unknowns concern convection and latent heat release, the interaction with Neptune's fluid interior, and the importance of internal energy relative to solar energy in driving the circulation.